2020年10月，熊克才盖艳丽课题组在Journal of Cluster Science上发表题为“Two Novel Titanium(IV)-based Compounds Supported by Thiacalix[4]arene: Syntheses, Structures and Photocatalytic Properties”的研究论文，该工作为开发新型基于杯芳烃的钛氧簇合物用于有机染料分子亚甲基蓝的光催化降解提供了有益的借鉴。2017级研究生赵雪艳、2017级本科生朱怡为论文共同第一作者。
Two new titanium(IV)-based compounds supported by p-tert-butylthiacalix[4]arene have been synthesized and characterized, in which p-tert-butylthiacalix[4]arenes display the cone conformation and 1,2-alternate conformation, respectively. Interestingly, compounds 1 and 2 display much higher and more efficient photocatalytic degradation ability for methylene blue than TiO2 under visible light irradiation.
Xue-Yan Zhao#, Yi Zhu#, Chun-Xue Zhuo, Yan-Li Gai, Miao Wu, Wen-Shu Zhang, Yu-Die Zhou, Rui-Ting Wen, Ke-Cai Xiong* Two Novel Titanium(IV)-based Compounds Supported by Thiacalix[4]arene: Syntheses, Structures and Photocatalytic Properties, Journal of Cluster Science 2020, https://doi.org/10.1007/s10876-020-01875-8.
论文链接：http://link.springer.com/article/10.1007/s10876-020-01875-8