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郑庆舒 助理研究员、讲师     进组时间: 2021.12

科研经历:

     12/2021 – 至今            助理研究员, 上海交通大学,变革性分子前沿科学中心

     10/2018 – 11/2021     博士后,复旦大学,化学系,合作导师:涂涛 教授、俞燕蕾 教授

     09/2014 – 08/2018     博士,英国爱丁堡大学,化学系,导师:Prof. Scott L. Cockroft

     09/2011 – 07/2014     硕士,复旦大学,化学系,无机化学,导师:周亚明 教授

     09/2006 – 07/2010     学士,山东大学,化学与化工学院

已发及待发表文章:

1. Q. Zheng, S. Borsely, T. Tu, S. L. Cockroft*. Reversible stimuli-responsive chromism of a cyclometallated platinum(ii) complex. Chem. Commun. 2020, 56, 14705-14708. (SCI, IF: 6.222)

2. Q. Zheng, S. Borsely, G. S. Nichol, F. Duarte, S. L. Cockroft*. The energetic significance of metallophilic interactions. Angew. Chem. Int. Ed. 2019, 58, 12617-12623. (SCI, IF: 15.336)

3. Q. Zheng, M. Deng, X. Liu, Z. Chen, Y. Wang, Y. Ling*, L. Weng, Y. Zhou*. A porous metal-organic framework constructed from carboxylate-pyrazolate shared heptanuclear zinc clusters: synthesis, gas adsorption and guest-dependent luminescent properties. Inorg. Chem. 2013, 52, 10368-10374. (SCI, IF: 5.165)

4. Q. Zheng, T. Tu*. N-Heterocyclic carbene iridium catalyzed dehydrogenative oxidation of polyols to lactic acid and its derivatives. To be submitted

5. Q. Zheng, Y. Shen, T. Tu*. Morphology controlled catalytic activity of single site hierarchical porous organometallic polymers towards hydrogenation reaction. To be submitted

6. Y. Shen, Q. Zheng, Z.-N. Chen, D. Wen, J. H. Clark, X. Xu*, T. Tu*. Highly efficient and selective N-formylation of amines with CO2 and H2 catalyzed by porous organometallic polymers. Angew. Chem. Int. Ed. 2021, 60, 4125–4132. (SCI, IF: 15.336)

7. Z. Lu, Q. Zheng, S. Yang, C. Qian, Y. Shen, T. Tu*. NHC-iridium-catalyzed deoxygenative coupling of primary alcohols producing alkanes directly: synergistic hydrogenation with sodium formate generated in situ. ACS Catal. 2021, 11, 10796-10801. (SCI, IF: 13.084)

8. L. Shen, Z-N Chen, Q. Zheng, J. Wu, X. Xu* and T. Tu*. Selective transformation of vicinal glycols to α-hydroxy acetates in water via a dehydrogenation and oxidization relay process by a self-supported single-site iridium catalyst. ACS Catal. 2021, 11, 12833-12839. (SCI, IF: 13.084)

9. L. Shen, Q. Zheng, Y. Liu, J. Wu, Z. Lu, and T. Tu*. Efficient hydrogenation of levulinic acid catalysed by spherical NHC-Ir assemblies with atmospheric pressure of hydrogen. Green Chem. 2021, 23, 5037–5042. (SCI, IF: 10.182)

10. Z. Lu, Q. Zheng, G. Zeng, Y. Kuang, J. H. Clark, and T. Tu*. Highly efficient NHC-iridium-catalyzed β-methylation of alcohols with methanol at low catalyst loadings. Sci. China Chem. 2021, 64, 1361-1366. (SCI, IF: 9.445)

11. C. Huang, J. Li, J. Wang, Q. Zheng, Z. Li, T. Tu*. Hydrogen-bond-assisted transition-metal-free catalytic transformation of amides to esters. Sci. China Chem. 2021, 64, 66-71. (SCI, IF: 9.445)

12. Y. Shen, Q. Zheng, J. Liu, T. Tu*. Metallo-aerogels derived from chitosan with encapsulated metal nanoparticles as robust, efficient and selective nanocatalysts towards reduction of nitroarenes. Nano Res. 2021, 14, 59-65. (SCI, IF: 8.897)

13. J. Li, C. Huang, D. Wen, Q. Zheng, B. Tu*; T. Tu*. Nickel-catalyzed amination of aryl chlorides with amides. Org. Lett. 2021, 23, 687-691. (SCI, IF: 6.005)

14. D. Wen, Q. Zheng, C. Wang, T. Tu*. Rare-earth-catalyzed transsulfinamidation of sulfinamides with amines. Org. Lett. 2021, 23, 3718-3723. (SCI, IF: 6.005)

15. X. Bao*, J. Liu, Q. Zheng, L. Duan, Y. Zhang, J. Qian, T. Tu*. Colorimetric recognition of melamine in milk using novel pincer zinc complex stabilized gold nanoparticles. Chin. Chem. Lett. 2021, j.cclet.2021.04.014. (SCI, IF: 6.779)

16. Y. Shen, Q. Zheng, H. H. Zhu, T. Tu*. Hierarchical porous organometallic polymers fabricated by direct knitting: recyclable single-site catalysts with enhanced activity. Adv. Mater. 2020, 32, 1905950. (SCI, IF: 30.849)

17. J. Wu, L. Shen, Z.-N. Chen, Q. Zheng, X. Xu*, T. Tu*. Iridium-catalyzed selective cross-coupling of ethylene glycol and methanol to lactic acid. Angew. Chem. Int. Ed. 2020, 59, 10421-10425. (SCI, IF: 15.336)

18. J. Wu, L. Shen, S. Duan, Z.-N. Chen, Q. Zheng, Y. Liu, Z. Sun, J. H. Clark, X. Xu*, T. Tu*. Selective catalytic dehydrogenative oxidation of bio-polyols to lactic acid. Angew. Chem. Int. Ed. 2020, 59, 13871-13878. (SCI, IF: 15.336)

19. Q. Deng, Q. Zheng, B. Zuo, T. Tu*. Robust NHC-palladacycles-catalyzed Suzuki-Miyaura cross-coupling of amides via C-N activation. Green Synth. Catal. 2020, 1, 75-78.

20. X. Bao*, J. Liu, Q. Zheng, W. Pei, Y. Yang, Y. Dai, T. Tu.* Visual recognition of melamine in milk via selective metallo-hydrogel formation. Chin. Chem. Lett. 2019, 30, 2266-2270. (SCI, IF: 6.779)

21. J. Zhu, J. Chen, T. Qiu, M. Deng*, Q. Zheng, Z. Chen, Y. Ling*, Y. Zhou. Cobalt substitution in a flexible metal–organic framework: modulating a soft paddle-wheel unit for tunable gate-opening adsorption. Dalton Trans. 2019, 48, 7100-7104.

22. F. Yang, Q. Zheng, Z. Chen, Y. Ling*, X. Liu, L. Weng, Y. Zhou*. A three-dimensional structure built of paddle-wheel and triazolate-dinuclear metal clusters: synthesis, deformation and reformation of paddle-wheel unit in the single-crystal-to-single-crystal transformation. CrystEngComm 2013, 15, 7031-7037. (SCI, IF: 3.117)

23. F. Zhai, Q. Zheng, Z. Chen*, Y. Ling, X. Liu, L. Weng and Y. Zhou*. Crystal transformation synthesis of a highly stable phosphonate MOF for selective adsorption of CO2. CrystEngComm 2013, 15, 2040-2043. (SCI, IF: 3.117)

24. B. Xia, Z. Chen, Q. Zheng, H. Zheng, M. Deng, Y. Ling*, L. Weng and Y. Zhou*. A flexible porous metal-azolate framework constructed by [Cu3(μ3-OH)(μ2-O)(triazolate)2]+ building blocks: synthesis, reversible structural transformation and related magnetic properties. CrystEngComm 2013, 15, 3484-3489. (SCI, IF: 3.117)

25. M. Deng, X. Liu, Q. Zheng, Z. Chen*, C. Fang, B. Yue and H. He*. Controllable preparation and structures of two zinc phosphonocarboxylate frameworks with MER and RHO zeolitic topologies. CrystEngComm 2013, 15, 7056-7061. (SCI, IF: 3.117)

26. S. Song, Q. Zheng, A. Song*, and J. Hao. Self-assembled aggregates originated from the balance of hydrogen-bonding, electrostatic, and hydrophobic interactions. Langmuir 2012, 28, 219-226. (SCI, IF: 3.557)

专著:

Qingshu Zheng, Tao Tu. Chapter 9: Assembly of Organometallics: Application in Catalysis and Molecular Recognition. Supramolecular Catalysts: Design, Fabrication, and Applications, World Scientific Publishing Company, May 2020, Editors: Leyong Wang, Cheng-Yong Su. 

专利:

1. 涂涛,吴嘉杰,郑庆舒。一种乙二醇选择性催化转化制备乳酸的方法。专利号:ZL201910664798.2;申请日期:2019年7月23日;授权日期2021年9月8日。

2. 涂涛,申雅靓,郑庆舒。单分散多孔有机金属聚合物材料及其制备方法和应用。专利号:ZL201910684548.5;申请日期:2019726日;授权日期:2021723日。

3. 凌云,郑庆舒,周亚明,陈珍霞,刘小锋,杨永泰,翁林红。具有荧光识别作用的双层墙壁的微孔自组装材料及其制备方法。专利号ZL201210374110.5;申请日期:2012107日;授权日期:2015129日。

4. 涂涛,申雅靓,郑庆舒。一种多孔材料催化二氧化碳氢化制备甲酰胺类化合物的方法。申请号:CN202010077178.1;申请日期:2020124日。

5. 涂涛,陆泽野,郑庆舒。氮杂环卡宾金属化合物催化的一级醇偶联制备烷烃的方法。申请号:CN202110558479.0;申请日期:2021521日。

6. 涂涛,钱春,郑庆舒。一种烯烃选择性氢胺甲基化制备线性胺的方法。申请号:CN202110751460.8;申请日期:20217月3日。

7. 涂涛,陆泽野,曾广阔,杨思琪,郑庆舒。二级醇高选择性催化脱氢偶联制备β-取代酮/醇的方法。申请号:CN202110815791.3;申请日期:2021720日。