Highly Efficient Conversion of Propargylic Alcohols and Propargylic Amines with CO2 Activated by Noble-Metal-Free Catalyst Cu2O@ZIF-8,Angewandte Chemie International Edition

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Highly Efficient Conversion of Propargylic Alcohols and Propargylic Amines with CO2 Activated by Noble-Metal-Free Catalyst Cu2O@ZIF-8
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2022-01-11 , DOI: 10.1002/anie.202114817
Ai-Ling Gu _{1,

2} , Ya-Xin Zhang _{1,

2} , Zhi-Lei Wu _{1,

2} , Hui-Ya Cui _{1,

2} , Tian-Ding Hu ₃ , Bin Zhao ₁

Affiliation

The noble-metal-free catalyst Cu₂O@ZIF-8 with a yolk–shell structure was synthesized, and it represents the first noble-metal-free catalyst that can effectively catalyze both propargylic alcohols and propargylic amines with CO₂ under mild conditions.

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