![](https://xpic.x-mol.com/20200509%2F1589016737642.jpg)
研究方向:过渡金属配合物设计及催化性能,烯烃、极性单体可控聚合,生物基高分子合成,小分子活化
联系方式:chguyao@163.com
教育与工作背景
2020/05 至今:南昌大学化学化工学院副教授
2015/12–2019/12:博士后,King Abdullah University of Science and Technology,
金属有机化学(合作导师:Kuo-Wei Huang 教授)
2009/09–2015/07:硕博连读,中国科学院长春应用化学研究所,高分子物理与化学国家重点实验室,高分子化学(导师:崔冬梅 研究员)
2005/09–2009/07:本科,陕西师范大学,材料化学
代表性论文:
1. Changguang Yao, Xiufang Wang and Kuo-Wei Huang*. “Nitrogen Atom Transfer Mediated by a New PN3P-Pincer Nickel Core via a Putative Nitrido Nickel Intermediate” Chem. Commun. 2018,54, 3940–3943.
2. Changguang Yao, Fei Lin, Meiyan Wang, Dongtao Liu, Bo Liu, Na Liu, Zichuan Wang, Shiyu Long, Chunji Wu* and Dongmei Cui*. “Highly Syndioselective 3,4-Trans Polymerization of (E)-1-(4-Methylphenyl)-1,3-butadiene by Fluorenyl N-Heterocyclic Carbene Ligated Lutetium Bis(alkyl) Precursor” Macromolecules 2015, 48, 1999–2005. 3. Changguang Yao, Na Liu, Shiyu Long, Chunji Wu and Dongmei Cui*. “Highly cis-1,4-Selective Coordination Polymerization of Polar 2-(4-Methoxyphenyl)-1,3-Butadiene and Copolymerization with Isoprene Using a β-Diketiminato Yttrium Bis(alkyl) Complex” Polym. Chem. 2016, 7, 1264–1270.
4. Changguang Yao, Priyanka Chakraborty, Emanuele Aresu, Huaifeng Li, Chao Guan, Chunhui Zhou, Lan-Chang Liang* and Kuo-Wei Huang*. “Monomeric Nickel Hydroxide Stabilized by a Sterically Demanding Phosphorus-Nitrogen PN3P-pincer Ligand: Synthesis, Reactivity and Catalysis”. Dalton Trans., 2018, 47, 16057–16065.
5. Changguang Yao, Tonghuan Zhang, Chunhui Zhou and Kuo-Wei Huang*. “Interrogating the Steric Outcome During H2 Heterolysis: In-Plane Steric Effects in the Regioselective Protonation of the PN3P-Pincer Ligand” Dalton Trans., 2019, 48, 12817–12821.
6. Changguang Yao, Dongtao Liu, Ping Li, Chunji Wu, Shihui Li, Bo Liu and Dongmei Cui*. “Highly 3,4-Selective Living Polymerization of Isoprene and Copolymerization with ε-Caprolactone by an Amidino N-heterocyclic Carbene Ligated Lutetium Bis(alkyl) Complex” Organometallics 2014, 33, 684–691.
7. Changguang Yao, Chunji Wu, Baoli Wang and Dongmei Cui*. “Copolymerization of Ethylene with 1-Hexene and 1-Octene Catalyzed by Fluorenyl N-Heterocyclic Carbene Ligated Rare-Earth Metal Precursors” Organometallics 2013, 32, 2204–2209. 8. Changguang Yao, Hongyan Xie and Dongmei Cui*. “Highly 3,4-Selective Living Polymerization of 2-Phenyl-1,3-Butadiene with Amidino N-Heterocyclic Carbene Ligated Rare-Earth Metal Bis(alkyl) Complexes” RSC Adv. 2015, 5, 93507–93512.
9. Dongtao Liu, Changguang Yao, Rong Wang, Meiyan Wang, Zichuan Wang, Chunji Wu, Fei Lin, Shihui Li, Xinhua Wan and Dongmei Cui*. “Highly Isoselective Coordination Polymerization of ortho-Methoxystyrene with β-Diketiminato Rare-Earth-Metal Precursors” Angew. Chem. Int. Ed. 2015, 54, 5205–5209.
10. Zhaohe Liu, Changguang Yao, Chunji Wu, Zhongfu Zhao* and Dongmei Cui*. “Additive-Triggered Chain Transfer to a Solvent in Coordination Polymerization” Macromolecules 2020, 53, 1205–1211.
申请专利:
1. 崔冬梅*,姚昌广,吴春姬,刘波,亚历山大·特里弗诺夫:稀土催化剂组合及其用于异戊二烯类化合物的3, 4-聚合(ZL 2013 1 0689037.5)
2. 崔冬梅*,姚昌广,吴春姬,刘波: 2-芳基-1, 3丁二烯3, 4-聚合物及其制备方法(ZL 2015 1 0224201.4)
3. 崔冬梅*,姚昌广,刘东涛,吴春姬: 2-芳基-1, 3丁二烯顺-1, 4-聚合物及其制备方法(ZL 2015 1 0224184.4)
4. 崔冬梅*,吴春姬,姚昌广: 茂金属配合物及其制备方法、催化剂组合物(ZL 2013 1 0478190.3, US 9896519 B2, EP 3056505 B1, JP 6302565 B2)