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Synergistic role for CO
Nature Catalysis ( IF 42.8 ) Pub Date : 2024-10-23 , DOI: 10.1038/s41929-024-01226-0
Estíbaliz Merino

Typically, active acyl intermediates are quenched with nucleophiles to complete carbonylation. Now, a visible-light-induced radical relay enables CO insertion and selective (hetero)aryl group migration without nucleophiles.

中文翻译:

 CO 的协同作用


通常,活性酰基中间体与亲核试剂一起淬灭以完成羰基化。现在,可见光诱导的自由基中继能够在没有亲核试剂的情况下实现 CO 插入和选择性(异)芳基迁移。
更新日期:2024-10-24
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