Spin Manipulation in a Metal–Organic Layer through Mechanical Exfoliation for Highly Selective CO2 Photoreduction,Angewandte Chemie International Edition

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Spin Manipulation in a Metal–Organic Layer through Mechanical Exfoliation for Highly Selective CO2 Photoreduction
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2023-03-03 , DOI: 10.1002/anie.202301925
Dayu Wu ₁ , Hua-Qing Yin ₂ , Zeshi Wang ₃ , Mingren Zhou ₁ , Chengfeng Yu ₁ , Jing Wu ₁ , Huixian Miao ₁ , Takashi Yamamoto ₄ , Wenjiang Zhaxi ₁ , Zetao Huang ₁ , Luying Liu ₁ , Wei Huang ₁ , Wenhui Zhong ₅ , Yasuaki Einaga ₄ , Jun Jiang ₃ , Zhi-Ming Zhang ₂

Affiliation

The manipulation of Fe³⁺ spin states from high spin (HS; s=5/2) in bulk crystals to mixed spin lattices (with s=5/2 and low spin (LS); s=1/2) is demonstrated in a two-dimensional ultrathin metal–organic layer catalyst by mechanical exfoliation. The resulting catalyst has enhanced activity and selectivity for CO₂ photoreduction (CO2RR) over the hydrogen evolution reaction (HER).

中文翻译：

通过机械剥离在金属有机层中进行自旋操纵以实现高选择性 CO2 光还原

从块状晶体中的高自旋（HS；s =5/2）到混合自旋晶格（s =5/2 和低自旋（LS）；s =1/2）的 Fe ³⁺自旋状态的操纵在中得到证明通过机械剥离的二维超薄金属有机层催化剂。所得催化剂具有比析氢反应 (HER)更高的 CO _{2光还原 (CO2RR) 活性和选择性。}

更新日期：2023-03-03

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