Separation and Purification Technology ( IF 8.1 ) Pub Date : 2020-05-21 , DOI: 10.1016/j.seppur.2020.116954 Ridha Djellabi , Jafar Ali , Bo Yang , Muhammad Rizwan Haider , Peidong Su , Claudia L. Bianchi , Xu Zhao
In this study, we report the synthesis of magnetic electron-rich CP@Fe3O4 (Conjugated Polymer (CP) = TCTA-PVP-bipyridine) by hydrothermal method. For this aim, the Fe3O4 nanoparticles were incorporated into photoactive TCTA-PVP-bipyridine based Conjugated Polymer. The photo-redox abilities of CP@Fe3O4 and bare CP were tested for oxidation of methylene blue and reduction of Cr(VI) under UV–visible light and visible light (λ > 420 nm). The CP@Fe3O4 showed a good ability for performing the Fenton-like reaction by adding H2O2 as oxidizing agent. Additionally, reveals high photocatalytic reduction ability of Cr(VI) for CP@Fe3O4 in compare with bare CP. Furthermore the photocatalytic antibacterial ability of CP@Fe3O4 towards E. coli and Pseudomonas Aerogenosa in water was studied. The obtained CFU reduction efficiencies were found about 85% and 90% for E. coli and P. Aeruginosa, respectively. Interestingly the collecting and recyclability of CP@Fe3O4 after photocatalytic reactions were done easily due to its magnetic property.
中文翻译:
磁性可回收的富电子的TCTA @ PVP基共轭聚合物的合成,用于光催化水的修复和消毒
在这项研究中,我们报告了通过水热法合成富磁性电子CP @ Fe 3 O 4(共轭聚合物(CP)= TCTA-PVP-联吡啶)。为此目的,将Fe 3 O 4纳米颗粒掺入光敏TCTA-PVP-联吡啶基共轭聚合物中。在紫外可见光和可见光(λ> 420 nm)下,测试了CP @ Fe 3 O 4和裸CP的光氧化还原能力,用于亚甲基蓝的氧化和Cr(VI)的还原。CP @ Fe 3 O 4通过添加H 2 O 2表现出良好的芬顿样反应能力。作为氧化剂。另外,与裸CP相比,揭示了Cr(VI)对CP @ Fe 3 O 4的高光催化还原能力。此外,研究了CP @ Fe 3 O 4在水中对大肠杆菌和绿脓杆菌的光催化抗菌能力。对于大肠杆菌和铜绿假单胞菌,发现获得的CFU降低效率分别为约85%和90%。有趣的是,由于CP @ Fe 3 O 4的磁性,其光催化反应后的收集和再循环性很容易实现。