研究方向

• 亲核取代竞争反应

• 微溶剂化反应机理

• 直接动力学模拟

发表论文

1. Xiangyu Wu, Chongyang Zhao,* Jing Xie,* Microsolvated Ion-Molecule SN2 Reactions with Dual Nucleophiles Induced by Solvent Molecules. ChemPhysChem, 2022, DOI: 10.1002/cphc.202200285

2. Xiangyu Wu, Shaowen Zhang,* Jing Xie,* Investigating the Competing E2 and SN2 Mechanisms for the Microsolvated HO-(H2O)n=0-4 + CH3CH2Y Reactions.  Physical Chemistry Chemical Physics, 2022, 24, 12993-13055. DOI: 10.1039/D1CP04010C

3. Mengxi Zhang, Anke Yu, Xiangyu Wu, Pengpeng Shao, Xin Huang, Dou Ma, Xianghao Han, Jing Xie, Xiao Feng, Bo Wang. Sealing functional ionic liquids in conjugated microporous polymer membrane by solvent-assisted micropore tightening. Nano Research, 2021, 15, 2552-2557. https://doi.org/10.1007/s12274-021-3750-z

4. Chongyang Zhao, Xinyou Ma, Xiangyu Wu, Ditte L. Thomsen, Veronica Bierbaum,* Jing Xie* Single Solvent Molecules Induce Dual Nucleophiles in Gas-Phase Ion-Molecule Nucleophilic Substitution Reactions. J. Phys. Chem. Lett. 2021, 12, 7134-7139

5. Yang Hu, Xiangyu Wu, Jing Xie* Nucleophilic Substitution Reactions of Microsolvated Hydroperoxide Anion HOO−(NH3)n with Methyl Chloride and Comparison Between Ammonia and Water as Solvent. Physical Chemistry Chemical Physics 2023, 25, 1947 - 1956. DOI: 10.1039/D2CP04693H

6. 宋哲轩，胡阳，吴翔钰，谢静*. 对“应用量子化学计算理解溶剂对CH3O−/CH3S−亲核性的影响”的思考与拓展,大学化学,2023, 38 (9), 280-286. DOI: 10.3866/PKU.DXHX202211018

7. Xiangyu Wu, F. Matthias Bickelhaupt,* Jing Xie.* Solvent-Induced Dual Nucleophiles and the α-Effect in the SN2 versus E2 Competition. Phys. Chem. Chem. Phys. 2024, 26, 11320-11330. DOI: 10.1039/D4CP00671B  2024 PCCP HOT Paper 

8. Xiangyu Wu, Chongyang Zhao, Shaowen Zhang,* Jing Xie.* Shapeshifting Nucleophile Singly-hydrated Hydroperoxide Anion Leads to the Occurrence of Thermodynamically Unfavoured SN2 Product. J. Phys. Chem. A 2024, 128, 2393-2398.  DOI: 10.1021/acs.jpca.4c01159 

9. Xiangyu Wu,# Yang Hu,# Shaowen Zhang,* Jing Xie.* Shapeshifting Nucleophiles HO‒(NH3)n React with Methyl Chloride. J. Phys. Chem. A 2024, 128, 2556-2564.  DOI: 10.1021/acs.jpca.3c07553 Published as part of The Journal of Physical Chemistry A virtual special issue “Women Scientists in China”.

荣誉&奖励

     1. 2022.8 获得“第十七届全国化学动力学会议”优秀海报奖