近日,中国科协高起点期刊,Wiely出版的cMat创刊号发布,团队和土耳其学者Onder Metin合作发表综述论文“Hydrogen production from chemical hydrogen storage materials over copper-based catalysts”,课题组研究生龙建军,吴昊翀,刘源婷,丁毅悦等为共同第一作者,团队教师姚淇露和卢章辉等为共同通讯作者。
原文链接: https://doi.org/10.1002/cmt2.10
摘要:
Hydrogen, as a clean and efficient energy source, is one of the important energy carriers in the future. However, the safe storage and delivery of hydrogen is still a bottleneck in its practical applications. Chemical hydrides (such as NaBH4, NH3BH3, N2H4·H2O, N2H4BH3, and HCOOH) are considered as potential chemical hydrogen storage materials that can achieve rapid on-site hydrogen production. At present, the most critical issue for them is to develop economic catalysts to achieve efficient hydrogen production from chemical hydrides. Copper (Cu) is considered as a promising catalyst that is one of the most reactive metals among the first-row transition metals and economically cheap. In this review, we outline the recent advancements of Cu-based catalysts in catalyzing hydrogen production from chemical hydrides. Moreover, the synthesis methods, characterization techniques, and hydrogen production catalytic activity of Cu-based catalysts were also introduced. Finally, a brief conclusion and outlook are given for the application of Cu-based catalysts in the dehydrogenation of chemical hydrides. We hope that this review will stimulate interest in the promising research area of Cu-based catalysts for the dehydrogenation of chemical hydrides.