Control of Redox-Active Ester Reactivity Enables a General Cross-Electrophile Approach to Access Arylated Strained Rings**,Angewandte Chemie International Edition

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Control of Redox-Active Ester Reactivity Enables a General Cross-Electrophile Approach to Access Arylated Strained Rings**
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2022-06-10 , DOI: 10.1002/anie.202205673
Daniel C Salgueiro ₁ , Benjamin K Chi ₁ , Ilia A Guzei ₁ , Pablo García-Reynaga ₂ , Daniel J Weix ₁

Affiliation

Aliphatic strained rings can be (hetero)arylated through a decarboxylative cross-electrophile coupling. The keys to this advance are: 1) a new ligand that enables tolerance of a variety of strained ring classes and 2) electronic tunability of redox-active esters to control the rate of radical generation.

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