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Practical and General Alcohol Deoxygenation Protocol
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2023-02-25 , DOI: 10.1002/anie.202300178 Oliver P Williams 1 , Alyah F Chmiel 1 , Myriam Mikhael 2 , Desiree M Bates 1 , Charles S Yeung 2 , Zachary K Wickens 1
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2023-02-25 , DOI: 10.1002/anie.202300178 Oliver P Williams 1 , Alyah F Chmiel 1 , Myriam Mikhael 2 , Desiree M Bates 1 , Charles S Yeung 2 , Zachary K Wickens 1
Affiliation
A new protocol for alcohol deoxygenation that functions across a wide range of alcohol structures is reported. This approach combines the reductive potency of carbon dioxide radical anion with acidic additives to promote the kinetically slow C(sp3)−O bond cleavage.
中文翻译:
实用且通用的酒精脱氧方案
据报道,一种新的醇脱氧方案可在多种醇结构中发挥作用。这种方法将二氧化碳自由基阴离子的还原能力与酸性添加剂相结合,以促进动力学上缓慢的 C(sp 3 )−O 键裂解。
更新日期:2023-02-25
中文翻译:
实用且通用的酒精脱氧方案
据报道,一种新的醇脱氧方案可在多种醇结构中发挥作用。这种方法将二氧化碳自由基阴离子的还原能力与酸性添加剂相结合,以促进动力学上缓慢的 C(sp 3 )−O 键裂解。