Porphyrin(2.1.2.1) as a novel binucleating ligand: synthesis and molecular structures of mono- and di-rhodium(I) complexes,Chemical Communications

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Porphyrin(2.1.2.1) as a novel binucleating ligand: synthesis and molecular structures of mono- and di-rhodium(I) complexes
Chemical Communications ( IF 4.3 ) Pub Date : 2021-11-12 , DOI: 10.1039/d1cc05641g
Songlin Xue _{1,

2} , Ningchao Liu ₁ , Peifeng Mei ₃ , Daiki Kuzuhara ₄ , Mingbo Zhou ₂ , Jianming Pan ₁ , Hiroko Yamada ₃ , Fengxian Qiu ₁

Affiliation

The first example of monovalent and bimetallic porphyrins(2.1.2.1), the rhodium(I) complex of porphyrin(2.1.2.1), was readily obtained under controlled conditions. The coordinated rhodium(I) drastically influenced the molecular structure and optical and electronic properties. Our results clearly demonstrate that porphyrin(2.1.2.1) could be developed as a new binucleating ligand for the fabrication of bimetallic complexes.

中文翻译：

卟啉（2.1.2.1）作为一种新型双核配体：单-和二-铑（I）配合物的合成和分子结构

单价和双金属卟啉 (2.1.2.1) 的第一个例子，即卟啉 (2.1.2.1) 的铑 ( I ) 络合物，在受控条件下很容易获得。配位的铑（I）极大地影响了分子结构和光学和电子特性。我们的结果清楚地表明，卟啉 (2.1.2.1) 可以作为一种新的双核配体用于制造双金属配合物。

更新日期：2021-11-17

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