Synthesis of Flavin-Indole Conjugates with Rigid Diamino Linkers as Cryptochrome Model Compounds,European Journal of Organic Chemistry

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Synthesis of Flavin-Indole Conjugates with Rigid Diamino Linkers as Cryptochrome Model Compounds
European Journal of Organic Chemistry ( IF 2.5 ) Pub Date : 2022-12-14 , DOI: 10.1002/ejoc.202201327
Nils Schröder ₁ , Marc Schmidtmann ₁ , Henrik Mouritsen ₂ , Jens Christoffers ₃

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Stepwise reductive aminations of aldehydes derived from indole and flavin with rigid 1,4-diaminocyclohexane and 2,6-diamino-trans-decalin linkers furnished two model compounds for avian cryptochromes. Radical pair formation by light-induced electron-transfer in such dyads was proposed to show a magnetic-field-dependent quantum effect.

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