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Interactions of CO2 with Hydrocarbon Liquid Observed from Adsorption of CO2 in Organic-Rich Shale
Energy & Fuels ( IF 5.2 ) Pub Date : 2020-11-06 , DOI: 10.1021/acs.energyfuels.0c02774
Jinsheng Wang 1 , David Ryan 1 , Hanin Samara 2, 3 , Philip Jaeger 3
Affiliation  

Whereas the importance of shale oil and gas production to the energy supply is increasing, the recovery of shale oil and gas is low and the environmental performance needs improvement. Injection of CO2 captured from industrial emitters into shale reservoirs could enhance the oil and gas recovery and retain CO2 through adsorption in shale to offset greenhouse gas emissions. In this work, we present a study on adsorption of CO2 in an organic-rich shale. Unusual adsorption behaviors have been observed: The rate of adsorption increased with increasing pressure without showing a trend of saturation. Moreover, mass loss occurred at an elevated pressure. The adsorption behaviors have been elucidated by extraction of hydrocarbons from shale by CO2, from which the interactions of CO2 with hydrocarbons are elucidated and new insights are obtained.

中文翻译:

CO的相互作用2与烃类液体从观察吸附CO的2有机富页岩

尽管页岩油气生产对能源供应的重要性日益提高,但页岩油气的回收率较低,环境性能需要改善。从工业排放源捕获的CO 2注入页岩储层可以增强油气的采收率,并通过吸附在页岩中来保留CO 2,以抵消温室气体的排放。在这项工作中,我们提出了对富含有机物的页岩中CO 2吸附的研究。观察到不寻常的吸附行为:吸附速率随压力增加而增加,而没有显示饱和趋势。而且,在高压下发生质量损失。通过用CO 2从页岩中提取碳氢化合物来阐明吸附行为,从中阐明了CO 2与烃类的相互作用并获得了新的见解。
更新日期:2020-11-19
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