Sensors and Actuators B: Chemical ( IF 8.0 ) Pub Date : 2020-08-17 , DOI: 10.1016/j.snb.2020.128755 Jinglong Bai , Yibing Luo , Chen Chen , Yao Deng , Xu Cheng , Beixi An , Qiao Wang , Jianpeng Li , Jinyuan Zhou , Yanrong Wang , Erqing Xie
Herein, pristine indium oxide (In2O3) and rare earth (Ce, Tm, Eu, Er, and Tb)-doped In2O3 nanotubes were synthesized by a facile one-step electrospinning method. Rare-earth (RE) doping increases the number of active sites on the surface, which enhances the electrical response and gas-sensing performance of In2O3, with different RE elements causing different enhancement effects. Transmission electron microscopy elemental mapping shows a homogeneous distribution of RE elements on the whole nanotube. Analysis of the gas-sensing mechanism shows that RE doping modifies the oxygen species adsorbed on the sensor surface. Our findings promote the development of new dopant-based metal oxide semiconductors for high-performance gas sensing.
中文翻译:
稀土掺杂剂对具有大量氧空位的1D In 2 O 3纳米管进行功能化,用于超高灵敏度乙醇检测
在此,通过简便的一步骤电纺丝法合成了掺杂有原始氧化铟(In 2 O 3)和稀土元素(Ce,Tm,Eu,Er和Tb)的In 2 O 3纳米管。稀土(RE)掺杂会增加表面上的活性位点数量,从而增强In 2 O 3的电响应和气敏性能,不同的RE元素会产生不同的增强效果。透射电子显微镜的元素图谱显示RE元素在整个纳米管上的均匀分布。对气体传感机制的分析表明,稀土元素掺杂会改变吸附在传感器表面的氧种类。我们的发现促进了用于高性能气体传感的新型基于掺杂剂的金属氧化物半导体的开发。