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Copper-Catalyzed B–H Bond Insertion Reaction: A Highly Efficient and Enantioselective C–B Bond-Forming Reaction with Amine–Borane and Phosphine–Borane Adducts
Journal of the American Chemical Society ( IF 14.4 ) Pub Date : 2013-09-13 , DOI: 10.1021/ja408306a
Qing-Qing Cheng 1 , Shou-Fei Zhu 1 , Yong-Zhen Zhang 1 , Xiu-Lan Xie 1 , Qi-Lin Zhou 1
Affiliation  

A copper-catalyzed B-H bond insertion reaction with amine- and phosphine-borane adducts was realized with high yield and enantioselectivity under mild reaction conditions. The B-H bond insertion reaction provides a new C-B bond-forming methodology and an efficient approach to chiral organoboron compounds.

中文翻译:

铜催化的 B-H 键插入反应:与胺-硼烷和膦-硼烷加合物的高效对映选择性 C-B 键形成反应

在温和的反应条件下,以高产率和对映选择性实现了铜催化的 BH 键插入反应与胺-和膦-硼烷加合物。BH 键插入反应提供了一种新的 CB 键形成方法和手性有机硼化合物的有效方法。
更新日期:2013-09-13
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