<br>多齿配体增强螯合以稳定高性能钙钛矿太阳能电池的埋入界面,Angewandte Chemie International Edition

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多齿配体增强螯合以稳定高性能钙钛矿太阳能电池的埋入界面
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2024-01-05 , DOI: 10.1002/anie.202317185
Baibai Liu ₁ , Qian Zhou ₁ , Yong Li ₂ , Yu Chen ₁ , Dongmei He ₁ , Danqing Ma ₁ , Xiao Han ₁ , Ru Li ₁ , Ke Yang ₃ , Yingguo Yang ₄ , Shirong Lu ₅ , Xiaodong Ren ₆ , Zhengfu Zhang ₇ , Liming Ding ₈ , Jing Feng ₇ , Jianhong Yi ₇ , Jiangzhao Chen _{1,

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Affiliation

Key Laboratory of Optoelectronic Technology & Systems (Ministry of Education), College of Optoelectronic Engineering, Chongqing University, Chongqing, 400044, China.
Key Laboratory of Applied Surface and Colloid Chemistry, Ministry of Education, Shaanxi Key Laboratory for Advanced Energy Devices, Shaanxi Engineering Lab for Advanced Energy Technology, Institute for Advanced Energy Materials, School of Materials Science and Engineering, Shaanxi Normal University, Xi'an, 710119, China.
Chongqing Institute of Green and Intelligent Technology, Chinese Academy of Sciences, Chongqing, 400714, China.
School of Microelectronics, Fudan University, Shanghai, 200433, China.
Department of Material Science and Technology, Taizhou University, Taizhou, 318000, China.
Yunnan Key Laboratory for Micro/Nano Materials & Technology, International Joint Research Center for Optoelectronic and Energy Materials, School of Materials and Energy, Yunnan University, Kunming, 650091, China.
Faculty of Materials Science and Engineering, Kunming University of Science and Technology, Kunming, 650093, China.
Center for Excellence in Nanoscience (CAS), Key Laboratory of Nanosystem and Hierarchical Fabrication (CAS), National Center for Nanoscience and Technology, Beijing, 100190, China.

提出了一种多齿配体增强螯合策略，通过管理界面缺陷和应力来增强埋入界面的稳定性。经过 BTP 改进的器件实现了 24.63% 的令人鼓舞的功率转换效率 (PCE)。经过 3000 小时以上的环境老化和 1728 小时的热应力后，未封装的 BTP 改性器件分别退化至其初始 PCE 值的 98.6% 和 84.2%。

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更新日期：2024-01-05

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