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程载哲 博士后    

教育经历:

2013.09-现在         天津大学 (推荐免试)    博士在读             专业:化学工艺

2017.02-2018.02      澳大利亚联邦科工(CSIRO)能源部门联合培养      专业:化学工艺

2009.09-2013.07         天津大学             化工学士             专业:分子科学与工程(双学位)

2009.09-2013.07         南开大学             化学学士             专业:分子科学与工程(双学位)


科研经历:

2013.09-现在              天津大学绿色合成与转化教育部重点实验室            导师:马新宾教授

研究方向:合成气高效利用,分子筛合成,金属负载,催化过程动力学模拟

研究课题:丝光沸石分子筛催化二甲醚羰基化反应制乙酸甲酯

研究成果:

1. 通过多种催化表征手段对失活催化剂进行了系统性的表征,明确了主要积碳物种及其对丝光沸石中不同孔道酸位以及孔道结构的影响,基于原位红外表征建立了积碳动力学模型,解释了铜改性与未改性分子筛失活行为的不同。

2. 对反应中的失活动力学过程进行了研究,通过动力学计算和红外等手段,从动力学角度揭示了失活机理,确定了最优失活动力学模型,为反应器的设计和工艺条件的确定提供了参考。

3. 通过原位红外、质谱等表征手段对催化剂积碳失活过程进行了原位研究,明确了主要的积碳路径,并提出了可能的积碳生成机理。


参与基金项目:

国家杰出青年科学基金:一碳化工                          

青年科学基金项目 :中心Cu-分子筛的构筑及催化氧化羰基反应的机理研究    

国家自然科学基金石油化工联合基金重点项目:合成气直接制低碳烯烃的催化基础研究    

千吨级二甲醚制乙醇项目中试    

                                             

发表论文及专利:                                                             

1. Zaizhe Cheng, Shouying Huang*, Ying Li, Kai Cai, Dawei Yao, Xinbin Ma. Carbonylation of dimethyl ether over MOR and Cu/H-MOR catalysts: comparative investigation of deactivation behavior. Applied Catalysis A-General, 2019, 576, 1-10. (IF=4.521)

2. Zaizhe Cheng, Shouying Huang*, Ying Li, Jing Lv, Kai Cai, and Xinbin Ma*. Deactivation kinetics for the carbonylation of dimethyl ether to methyl acetate on H-MOR. Industrial & Engineering Chemistry Research, 2017, 56, 13618-13627. (IF=3.141)

3. Zaizhe Cheng, Tibra Mozammel, Jim Patel, Woo Jin Lee, Shouying Huang, Seng Lim, Xinbin Ma, Suresh Bhargava, Chao’en Li*. A method for the quantitative analysis of gaseous mixtures by online mass spectrometry. International Journal of Mass Spectrometry, 2018, 434, 23-28. (IF=1.826)

4. Zaizhe Cheng, Chao’en Li, Woo Jin Lee, Yunxia Yang, Liangguang Tang, Seng Lim, Shouying Huang, Xinbin Ma*, Jim Patel*. Kinetic study on direct synthesis of hydrogen peroxide from hydrogen and oxygen. Industrial & Engineering Chemistry Research, 2019, 58, 20573-20584. (IF=3.141).

5. Ying Li, Shouying Huang*, Zaizhe Cheng, Kai Cai, Landong Li, Emile Milan, Jing Lv, Yue Wang, Qi Sun, Xinbin Ma*. Promoting the activity of Ce-incorporated MOR in dimethyl ether carbonylation through tailoring the distribution of Brønsted acids. Applied Catalysis B: Environmental, 2019, 256.

6. Ying Li1, Shouying Huang1, Zaizhe Cheng, Shengping Wang, Qingfeng Ge*, Xinbin Ma*. Synergy between of Cu and Brønsted acid sites on carbonylation of dimethyl ether over Cu/H-MOR. Journal of Catalysis, 2018, 365, 440-449. (IF=6.759)

7. Ying Li, Qi Sun, Shouying Huang*, Zaizhe Cheng, Kai Cai, Jing Lv, Xinbin Ma, Dimethyl ether carbonylation over pyridine-modified MOR: Enhanced stability influenced by acidity. Catalysis Today, 2018, 311, 81-88. (IF=4.667)

8. Kai Cai, Shouying Huang*, Ying Li, Zaizhe Cheng, Jing Lv, and Xinbin Ma*, Influence of Acid Strength on the Reactivity of Dimethyl Ether Carbonylation over H‑MOR. ACS Sustainable Chemistry & Engineering, 2019, 7, 2027-2034. (IF=6.140)

9. Hongbao Shen, Ying Li, Shouying Huang*, Kai Cai, Zaizhe Cheng, Jing Lv, Xinbin Ma, The carbonylation of dimethyl ether catalyzed by supported heteropoly acids: The role of Brønsted acid properties. Catalysis Today, 2018, 330, 117-123. (IF=4.667)

10. Meixia Wang, Shouying Huang*, Jing Lü, Zaizhe Cheng, Ying Li, Shengping Wang, Xinbin Ma*. Modifying the acidity of H-MOR and its catalytic carbonylation of dimethyl ether. Chinese Journal of Catalysis, 2016, 37, 1530-1537. (IF=3.525)