个人简介

郑汉良，博士，硕士生导师，浙江师范大学“双龙学者”特聘教授

通讯地址：浙江省金华市迎宾大道688号浙江师范大学生化学院

邮箱：hanliang@zjnu.edu.cn

主要经历：

2021.08 – 至今：浙江师范大学，“双龙学者”特聘教授

2016.09 – 2021.06：南开大学，元素有机国家重点实验室，有机化学专业，博士研究生，导师：程津培院士，薛小松研究员

2012.09 – 2016.06：浙江师范大学，初阳学院，化学专业，理学学士

研究方向：

（1）物理有机化学。以实验与计算结合的手段探究反应机理与重要试剂的构效关系，揭示重要有机反应中影响反应性与选择性的关键因素，为理性设计反应与催化剂提供理论依据。

（2）计算有机化学。采用高精度量子化学计算方法深入探索有机催化反应机理，剖析控制反应选择性起源的因素，为合理解释实验现象和理性设计新反应与新催化剂提供理论支持。

代表性论文：

1. Hanliang Zheng, Zhen Li, Jianfang Jing, Xiao-Song Xue,* and Jin-Pei Cheng, The Acidities of Nucleophilic Monofluoromethylation Reagents: An Anomalous ‐Fluorine Effect. Angew. Chem. Int. Ed.2021,60, 9401-9406. (Very Important Paper)

2. Hanliang Zheng, Yueqian Sang, K. N. Houk,* Xiao-Song Xue,* and Jin-Pei Cheng, Mechanism and Origins of Enantioselectivities in Spirobiindane-Based Hypervalent Iodine(III)-Induced Asymmetric Dearomatizing Spirolactonizations. J. Am. Chem. Soc.2019, 141, 40, 16046–16056.

3. Hanliang Zheng and Xiao-Song Xue,*Recent Computational Studies on Mechanisms of Hypervalent Iodine(III)-Promoted Dearomatization of Phenols. Curr. Org. Chem.,2020, 24, 2106-2117. (Invited contribution)

4. Haiqian Zhu,^§Hanliang Zheng,^§ Junhua Zhang,^§ Jian Feng, Lichun Kong, Fang Zhang, Xiao-Song Xue* and Gangguo Zhu,* Chem. Sci., 2021, 12, 11420-11426.

5. Chenyun Shu,^§ Jian Feng,^§Hanliang Zheng,^§ Cungui Cheng, Zheliang Yuan, Zuxiao Zhang,Xiao-Song Xue, and Gangguo Zhu,*Internal Alkyne-Directed Fluorination of Unactivated C(sp³)–H Bonds. Org. Lett.2020, 22, 9398−9403.

6. Yu-Liang Pan, Han-Liang Zheng, Jie Wang, Chen Yang, Xin Li,* and Jin-Pei Cheng,Enantioselective Allylation of Oxocarbenium Ions Catalyzed by Bi(OAc)₃/Chiral Phosphoric Acid. ACS Catal. 2020, 10, 8069–8076.

7. Guo-Hui Yang, Hanliang Zheng, Xin Li,* and Jin-Pei Cheng, Asymmetric Synthesis of Axially Chiral Phosphamides via Atroposelective N-Allylic Alkylation. ACS Catal. 2020, 10, 15, 2324–2333.

8. Feng Shen, Hanliang Zheng, Xiao-Song Xue, Long Lu,* and Qilong Shen,* Transition-Metal-Free ipso-Trifluoromethylthiolation of Lithium Aryl Boronates. Org. Lett. 2019, 21, 6347−6351.

9. Wei Zhang, Han-Liang Zheng, Yang Liu, Ao Yu, Chen Yang,* Xin Li,* and Jin-Pei Cheng, Catalyst-free Amination of α-Cyanoarylacetates Enabled by Single-Electron Transfer. Org. Chem. Front., 2019, 6, 1900–1904.

10. Jiansheng Zhu, Hanliang Zheng, Xiao-Song Xue,* Yisa Xiao, Yafei Liu and Qilong Shen,* Carbon-Selective Difluoromethylation of Soft Carbon Nucleophiles with Difluoromethylated Sulfonium Ylide. Chin. J. Chem., 2018, 36, 1069-1074.