题目：

Hybrid Block Copolymer/Perovskite Heterointerfaces for Efficient Solar Cells

作者：

Jianguo Sun¹, Bin Li¹, Long Hu⁴, Junjun Guo¹, Xufeng Ling¹, Xuliang Zhang¹, Chi Zhang⁵, Xianxin Wu⁶, Hehe Huang¹, Chenxu Han¹, Xinfeng Liu⁶, Youyong Li^1,3, Shujuan Huang⁴, Tom Wu⁷, Jianyu Yuan^1,2,* and Wanli Ma^1,2,*

单位：

¹Institute of Functional Nano & Soft Materials (FUNSOM), Soochow University, Suzhou, Jiangsu 215123, P.R. China

²Jiangsu Key Laboratory of Advanced Negative Carbon Technologies, Soochow University, Suzhou, 215123, Jiangsu, P. R. China

³Jiangsu Key Laboratory for Carbon-Based Functional Materials and Devices, Soochow University, Suzhou, Jiangsu 215123, P. R. China

⁴School of Engineering, Macquarie University, Sydney, New South Wales, 2109, Australia
⁵i-Lab, CAS Center for Excellence in Nanoscience, Suzhou Institute of Nano-Tech and Nano-Bionics, Chinese Academy of Sciences, Suzhou, Jiangsu 215123, P. R. China

⁶CAS Key Laboratory of Standardization and Measurement for Nanotechnology, CAS Center for Excellence in Nanoscience, National Center for Nanoscience and Technology, Chinese Academy of Sciences, Beijing, 100190, P. R. China

⁷School of Materials Science and Engineering, University of New South Wales (UNSW), Sydney, NSW, 2052 Australia

摘要：

Solution processable semiconductors like organics and emerging lead halide perovskites (LHPs) are ideal candidates for photovoltaics combining high performance and flexibility with reduced manufacturing cost. Moreover, the study of hybrid semiconductors would lead to advanced structures and deep understanding that will propel this field even further. Herein, we investigate a novel device architecture involving block copolymer/perovskite hybrid bulk heterointerfaces, such a modification could enhance light absorption, create an energy level cascade and provides a thin hydrophobic layer, thus enabling enhanced carrier generation, promoting energy transfer and preventing moisture invasion, respectively. The resulting hybrid block copolymer/perovskite solar cell exhibits a champion efficiency of 24.07% for 0.0725 cm2-sized devices and 21.44% for 1 cm2-sized devices, respectively, together with enhanced stability, which is among the highest reports of organic/perovskite hybrid devices. More importantly, this approach has been effectively extended to other LHPs with different chemical compositions like MAPbI3 and CsPbI3, which may shed light on the design of highly efficient block copolymer/perovskite hybrid materials and architectures that would overcome current limitations for realistic application exploration.

影响因子：

30.849

分区情况：

一区

链接：

https://onlinelibrary.wiley.com/doi/10.1002/adma.202206047