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Phase Transfer-Mediated Degradation of Ether-Based Localized High-Concentration Electrolytes in Alkali Metal Batteries
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2022-06-13 , DOI: 10.1002/anie.202207018
Xiaojuan Chen 1 , Lei Qin 2 , Jiaonan Sun 2 , Songwei Zhang 2 , Dan Xiao 1 , Yiying Wu 2
Affiliation  

Rethinking the stability of localized high-concentration electrolytes in alkali metal batteries: Ether solvent can act as a phase transfer reagent that dissolves alkali metals into solvated electrons and metal anions to decompose inert hydrofluoroether co-solvents, preventing the formation of stable solid-electrolyte interphases.

中文翻译:

碱金属电池中醚基局部高浓度电解质的相转移介导降解

重新思考碱金属电池中局部高浓度电解质的稳定性:醚溶剂可以作为相转移试剂,将碱金属溶解成溶剂化电子和金属阴离子,分解惰性氢氟醚助溶剂,防止形成稳定的固体电解质界面.
更新日期:2022-06-13
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