Boron nitride (BN) has gradually emerged as a significant focus of research field due to its unique physical and chemical properties. Over the past few years, substantial advancements have been achieved in the domains of gas adsorption and sensing, driven by improvements in modification technology and a deeper understanding of gas sensing mechanisms. BN-based nanomaterials have been instrumental in these advancements. The application of some properties of BN in the fabrication of gas sensing components is anticipated to lead to new breakthrough. Furthermore, BN is projected to become one of the most promising materials for high-performance gas sensors, owing to its high thermal stability, chemical stability, and exceptional mechanical properties. While numerous review articles have been released regarding BN, primarily focusing on its synthesis, properties, and functionalities, few have made significant contributions to the realm of gas adsorption and detection through theoretical calculations and practical applications. This review comprehensively examines the integration of BN with various gas adsorption and sensing techniques, covering aspects such as model development, theoretical computations, material synthesis, and real-world applications. These methods provide valuable insights into the potential of BN for gas sensing applications. Furthermore, the paper discusses the challenges encountered in utilizing BN-based gas sensors and offers recommendations for overcoming these challenges. Finally, the future prospects for the advancement of BN-based gas sensors are considered, highlighting new possibilities and areas for improvement within this field.