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A Spectroscopic Study on Nitrogen Electrooxidation to Nitrate
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2023-03-13 , DOI: 10.1002/anie.202217411 Tieliang Li 1 , Shuhe Han 1 , Yuting Wang 1 , Jin Zhou 1 , Bin Zhang 1 , Yifu Yu 1, 2
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2023-03-13 , DOI: 10.1002/anie.202217411 Tieliang Li 1 , Shuhe Han 1 , Yuting Wang 1 , Jin Zhou 1 , Bin Zhang 1 , Yifu Yu 1, 2
Affiliation
The powerful electrochemical in situ attenuated total reflection surface-enhanced infrared absorption spectroscopy (ATR-SEIRAS) and online differential electrochemical mass spectrometry (DEMS) techniques are employed to detect reaction intermediates. Based on the detected intermediates, the associative mechanism with the addition of hydroxyl at distal N (distal mechanism) is deduced for nitrogen oxidation reaction (NOR).
中文翻译:
氮电氧化生成硝酸盐的光谱研究
采用强大的电化学原位衰减全反射表面增强红外吸收光谱 (ATR-SEIRAS) 和在线微分电化学质谱 (DEMS) 技术检测反应中间体。基于检测到的中间体,推导了氮氧化反应 (NOR) 与在远端 N 处添加羟基的缔合机制(远端机制)。
更新日期:2023-03-13
中文翻译:
氮电氧化生成硝酸盐的光谱研究
采用强大的电化学原位衰减全反射表面增强红外吸收光谱 (ATR-SEIRAS) 和在线微分电化学质谱 (DEMS) 技术检测反应中间体。基于检测到的中间体,推导了氮氧化反应 (NOR) 与在远端 N 处添加羟基的缔合机制(远端机制)。