Functionalized Hierarchically Porous Carbon Doped Boron Nitride for Multipurpose 

and Efficient Treatment of Radioactive Sewage

ABSTRACT

    In order to recycle Uranium (U) for the sustainable development of nuclear energy, diamide bipyridine (DABP) modified hierarchically porous carbon doped boron nitride (BCN-DABP) was synthesized as an adsorbent for the multipurpose removal of U. BCN-DABP displayed good adsorption performance for U in both weakly and highly acidic solutions. The hierarchically porous structure endowed BCN-DABP with ultrafast adsorption kinetics, and adsorption reached equilibrium within 180.0 and 0.5 min under pH = 4.0 and 2.00 mol L−1 HNO3, respectively. Moreover, combination of adsorption isotherm studies and DFT calculations showed that BCN-DABP possessed high adsorption capacities for U and displayed different adsorption performance under different conditions. BCN-DABP adsorbed UO22+ by chelation and electrostatic attraction under pH 4.0 and 2.00 mol L−1 HNO3, the maximum adsorption capacity under two conditions reached 818.7 and 1296.7 mg g−1, respectively. As a result, BCN-DABP is expected to be used for the rapid and efficient removal of U in various kinds of contaminated water. Furthermore, excellent salinity tolerance, good adsorption selectivity, and outstanding radiation resistance also endowed BCN-DABP with great practical potential for removing U in radioactive contaminated water as well as high level liquid waste.

KEYWORDS: carbon doped boron nitride, diamide bipyridine, uranium, adsorption mechanism, theoretical calculation