Synthesis of 2-Pyrones from Renewable Resources,Synthesis

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Synthesis of 2-Pyrones from Renewable Resources
Synthesis ( IF 2.2 ) Pub Date : 2023-05-31 , DOI: 10.1055/a-2085-4089
Daniel Dobler ₁ , Michael Leitner ₁ , Peter Kreitmeier ₁ , Oliver Reiser ₁

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An atom-economic reaction sequence on a multigram scale for synthesizing 2-pyrone was developed starting from furfuryl alcohol, a renewable resource made from bran or bagasse, utilizing a large-scale thermal rearrangement of cyclopentadienone epoxide as the key step. Additionally, 6-substituted 2-pyrone natural product derivatives are readily accessible by this approach.

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