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A novel N–N bond cleavage in 1,5-diaminotetrazole: synthesis and characterization of 5-picrylamino-1,2,3,4-tetrazole (PAT)†
Journal of Materials Chemistry A ( IF 10.7 ) Pub Date : 2014-01-10 00:00:00 , DOI: 10.1039/c3ta14485b
Yongxing Tang , Hongwei Yang , Xuehai Ju , Hui Huang , Chunxu Lu , Guangbin Cheng

The reaction of 1,5-diaminotetrazole with picryl chloride (PiCl) forms 5-picrylamino-1,2,3,4-tetrazole (PAT) rather than the expected 1-picrylamino-5-amino-1,2,3,4-tetrazole or 5-picrylamino-1-amino-1,2,3,4-tetrazole. The structure of PAT was confirmed by single-crystal X-ray diffraction. Some of the energetic properties of the synthesized compound were also studied.

中文翻译:

1,5-二氨基四唑中的新型N–N键裂解:5-吡啶甲基-1,2,3,4-四唑(PAT)的合成与表征

1,5-二氨基四唑与甲基吡啶氯化物(PiCl)的反应形成了5-picrylamino-1,2,3,4-tetrazole(PAT),而不是预期的1-picrylamino-5-amino-1,2,3,4 -四唑或5-吡啶甲基-1-氨基-1,2,3,4-四唑。通过单晶X射线衍射确认了PAT的结构。还研究了合成化合物的一些能量性质。
更新日期:2014-01-10
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