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姚勇,男,博士,1986年10月生,江苏溧阳人。江苏省特聘教授,江苏省六大人才高峰高层次人才,南通市优秀科技工作者,江苏省科协青年托举人才,中国化学会高级会员,全球前2%影响力科学家。2011年硕士毕业于扬州大学化学化工学院有机化学专业,师从颜朝国教授;2015年博士毕业于浙江大学化学系,师从长江学者特聘教授,国家杰青黄飞鹤教授, 博士期间获得多次国家奖学金以及浙江省化学会创新奖等荣誉。2015-2017在美国犹他大学从事博士后研究,合作导师Peter. J. Stang教授。2017年底全职加入南通大学化学化工学院。迄今以第一作者和通讯作者论文100余篇,其中包括JCR化学类一区50余篇,总引用超过5300次,单篇被引用最高367次。主持国家自然科学基金、江苏省自然科学基金等。
一作及通讯论文:
1. Yao, Y.; Xue, M.; Chen, J.; Zhang, M.; Huang, F.* “An Amphiphilic Pillar[5]arene: Synthesis, Controllable Self-Assembly in Water, and Application in Calcein Release and TNT Adsorption” J. Am. Chem. Soc. 2012, 134, 15712−15715.
2. Yao, Y.; Xue, M.; Chi, X.; Ma, Y.; He, J.; Abliz, Z.; Huang, F.* “A new water-soluble pillar[5]arene: synthesis and application in the preparation of gold nanoparticles” Chem. Commun. 2012, 48, 6505–6507.
3. Yao, Y.; Xue, M.; Zhang, Z.; Zhang, M.; Wang, Y.; Huang, F.* “Gold nanoparticles stabilized by an amphiphilic pillar[5]arene: preparation, self-assembly into composite microtubes in water and application in green catalysis” Chem. Sci. 2013, 4, 3667–3672.
4. Yao, Y.; Wang, Y.; Huang, F.* “Synthesis of various supramolecular hybrid nanostructures based on pillar[6]arene modified gold nanoparticles/nanorods and their application in pH- and NIR-triggered controlled release” Chem. Sci. 2014, 5, 4312-4316.
5. Yao, Y.; Chi, X.; Zhou, Y.; Huang, F.* “A bola-type supra-amphiphile constructed from a water-soluble pillar[5]arene and a rod–coil molecule for dual fluorescent sensing” Chem. Sci. 2014, 4, 2778–2782.
6. Yao, Y.; Zhou, Y.; Dai, J.; Yue, S.; Xue, M.* “Host–guest recognition-induced color change of water-soluble pillar[5]arene modified silver nanoparticles for visual detection of spermine analogues” Chem. Commun. 2014, 50, 869–871.
7. Yao, Y.; Jie, K.; Zhou, Y.; Xue, M.* “Reversible assembly of silver nanoparticles driven by host–guest interactions based on water-soluble pillar[n]arenes” Chem. Commun. 2014, 50, 5072–5074.
8. Yao, Y.; Wei, P.; Yue, S.; Li, J.; Xue, M.* “Amphiphilic pillar[5]arenes: influence of chemical structure on self-assembly morphology and application in gas response and λ-DNA condensation” RSC Adv. 2014, 4, 6042-6047.
9. Yao, Y.; Li, J.; Dai, J.; Chi, X.; Xue, M.* “A water-soluble pillar[6]arene: synthesis, host–guest chemistry, controllable self-assembly, and application in controlled release” RSC Adv. 2014, 4, 9039-9043.
10. Yao, Y.; Jie, K.; Zhou, Y.; Xue, M.* “Water-soluble pillar[6]arene stabilized silver nanoparticles: preparation and application in amino acid detection” Tetrahedron Lett. 2014, 55, 3195-3199.
11. Yao, Y.; Sun, Y.; Han, Y.; Yan, C.-G.* “Preparation of resorcinarene-functionalized gold nanoparticles and their catalytic activities for reduction of aromatic nitro compounds” Chin. J. Chem., 2010, 28, 705-712.
12. Zhou, Y.; Yao, Y.*; Xue, M. “Well-defined nano-sunflowers formed by self-assembly of a rod-coil amphiphile in water and their morphology transformation based on a water-soluble pillar[5]arene” Chem. Commun. 2014, 50, 8040-8042.
13. Zhou, Y.; Li, Z.; Chi, X.; Thompson, C.; Yao, Y.* “Formation of a [2]pseudorotaxane based on a pillar[5]arene and a rigid guest in solution and in the solid state” Chem. Commun. 2014, 50, 10482-10484.
14. Shi, B.; Xia, D.; Yao, Y.* “A water-soluble supramolecular polymer constructed by pillar[5]arene-based molecular recognition” Chem. Commun. 2014, 50, 13932-13935.
15. Yue, S.; Zhou, Y.; Yao, Y.;* Xue, M,* “Pillar[n]arenes: From Synthesis, Host-Guest Chemistry to Self-Assembly Properties and Applications” Acta Chim. Sinica. 2014, 72, 1053-1069.
16. Zhou, Y.; Jie, K.; Shi, B.; Yao, Y.* “A γ-ray and dual redox-responsive supramolecular polymer constructed by a selenium containing pillar[5]arene dimer and a neutral guest” Chem. Commun., 2015, 51, 11112-11114.
17. Jie, K.; Zhou, Y.; Shi, B.; Yao, Y.* “A Cu2+ specific metallohydrogel: preparation, multi-responsiveness and pillar[5]arene-induced morphology transformation” Chem. Commun., 2015, 51, 8461-8464.
18. Shi, B.; Jie, K.; Zhou, Y.; Xia, D.; Yao, Y.* “Formation of fluorescent supramolecular polymeric assemblies via orthogonal pillar[5]arene-based molecular recognition and metal ion coordination” Chem. Commun., 2015, 51, 4503-4506.
19. Zhou, Y.; Jie, K.; Thompson, C.; Yao, Y.* “An Ag2O-responsive [2]pseudorotaxane based on the pillar[5]arene/bis(imidazolium) dication molecular recognition motif” Tetrahedron Letters, 2015, 16, 2091–2093.
20. Yao, Y.; Wang, Y.; Zhao, R.; Shao, L.; Tang, R.*; Huang, F.* “Improved in vivo tumor therapy via host-guest complexation” J. Mater. Chem. B, 2016, 4, 2691-2696.
21. Xia, D.; Li, Y.; Jie, K.; Shi, B.; Yao, Y.* “A Water-Soluble Cyclotriveratrylene-Based Supra-amphiphile: Synthesis, pH-Responsive Self-Assembly in Water, and Its Application in Controlled Drug Release” Org. Lett., 2016, 18, 2910-2913.
22. Xu. H.; Yao, Y.* “Supramolecular amphiphilies based on water-soluble pillar[5]arene/paraquat derivatives and their self-assembly behaviour in water” Supramolecular Chemistry 2017, 3, 161-166.
23. Sun. Y.*; Wang, J.; Yao, Y.* “First water-soluble pillar[5]arene dimer: synthesis and construction of a reversible fluorescent supramolecular polymer network in water” Chem. Commun., 2017, 53,165-167.
24. Zhou. Y.; Jie, K.; Yao, Y.* “A cavity extended water-soluble resorcin[4]arene: synthesis, pH-controlled complexation with paraquat, and application in controllable self-assembly” New J. Chem., 2017, 41, 916-919.
25. Sun, Y.*; Fu, W.; Chen, C.; Wang, J.; Yao, Y.* “Water-soluble pillar[5]arene induced the morphology transformation of self-assembled nanostructures and further application in paraquat detection” Chem. Commun., 2017, 53,3725-3728.
26. Yao, Y.*; Sun, Y.; Yu, H.; Chen, W.; Dai, H.; Shi, Y.* “A pillar[5]arene based gel from a low-molecular-weight gelator for sustained dye release in water” Dalton Trans., 2017, 46, 16802-16806.
27. Yao, Y.*; Wei, X.; Chen, J.; Dai, H.; Shi, Y. “Amphiphilic pillar[n]arenes” Supramolecular Chemistry 2018, 7, 610-618.
28. Yao, Y.*; Wei, X.; Cai, Y.; Kong, X.; Chen, J.; Wu, J.; Shi, Y. “Hybrid supramolecular materials constructed from pillar[5]arene based host-guest interactions with photo and redox tunable properties” J. Colloid. Interf. Sci., 2018, 525, 48-53.
29. Yao, Y.*; Zhao, R.; Shi, Y.; Cai, Y.; Chen, J.; Sun, S.; Zhang, W.*; Tang, R.* “2D amphiphilic organoplatinum(II) metallacycles: syntheses, self-assembly in water and their potential application in photodynamic therapy”, Chem. Commun., 2018, 54, 8068-8071.
30. Zhou, J.; Dai, H.*; Qian, H.; Du, X.; Mao, X.; Shi, Y.*; Feng, H.; Shi, J.; Yao, Y.* “Synthesis and Biological Activity of New Cyanoacrylate Compounds Bearing Oxazole Moiety”, Chin. J. Org. Chem., 2018, 38, 2122-2129.
31. Sun, Y.*#; Yao, Y.#; Wang, H.; Fu, W.; Chen, C.; Sasa, M. L.; Zhang, M.; Datta, S.; Zhou, Z.; Yu, H.; Li, X.; Stang, P. J.* “Self-Assembly of Metallacages into Multidimensional Suprastructures with Tunable Emissions”, J. Am. Chem. Soc., 2018, 140, 12819−12828. (共一).
32. Sun, S.; Geng, M.; Huang, L.; Chen, Y.; Cen, M.; Lu, D.; Wang, A.; Wang, Y.;* Shi, Y.;* Yao, Y.* “A new amphiphilic pillar[5]arene: synthesis, controllable selfassembly in water and application in white-light-emitting system ” Chem. Commun., 2018, 54, 13006-13009.
33. Chen, Y.; Sun, S.; Lu, D.; Shi, Y.;* Yao, Y.;* “Water-soluble supramolecular polymers constructed by macrocycle-based host-guest interactions” Chin. Chem. Lett., 2019, 30, 37-43.
34. Sun, S.; Lu, D.; Huang, Q.; Liu, Q.; Yao, Y.*; Shi, Y.* “Reversible surface activity and self-assembly behavior and transformation of amphiphilic ionic liquids in water induced by a pillar[5]arene-based host-guest interaction”, J. Colloid. Interf. Sci., 2019, 533, 42-46.
35. Wang, Y.; Wang, C.; Long, R.; Cao, Y.; Fan, D.; Cen, M.; Cao, L.; Chen, Y.; Yao, Y.* “Synthesis and controllable self-assembly of 3D amphiphilic organoplatinum (II) metallacages in water”, Chem. Comm., 2019, 55, 5167-5170.
36. Dai, H.; Huang, M.; Qian, J.; Liu, J.; Meng, C.; Li, Y.; Ming, G.; Zhang, T.; Wang, S.; Shi, Y.; Yao, Y.*; Ge, S.; Zhang, Y.; Ling, Y. “Excellent antitumor and antimetastatic activities based on novel coumarin/pyrazole hybrids” European Journal of Medicinal Chemistry, 2019, 166, 470-479.
37. Wang, Y.; Liu, T.; Jiang, J.; Chen, Y.; Cen, M.; Lu, D.; Cao, L.; Sun, S.; Yao, Y.* “Syntheses of water soluble acyclic naphthalene oligomers and their application in water”, Dalton Trans., 2019, DOI: 10.1039/C9DT00709A
其他论文:
38. Yu, G.; Zhang, M.; Saha, M. L.; Mao, Z.; Chen, J.; Yao, Y.; Zhou, Z.; Liu, Y.; Gao, C.; Huang, F.*; Chen, X.*; Stang, P. J.* “Antitumor Activity of a Unique Polymer That Incorporates a Fluorescent Self-Assembled Metallacycle” J. Am. Chem. Soc., 2017, 139, 15940–15949.
39. Jie, K.; Zhou, Y.; Yao, Y.; Huang, F.* “Macrocyclic amphiphiles” Chem. Soc. Rev., 2015, 44, 3568-3587.
40. Jie, K.; Zhou, Y.; Yao, Y.; Shi, B.; Huang, F.* “CO2-Responsive Pillar[5]arene-Based Molecular Recognition in Water: Establishment and Application in Gas-Controlled Self-Assembly and Release” J. Am. Chem. Soc., 2015, 137, 10472–10475.
41. Ji, X.; Yao, Y.; Li, J.; Yan, X.; Huang, F.* “A Supramolecular Cross-Linked Conjugated Polymer Network for Multiple Fluorescent Sensing” J. Am. Chem. Soc., 2013, 135, 74–77.
42. Yu, G.; Ma, Y.; Han, C.; Yao, Y.; Tang, G.; Ma, Z.; Gao, C.; Huang, F.* “A Sugar-Functionalized Amphiphilic Pillar[5]arene: Synthesis, Self-Assembly in Water, and Application in Bacterial Cell Agglutination” J. Am. Chem. Soc., 2013, 135, 10310–10313.
43. Yan, X.; Li, S.; Cook, T. R.; Ji, X.; Yao, Y.; Pollock, J. B.; Shi, Y.; Yu, G.; Li, J.; Huang, F.*; Stang, P. J.* “Hierarchical Self-Assembly: Well-Defined Supramolecular Nanostructures and Metallohydrogels via Amphiphilic Discrete Organoplatinum(II) Metallacycles” J. Am. Chem. Soc., 2013, 135 , 14036–14039.
44. Dong, S.; Zheng, B.; Yao, Y.; Han, C.; Yuan, J.* “LCST-Type Phase Behavior Induced by Pillar[5]arene/Ionic Liquid Host–Guest Complexation” Adv. Mater. 2013, 25, 6864–6867.
45. Li, L.; Yao, Y.; Sun, J.; Yan, C.-G.* “Preparation and application of tubular assemblies based on amphiphilic tetramethoxyresorcinarenes” RSC Adv., 2015, 5, 102454-102461.
46. Zhou, Y.; Yao, Y.; Huang, F.* “Four pillar[5]arene constitutional isomers: Synthesis, crystal structures, and host-guest complexation of their derivatives with paraquat in water” Chin. J. Chem., 2015, 33, 356-360.
47. Gao, L.; Yao, Y.; dong, S.; Yuan, J.* “Host–guest complexation between 1,4-dipropoxypillar[5]arene and imidazolium-based ionic liquids” RSC Adv., 2014, 4, 35489-35492.
48. Jie, K.; Yao, Y.; Chi, X.; Huang, F.* “A CO2-responsive pillar[5]arene: synthesis and self-assembly in water” Chem. Commun., 2014, 50, 5503-5505.
49. Yu, G.*; Yang, J.; Xia, D.; Yao, Y. “An enzyme-responsive supra-amphiphile constructed by pillar[5]arene/acetylcholine molecular recognition” RSC Adv., 2014, 4, 18763-18771.
50. Wang, P.; Yao, Y.; Xue, M. “A novel fluorescent probe for detecting paraquat and cyanide in water based on pillar[5]arene/10-methylacridinium iodide molecular” Chem. Commun., 2014, 50, 5064-5067.
51. Sun, J.; Zhang, L.-L.; Yao, Y.; Yan, C.-G.* “Synthesis, crystal structures and complexing properties of tetramethoxyresorcinarene functionalized tetraacylhydrazones” J. Incl. Phenom. Macro., 2014, 79, 485-494.
52. Gao, L.; Zheng, B.; Yao, Y.; Huang, F.* “Responsive reverse giant vesicles and gel from self-organization of a bolaamphiphilic pillar[5]arene” Soft Matter, 2013, 9, 7314-7319.
53. Chi, X.; Xue, M.; Yao, Y.; Huang, F.* “Redox-Responsive Complexation between a Pillar[5]arene with Mono(ethylene oxide) Substituents and Paraquat” Org. Lett., 2013, 15, 4722–4725.
54. Ma, Y.; Chi, X.; Yan, X.; Liu, J.; Yao, Y.; Chen, W.; Huang, F.*; Hou, J.-L.* “per-Hydroxylated Pillar[6]arene: Synthesis, X-ray Crystal Structure, and Host–Guest Complexation” Org. Lett., 2012, 14 , 1532–1535.
55. Sun, Y.; Yao, Y.; Yan, C.-G.*; Han, Y.; Shen, M.* “Selective Decoration of Metal Nanoparticles inside or outside of Organic Microstructures via Self-Assembly of Resorcinarene” ACS Nano, 2010, 4, 2129–2141.
56. Sun, Y.; Yan, C.-G.*; Yao, Y.; Han, Y.; Shen, M. * “Self-assembly and metallization of resorcinarene microtubes in water” Adv. Funct. Mater., 2008, 18, 3981-3990.
57. Yan, C.-G.*; Chen, W.; Chen, J.; Jiang, T.; Yao, Y. “Microwave irradiation assisted synthesis, alkylation reaction, and configuration analysis of aryl pyrogallol[4]arenes” Tetrahedron, 2007, 63, 9614-9620.