19992
当前位置: 首页   >  组员介绍   >  陈庆安
陈庆安 研究员,博士生导师    


  陈庆安,福建泉州人。2007年本科毕业于中国科学技术大学化学系,导师尤田耙教授。2012年在中国科学院大连化学物理研究所获得博士学位,导师周永贵研究员。2012年至2015年在美国加州大学欧文分校进行博士后研究,合作导师Vy M.Dong教授。2015年至2017年作为德国洪堡学者在德国柏林工业大学Martin Oestreich教授研究组开展博士后研究工作。2017年加入大连化物所开展独立研究工作,任研究组组长。国家专项引进青年人才(2017)、大连化物所张大煜青年学者。

 自开展研究工作以来,先后在Chem.  Rev.,Chem. Soc. Rev.,J.  Am. Chem. Soc., Angew.  Chem. Int. Ed. 等国际权威期刊上发表文章70余篇,总引用次数为3500余次,平均引用50余次(截止2023年9月)。此外还受邀担任J.  Am. Chem. Soc.,Chem.  Sci.,Chem. Commun. 等国际知名学术期刊的独立审稿人。2017年获得辽宁省自然科学一等奖(排名第二),2020年获得“Thieme  Chemistry Journal Award”国际学术奖。目前主要研究领域为仿生催化合成和金属有机化学。


Representative Publications:   

30. Ying Li, Wei-Song Zhang,  Sa-Na Yang, Xiao-Yu Wang, Yan Liu, Ding-Wei Ji,* and Qing-An Chen.*  Nickel-Catalyzed Unsymmetrical Bis-Allylation of Alkynes. Angew. Chem. Int. Ed. 2023, 62, e200300036.

29. Wei-Song Zhang,  Ding-Wei Ji, Ying Li, Xiang-Xin Zhang, Yong-Kang Mei, Bing-Zhi Chen, Qing-An Chen.*  Nickel-catalyzed divergent Mizoroki–Heck reaction of 1,3-dienes. Nature Communications 202314, 651.

28. Ding-Wei Ji, Yan-Cheng Hu,  Xiang-Ting Min, Heng Liu, Wei-Song Zhang, Ying Li, Yongjin J. Zhou,and Qing-An Chen.*  Skeleton-Reorganizing Coupling Reactions of Cyclohepta-triene and Cycloalkenones with Amines. Angew. Chem. Int. Ed. 2023, 62, e202213074.

27. Gong Zhang, Chao-Yang Zhao,  Xiang-Ting Min, Ying Li, Xiang-Xin Zhang, Heng Liu,Ding-Wei Ji, Yan-Cheng Hu, Qing-An Chen.*  Nickel-Catalysed Asymmetric Heteroarylative Cyclotelomerization of Isoprene. Nature Catalysis 20225, 708-715.

26. Xiang-Ting Min, Yong-Kang Mei,  Bing-Zhi Chen, Li-Bowen He, Ting-Ting Song, Ding-Wei Ji,Yan-Cheng Hu, Boshun Wan, Qing-An Chen.*  Rhodium-Catalyzed Deuterated Tsuji-Wilkinson Decarbonylation of Aldehydes with Deuterium Oxide. J. Am. Chem. Soc. 2022144, 11081-11087.

25. Chao-Yang Zhao, Ying-Ying Liu,  Xiang-Xin Zhang, Gu-Cheng He, Heng Liu, Ding-Wei Ji,Yan-Cheng Hu, Qing-An Chen.*  Bioinspired and Ligand-Regulated Unnatural Prenylation and Geranylation of Oxindoles with Isoprene under Pd Catalysis. Angew. Chem. Int. Ed. 202261, e202207202.

24. Xin Huang,† Bing-Zhi Chen,  Pengbin Li, Ding-Wei Ji, Jinxian Liu, Hao Zheng, Sa-Na Yang, Yan-Cheng Hu, Boshun Wan, Xiang-Ping Hu, Chunling Fu, Yankai Huang, Jian Zheng,* Qing-An Chen,* Shengming Ma.*  Palladium-catalyzed construction of butafulvenes. Nature Chemistry 202214, 1185-1192.

23. Hao Zheng,  Chang-Hui Liu, Shi-Yu Guo, Gu-Cheng He, Xiang-Ting Min, Bo-Chao Zhou, Ding-Wei Ji, Yan-Cheng Hu, Qing-An Chen.*  Regioselective C−H Phosphorylation of Group 8 Metallocenes under Electrochemical Autocatalysis. Nature Communications 202213, 3496.

22. Yan-Cheng Hu,  Xiang-Ting Min, Ding-Wei Ji, Qing-An Chen.*  Catalytic Prenylation and Reverse-Prenylation of Aromatics. Trends in Chemistry 20224, 658-675.

21. Gu-Cheng He,  Shi-Yu Guo, Hao Zheng, Chang-Hui Liu, Ying Li, Xiang-Ting Min, Ding-Wei Ji and Qing-An Chen.*  Photo-Induced Catalytic C−H Heteroarylation of Group 8 Metallocenes. Cell Rep. Phys. Sci. 20223, 100768.

20. Wei-Song Zhang,  Ding-Wei Ji, Ying Li, Xiang-Xin Zhang, Chao-Yang Zhao, Yan-Cheng Hu and Qing-An Chen.*  Regio- and Stereoselective Diarylation of 1,3-Dienes via Ni/Cr Co-catalysis. ACS Catal. 202212, 2158-2165.

19. Shi-Yu Guo, Fan Yang, Ting-Ting Song, Yu-Qing Guan, Xiang-Ting Min, Ding-Wei Ji, Yan-Cheng Hu and Qing-An Chen.*  Photo-Induced Catalytic Halopyridylation of Alkenes. Nature Communications 202112, 6538.

18. Heng Liu, Gu-Cheng He, Chao-Yang Zhao, Xiang-Xin Zhang, Ding-Wei Ji, Yan-Cheng Hu and Qing-An Chen.*  Redoxdivergent Construction of (Dihydro)thiophenes with DMSO. Angew. Chem. Int. Ed. 202160, 24284-24291.

17. Chao-Yang Zhao, Ding-Wei Ji, Hao Zheng, Gu-Cheng He, Heng Liu, Yan-Cheng Hu, and Qing-An Chen.* Pd-Catalyzed Redox Divergent Coupling of Ketones with Terpenols. ACS Cat. 2021,11, 6825-6834.

16. Wen-Shuang Jiang+, Ding-Wei Ji+, Wei-Song Zhang, Gong Zhang, Xiang-Ting Min, Yan-Cheng Hu, Xu-Liang Jiang*, and Qing-An Chen.* Orthogonal Regulation of Nucleophilic and Electrophilic Sites in Pd-Catalyzed Regiodivergent Couplings between Indazoles and Isoprene. Angew. Chem. Int. Ed. 202160, 8321-8328.

15. Yan-Cheng Hu+, Yingying Zhao+, Boshun Wan*, Qing-An Chen.* Reactivity of Ynamides in Catalytic Intermolecular Annulations. Chem. Soc. Rev. 202150, 2582-2625.

14. Xiang-Ting Min, Ding-Wei Ji, Yu-Qing Guan, Shi-Yu Guo, Yan-Cheng Hu, Boshun Wan, Qing-An Chen* Visible Light-Induced Bifunctional Rhodium Catalysis for Decarbonylative Coupling of Imides with Alkynes. Angew. Chem. Int. Ed. 202160, 1583-1587.

13. Chang-Sheng Kuai+, Ding-Wei Ji+, Chao-Yang Zhao, Heng Liu, Yan-Cheng Hu, Qing-An Chen.* Ligand Regulated Regiodivergent Hydrosilylation of Isoprene under Iron Catalysis. Angew. Chem. Int. Ed. 202059, 19115-19120.

12. Chao-Yang Zhao, Hao Zheng, Ding-Wei Ji, Xiang-Ting Min, Yan-Cheng Hu, and Qing-An Chen.* Copper-Catalyzed Asymmetric Carboboronation of Allenes to Access α-Quaternary Amino Esters with Adjacent Stereocenters. Cell Rep. Phys. Sci. 20201, 100067.

11. Jun Yang, Ding-Wei Ji, Yan-Cheng Hu, Xiang-Ting Min, Xiang-Ge Zhou,* Qing-An Chen.* Cobalt-Catalyzed Hydroxymethylarylation of Terpenes with Formaldehyde and Arenes. Chem. Sci. 201910, 9560-9564.        

10. Ding-Wei Ji, Yan-Cheng Hu, Hao Zheng, Chao-Yang Zhao, Qing-An Chen.* and Vy M. Dong. Catalytic Regioselectivity Switch in Pd-Catalyzed Hydroallylation of Alkynes. Chem. Sci. 201910, 6311-6315.

9. Yan-Cheng Hu, Ding-Wei Ji, Chao-Yang Zhao, Hao Zheng, Qing-An Chen.* Catalytic Prenylation and Reverse-Prenylation of Indoles with Isoprene: Regioselectivity Manipulation by Metal-Hydride. Angew. Chem. Int. Ed. 201958, 5438-5442.

8. Qing-An Chen, Hendrik F. T. Klare, and Martin Oestreich.* Bronsted Acid-Promoted Formation of Stabilized Silylium Ions for Catalytic Friedel-Crafts C-H Silylation. J. Am. Chem. Soc. 2016138, 7868-7871.

7. Qing-An Chen, Zhiwei Chen, Vy M. Dong.* Rhodium-Catalyzed Enantioselective Hydroamination of Alkynes with Indolines. J. Am. Chem. Soc. 2015137, 8392-8395.

6. Qing-An Chen, Faben A. Cruz, Vy M. Dong.* Alkyne Hydroacylation: Switching Regioselectivity by Tandem Ruthenium Catalysis. J. Am. Chem. Soc. 2015137, 3157-3160.

5. Qing-An Chen, Daniel K. Kim, Vy M. Dong.* Regioselective Hydroacylation of 1,3-Dienes by Cobalt-Catalysis. J. Am. Chem. Soc. 2014136, 3772-3775.

4. Qing-An Chen, Zhi-Shi Ye, Ying Duan and Yong-Gui Zhou.* Homogeneous Palladium Catalyzed Asymmetric Hydrogenation. Chem. Soc. Rev. 201342, 497-511.

3. Qing-An Chen, Kai Gao, Ying Duan, Zhi-Shi Ye, Lei Shi, Yan Yang and Yong-Gui Zhou.* Dihydrophenanthridine: A New and Easily Regenerable NAD(P)H Model for Biomimetic Asymmetric Hydrogenation. J. Am. Chem. Soc. 2012134, 2442-2448.

2. Qing-An Chen, Mu-Wang Chen, Chang-Bin Yu, Lei Shi, Duo-Sheng Wang, Yan Yang and Yong-Gui Zhou.* Biomimetic Asymmetric Hydrogenation: In Situ Regenerable Hantzsch Esters for Asymmetric Hydrogenation of Benzoxazinones. J. Am. Chem. Soc. 2011133, 16432-16435.

1. Qing-An Chen, Duo-Sheng Wang, Yong-Gui Zhou,* Ying Duan, Hong-Jun Fan,* Yan Yang, Zhang Zhang. Convergent Asymmetric Disproportionation Reactions: Metal/Bronsted Acid Relay Catalysis for Enantioselective Reduction of Quinoxalines. J. Am. Chem. Soc. 2011133, 6126-6129.