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Azine-linked covalent organic framework-modified GO membrane for high-efficiency separation of aqueous dyes and salts in wastewater
Journal of Membrane Science ( IF 8.4 ) Pub Date : 2022-04-30 , DOI: 10.1016/j.memsci.2022.120546
Hanchen Ye 1 , Dongyun Chen 1 , Najun Li 1 , Qingfeng Xu 1 , Hua Li 1 , Jinghui He 1 , Jianmei Lu 1
Affiliation  

Dyes, salts, microorganisms, and other pollutants found in wastewater can be harmful to the environment and are difficult to treat. To address this problem, we designed and prepared a graphene oxide (GO) membrane that was modified with an azine-linked covalent-organic framework via dipping and polymerization. This membrane could efficiently remove dyes with molecular weight from 319.85 to 1355.37 (removal efficiency greater than 90%), inorganic salts (greater than 80%), and microorganisms (nearly 100%). The maximum flux of the composite membrane can reach 47 L m−2 h−1 bar−1. The developed membrane was able to carry out its removal effect by utilizing a combination of sieving and electrostatic interactions, showing promising future application prospects. The removal mechanism of the developed membrane is also briefly discussed.



中文翻译:

用于废水中水性染料和盐类高效分离的氮杂连接共价有机骨架修饰的GO膜

废水中发现的染料、盐分、微生物和其他污染物对环境有害且难以处理。为了解决这个问题,我们设计并制备了一种氧化石墨烯 (GO) 膜,该膜通过浸渍和聚合用吖嗪连接的共价有机框架进行了改性。该膜可以有效去除分子量从319.85到1355.37的染料(去除效率大于90%)、无机盐(大于80%)和微生物(接近100%)。复合膜的最大通量可达47 L m -2  h -1 bar -1. 所开发的膜能够利用筛分和静电相互作用的结合来发挥其去除作用,显示出良好的未来应用前景。还简要讨论了开发膜的去除机制。

更新日期:2022-05-04
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