研究方向: 功能碳基材料/生物质资源化利用/有机合成
讲授课程: 《有机化学》、《有机合成》、《高等有机合成》、《有机化学实验》
学术成就: 担任海南大学化学化工学院应用化学系主任、Rare Metals期刊青年编委,在Bioresource Technology, Chemosphere, Organic Letters 等期刊发表SCI论文近50篇,出版专著和教材共4部。主持国家自然科学基金2项、省自然科学基金3项,参与国家自然科学基金和省自然科学基金10余项,获得海南省科技进步奖二等奖1项。在生物炭领域,率先提出“氧化磁化”策略,高效解决生物炭性能低下和分离难的问题。在有机合成领域,发展了铜催化氰胺、胺和硼酸(或碘盐)三组分反应,建立了多种快速构建胍类化合物的新方法。
科研项目:
1、氧化磁改性制备高吸附性能强磁性生物炭及其机制研究,国家自然科学基金,2022, 01-2025, 12,主持。
2、 过渡金属催化二芳基碘盐三组分原子经济性反应研究,国家自然科学基金,2019, 01-2021, 12,主持。
3、海洋矿物质改性制备高吸附性能生物炭及其机制,海南省自然科学基金高层次人才项目,2022,04-2025,12,主持。
4、生物炭的改性及吸附性能研究,海南省自然科学基金,2019, 03-2020, 12,主持。
5、 过渡金属催化氰胺、芳基硼酸和亲核试剂三组分反应合成胍类化合物研究,海南省自然科学基金,2016, 01-2017, 12,主持。
6、一石三鸟的使用转氨酶和羰基还原酶的双酶催化体系研究,国家自然科学基金,2019,01-2022,12,参与。
7、PVA纤维与多元水泥基材料间界面作用行为及机理研究,国家自然科学基金,2017,01-2019,12,参与。
论著专利:
25. A. Sun, S. Bian, L. Li, Z. Guo, W. Li, J. Li*, S. Xu, P.-D. Liu, Preparation of highly adsorptive biochar by sequential iron impregnation under refluxing and pyrolysis at low temperature for removal of tetracycline, Environmental Pollution, 2024, 348, 123886.
24. C. Zhong, Z. Guo, J. Hang, S. Xu, H. Song, W. Liu*, J. Li*, An efficient and general oxidative magnetization for preparation of versatile magnetic porous biochar at low temperature, Journal of Environmental Chemical Engineering, 2024, 12, 112187.
23. J. Hang, Z. Guo, C. Zhong, A. Sun, K. He, X. Liu, H. Song*, J. Li*, A super magnetic porous biochar manufactured by potassium ferrate-accelerated hydrothermal carbonization for removal of tetracycline, Journal of Cleaner Production, 2024, 435, 140470.
22. Z. Guo, X. Chen, J. Hang , Z. Li, C. Zhong d, A. Sun, J. Li*, S. Xu, Oxidative magnetization of biochar at relatively low pyrolysis temperature for efficient removal of different types of pollutants, Bioresource Technology, 2023, 387, 129572.
21. Y. Zhao, R. Yang, C. Wu, S. Wang, X. Liu, J. Li*, S. Xu*, Copper and In Situ-Generated Triflic Acid Relay-Promoted Four-Component Cascade Reaction for the Construction of Polysubstituted Cycloguanidines, The Journal of Organic Chemistry 2023, 88, 13, 8400-8412.
20. R. Yang, Y. Zhao, S. Wang, C. Wu, J. Li*, S. Xu, Base-controlled copper-catalyzed multicomponent cascade reactions of cyanamides, diaryliodonium triflates and propargylamine for rapid assembly of polysubstituted 2-aminoimidazoles and 2-iminoimidazoles, New Journal of Chemistry, 2023, 47, 8494.
19. Y. Chen, L. Li, Q. Wen, R. Yang, Y. Zhao, X. Rao, J. Li*, S. Xu, H. Song, Oxidative magnetic modification of pristine piochar assisted by ball-milling for removal of methylene blue and tetracycline in aqueous solution, Sustainability, 2022, 14, 9349.
18. Q. Wen,Y. Chen, X. Rao, R. Yang, Y. Zhao, J. Li*, Y. Chen, R. Yang, S. Xu, Z. Liang, Preparation of magnesium ferrite-doped magnetic biochar using potassium ferrate and seawater mineral at low temperature for removal of cationic pollutants, Bioresource Technology, 2022, 350, 126860.
17. Q. Wen, S. Wang, S. Liu, J. Li*, Y. Chen, R. Yang, S. Xu, Investigation of seawater mineral promoted pyrolysis at low temperature for improving the adsorption capabilities of biochar, Chemosphere, 2022, 292, 133447.
16. S. Wang, S. Bian, J. Liu, J. Li*, S. Xu, Z. Liang, Highly adsorptive pristine and magnetic biochars prepared from crayfish shell for removal of Cu(II) and Pb(II), J. Taiwan Inst. Chem.Eng., 2021, 127, 175-185.
15. S. Bian, S. Xu, Z. Yin, S. Liu, J. Li*, S. Xu* and Y. Zhang, An efficient strategy for enhancing the adsorption capabilities of biochar via sequential KMnO4-promoted oxidative pyrolysis and H2O2 oxidation, Sustainability 2021, 13, 2641.
14. S. Xu, W. Yu, S. Liu, C. Xu, J. Li*, Y. Zhang, A highly efficient strategy for enhancing the adsorptive and magnetic capabilities of biochar using Fenton oxidation, Bioresource Technology, 2020, 300, 122680.
13. Z. Yin, S. Xu, S. Liu, S. Xu, J. Li*, Y. Zhang, A novel magnetic biochar prepared by K2FeO4 -promoted oxidative pyrolysis of pomelo peel for adsorption of hexavalent chromium, Bioresource Technology, 2020, 300, 122680.
12. Sen Liu, J. Li*, Shuang Xu, Mengzhen Wang, Yucang Zhang*, Xinghua Xue, A modified method for enhancing adsorption capability of banana pseudostem biochar towards methylene blue at low temperature, Bioresource Technology, 2019, 282, 48-55.
11. Z. Yin, N. Liu, S. Bian, J. Li*, S. Xu*, Y. Zhang, Enhancing the adsorption capability of areca leaf biochar for methylene blue by K2FeO4-catalyzed oxidative pyrolysis at low temperature, RSC Advances, 2019, 9, 42343-42350.
10. S. Xu, W. Yu, S. Liu, C. Xu, J. Li*, Y. Zhang*, Adsorption of hexavalent chromium using banana pseudostem biochar and its mechanism, Sustainability, 2018, 10, 4250.
9. J. Li*, Z. Li, Y. Zhang, W. Xu, S. Xu, Progress on the Synthesis and Applications of Cyanamides,Chin. J. Org. Chem. 2017, 8, 1903-1915.
8. J. Li, H. Wang, Y. Hou, W. Yu, S. Xu, Yucang. Zhang* A General and Mild Copper(I)-Catalyzed Three-Component Reaction of Cyanamides, Amines, and Diaryliodonium Triflates, Eur. J. Org. Chem. 2016, 2388-2392.
7. S. Xu, X. Chen, J. Li*, W.. Xu, Y. Zhang*, Recent Advances in Transition Metal-Catalyzed Synthesis of Guanidines, Chin. J. Org. Chem. 2016, 36, 1985-1993.
6. J. Li, Xinyi. Zheng, W. Li, W. Zhou, Wen. Zhu, Y. Zhang*, Transition-Metal Free N-Arylation of Cyanamides by Diaryliodonium Triflates in Aqueous Media,New. J. Chem. 2016, 40, 77-80.
5. J. Li, L. Neuville*, Copper-Catalyzed Oxidative Three-Component Synthesis of N, N’, N’’-Trisubstituted Guanidines, Org. Lett. 2013, 15, 6124-6127.
4. J. Li, L. Neuville*, Copper Catalyzed Synthesis of Multisubstituted Imidazoles through C-N Coupling /Cycloaddtion of amidines and terminal acetylenes, Org. Lett. 2013, 15, 1752-1755. Hilihgted by Synfacts (2013, 9, 0603).
3. J. Li, S. Bénard, L. Neuville*, J. Zhu*, Copper Catalyzed N-Arylation of Amidines with Aryl Boronic Acids and One-Pot Synthesis of Benzimidazoles by a Chan–Lam–Evans N-Arylation and C–H Activation/C–N Bond Forming Process, Org. Lett. 2012, 14, 5980-5983.
2. J. Li, Y. Zhang, D. Wang, W. Wang, T. Gao, L. Wang, J. Li, G. Huang, B. Chen*, Metal- and Base-Free Three-Component Reaction of Ynones, Sodium Azide, and Alkyl Halides: Highly Regioselective Synthesis of 2,4,5-Trisubstituted 1,2,3-NH-Triazoles, Synlett 2010, 1617-1622.
1. J. Li, D. Wang, Y. Zhang, J. Li, B. Chen*, Facile One-Pot Synthesis of 4,5-Disubstituted 1,2,3-(NH)-Triazoles through Sonogashira Coupling/1,3-Dipolar Cycloaddition of Acid Chlorides, Terminal Acetylenes, and Sodium Azide, Org. Lett. 2009, 11, 3024-3027.