清华大学核能与新能源技术研究院聘请Prof Omar M. Yaghi为“清华大学名誉教授” 的申请近日被批准。聘请仪式计划于2022年1月13日下午7点（美国太平洋时间，北京时间14号中午11点）线上举行。Yaghi教授将为我们带来精彩学术报告，报告将进行公开“视频直播”。报告将在本公众号中“视频直播”。请大家关注本公众号，收看视频直播。
奥马尔·亚吉在金属有机骨架等方面贡献了开创性工作。他和他的研究团队设计并备了金属有机骨架（MOFs），沸石咪唑酯骨架结构材料（ZIFs），共价有机骨架（COFs），他们是一类具有高比表面积、低晶体密度的化合物。同时，他也成功的把这些材料从基础科学领域带入应用领域，其中包括清洁能源（氢气，甲烷）储存、二氧化碳吸附和储存。
详细介绍见http://yaghi.berkeley.edu/
奥马尔·亚吉（Omar M. Yaghi）
1965年生于约旦首都安曼。美籍约旦裔化学家，美国科学院院士、加州大学伯克利分校James和NeeltjeTretter讲席教授、劳伦斯伯克利国家实验室材料科学部主任。1990年博士毕业于伊利诺伊大学厄巴纳分校，同年赴哈佛大学从事博士后研究，1992年在亚利桑那州立大学任助理教授，1999年在密歇根大学任教授，2006年任加州大学洛杉矶分校教授，2012年起在加州大学伯克利分校任教授。1998年， Yaghi教授获得美国化学会固态化学奖；2006年，被大众科学杂志评为“美国十大杰出科学家”；2007年获得美国能源部储氢计划杰出贡献奖、美国材料研究学会奖章；2009年获得美国化学学会材料化学奖；2013年获得中国纳米奖；2017年获得英国皇家化学学会斯皮尔斯纪念奖；2018年，Yaghi教授因“通过金属有机框架和共价有机框架开创了网状化学”，获得沃尔夫化学奖。此外，Yaghi教授多次获得诺贝尔化学奖提名。目前担任《美国化学会志》(Journalof American Chemical Society)副主编。
Yaghi教授是金属有机骨架（MOFs）和共价有机框架(COFs)领域的开拓者和奠基人。他在功能多孔材料的合成及其储能等领域的应用有深入的研究，并取得了杰出的研究成果，共发表270多篇学术论文，其中29篇发表在Science和Nature杂志上，论文被引137,000余次，其hindex(143)在世界化学家中排名第2位。
聘请仪式计划于2022年1月13日下午7点（美国太平洋时间，北京时间14号中午11点）线上举行。Yaghi教授将为我们带来精彩学术报告。报告将在本公众号中“视频直播”。请大家关注本公众号，收看视频直播。
【背景】核能与新能源技术研究院于2018年引进徐宏博士。徐宏博士在COF领域开创性地设计出高稳定性的材料，为COF材料的应用奠定了基础。
个人简介-徐宏
徐宏，博士，1987年生，2005年-2012年在上海交通大学学习并获学士、硕士学位，2015年在日本国立分子科学研究所获博士学位，同年到美国康奈尔大学从事博士后研究工作。2018年7月起受聘清华大学核能与新能源技术研究院。现为清华大学副教授，博士生导师。主要研究方向为有机多孔材料，有机/无机纳米材料，极紫外光刻材料，锂离子电池，量子化学计算等。
徐宏主要学术贡献
共价有机框架（COF）在被发现的10年来，一直是化学领域的热门研究课题，但是，不稳定性使得这类化合物很难成为有用的材料，一直是亟需解决却又难以克服的挑战。徐宏博士的工作很好的解决了这一难题，为COFs研究领域做出了重大贡献。徐宏博士的工作对化学学科的发展具有重要贡献。
共价有机框架是一类通过共价键链接的多孔结晶性聚合物。材料的结晶性来源于热力学控制的可逆聚合反应，非能量最低构象的热力学不稳定性致使其在合成时就被再次分解。COF的通道阵列和高比表面积在气体分离/储存，非均相催化，离子传输等方面有着广泛的应用前景。然而极差的化学稳定性，严重地限制其实际应用。
徐宏博士通过亚胺类COF层间堆积能研究，提出亚胺构筑单元中引入给电子侧基提高层间堆积能的策略。在引入甲氧基之后，亚胺COF的结晶性从几乎无规的聚合物提升至高度结晶的水平，所带来的规整结构使材料内部塌陷得以避免，其比表面积接近材料的理论值，达到了二维COF最好水平。同时，材料层间堆积能的提高使得化学稳定性得到了极大的改善，解决了遇质子溶剂（水）不稳定的问题，并可在各类有机溶剂中稳定存在，甚至在苛刻的极端条件：12M盐酸、14M氢氧化钠，甚至100 ˚C沸水水解7天，结晶性和比表面积依然不变；而传统的高比表面积COF在室温条件下就会被微量湿气所分解。该研究成果解决了长期困扰COF领域的结晶性，多孔性，稳定性三者难以兼得的挑战，成果发表于Nature Chemistry（2015, 7, 905)。沿袭这一设计思路，徐宏博士成功研发了多个高综合性能的COF，成果发表于JACS（2017, 139,2428）和Science（2017, 357,673）。并实现了首例基于COF 的无水质子传导材料（Nature Mater. 2016, 15,722; Nature Chem. 2014, 6, 564），首例基于COF的非均相手性催化剂 (Nature Chem. 2015, 7,905; Chem. Commun. 2014, 50, 1292）。以及储能材料（Angew. Chem. Int. Ed. 2015, 54,6814; Chem. Commun. 2017, 53,11334.）,光电材料（Science 2017, 357, 673; NatureCommun. 2015, 6,7786; J. Am. Chem. Soc. 2015, 137, 3241），二氧化碳捕捉材料（Chem. Commun. 2017, 53,4242），污水处理材料（J.Am. Chem. Soc. 2017, 139, 2428），储氢（Journal of theAmericanChemical Society,2021, 143,92-96; Chemistry of Materials,published online）, 锂离子电池（Energy StorageMaterials, 2020，33, 360-381；Energy StorageMaterials, 2020，33, 188-215；Advanced EnergyMaterials, 2020，10；Chemical Communications, 2020，56, 10465 – 10468；Advanced Materials,2021，e2106335；Energy& Environmental Materials,2021；Nature Communications,2021，accepted）。
尽管COF材料在很多基于规整多孔特性的领域（如非均相催化，离子传输）具有很好的应用前景，但长期以来稳定性差使其无法实现。徐宏的贡献在于，大幅度地提高结晶性和多孔性的同时，材料极其稳定。基于这一重大进步，COF材料的诸多功能化开发得以实现。
新能源研究—新型能源与材料化学研究室
清华大学核能与新能源技术研究院于上个世纪九十年代初期，组建了新型能源与材料化学研究团队--新型能源与材料化学研究室，先后开展了镍氢电池、燃料电池和锂离子电池及材料的研发。承担了国家“973”项目10多项、“863”项目10多项和自然科学基金项目20多项。开展国际合作项目20多项，横向技术转让和技术服务项目100多项。已发表SCI论文750多篇，授权发明专利500多项。并为国家培养了一批技术领军人才。研究团队拥有SEM、粉体XRD、软包电池透射XRD，BET、TGA/DSC、ARC等大型仪器和5千多万元的专用仪器和测试设备，2千多平米的实验室，包括低露点的干燥房和洁净间，可进行高端材料化学合成以及新型锂离子电池试验装配和高质量燃料电池电堆组装及系统集成。
研究团队目前主要围绕氢能燃料电池和二次电池领域的关键材料和关键技术，开展前沿创新研究，以及核心部件、系统集成与控制技术的应用基础研究与工程开发。针对新能源汽车和新能源储能的重大需求，重点研发高安全性、长寿命、环境友好的新型电源（能源）技术。研究团队目前主要开展物理吸附储氢技术、超高比能量锂电池技术、动力电池安全性技术、低成本长寿命燃料电池技术、中低温固体氧化物燃料电池和新能源储能技术等领域的研究。
高性能电池前沿技术创新研究
20多年来，研究团队在锂离子电池领域取得多项技术成果并实现了产业化，例如高密度、高活性镍氢电池正极材料，高性能钴酸锂、锰酸锂、镍钴锰酸锂、磷酸铁锂等系列锂离子电池正极材料，以及隔膜改性技术、补锂技术和电池一致性测试技术等等。随着我国锂离子电池产业的逐步成熟，研究团队把更多力量投入到下一代电池技术的创新研究中，取得了多项具有自主知识产权的原始创新成果。部分成果近期正在开展产业化技术研发，例如红磷负极技术（r-P）和锂金属负极技术（Li metal）。目前正在进行新型快充电磷碳电池和下一代500Wh/kg电池的研发工作。
多孔材料物理吸附储氢技术
共价有机框架（Covalent Organic Frameworks，COFs）是一类由共价键连接的有机多孔结晶性聚合物，具有高度有序的孔道结构和高比表面积，在气体吸附及储存、光电转换、非均相催化、能源存储及转换领域有着广阔的应用前景。然而，由于缺乏行之有效的功能化方法以及COF本身稳定性的问题，对该类材料功能化开发的报道十分有限。基于晶体堆积能理论，核研院成功的开发出了兼具极高结构稳定性和高比表面积的COFs，解决了COF材料的稳定性问题。在此基础之上，开发了基于COF的无水质子传导材料，氢氧根传导材料，非均相催化剂以及储氢材料。
半导体极紫外光刻胶技术
目前半导体关键技术中，极紫外（Extreme Ultraviolet，EUV）光刻是一种采用波长13.5 nm极紫外光为工作波长的投影光刻技术，技术难度大、瓶颈多。由于国际上最先进EUV光源的稳定光功率只有250 W，现有聚合物EUV光刻胶因为曝光剂量高，导致EUV光刻技术面临产能低、成本高、设备技术遭遇垄断等问题。而高感光EUV光刻胶可有效突破上述所有瓶颈。核研院研发成功具有自主知识产权的尺寸最小的金属有机团簇光刻胶，曝光剂量可低于Intel公司提出的20 mJ/cm2的成本线；在分辨率方面，已实现13 nm的密集图形，可满足3.5 nm制程技术的分辨率要求。
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58 Overchargebehaviors and failure mechanism of lithium-ion batteries under different testconditions. Applied Energy, 250, 323-332,doi:10.1016/j.apenergy.2019.05.015 (2019).
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150 Improvement inHigh-voltage Performance of Lithium-ion Batteries Using Bismaleimide as anElectrolyte Additive. Electrochimica Acta, 121,264-269, doi:10.1016/j.electacta.2013.12.170 (2014).
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201 Controlledcrystallization and granulation of nano-scale beta-Ni(OH)(2) cathode materialsfor high power Ni-MH batteries. Journal of Power Sources, 152,285-290, doi:10.1016/j.jpowsour.2005.03.208 (2005).
202 Expansion andshrinkage of the sulfur composite electrode in rechargeable lithium batteries. Journalof Power Sources, 190, 154-156,doi:10.1016/j.jpowsour.2008.07.034 (2009).
203 Ytterbium coating ofspherical Ni(OH)(2) cathode materials for Ni-MH batteries at elevated temperature. Journalof Power Sources, 158, 1480-1483,doi:10.1016/j.jpowsour.2005.10.063 (2006).
204 Well-orderedspherical LiNixCo(1-2x)MnxO2 cathode materials synthesized from coboltconcentration-gradient precursors. Journal of Power Sources, 202,284-290, doi:10.1016/j.jpowsour.2011.10.143 (2012).
205 Stannum doping oflayered LiNi3/8Co2/8Mn3/8O2 cathode materials with high rate capability forLi-ion batteries. Journal of Power Sources, 158, 524-528,doi:10.1016/j.jpowsour.2005.08.026 (2006).
206 Synthesis andcharacterization of Li(Li0.23Mn0.47Fe0.2Ni0.1)O-2 cathode material for Li-ionbatteries. Journal of Power Sources, 244, 652-657,doi:10.1016/j.jpowsour.2012.12.107 (2013).
207 Synthesis andcharacterization of LiNi0.6Mn0.4-xCoxO2 as cathode materials for Li-ionbatteries. Journal of Power Sources, 189, 28-33,doi:10.1016/j.jpowsour.2008.12.046 (2009).
208 Electrochemicalperformance of SrF2-coated LiNi1/3Co1/3Mn1/3O2 cathode materials for Li-ionbatteries. Journal of Power Sources, 190, 149-153, doi:10.1016/j.jpowsour.2008.08.011(2009).
209 Internal shortcircuit detection for battery pack using equivalent parameter and consistencymethod. Journal of Power Sources, 294, 272-283,doi:10.1016/j.jpowsour.2015.06.087 (2015).
210 Anelectrochemical-thermal coupled overcharge-to-thermal-runaway model for lithiumion battery. Journal of Power Sources, 364, 328-340,doi:10.1016/j.jpowsour.2017.08.035 (2017).
211 Electrochemicalcharacteristics of sulfur composite cathode materials in rechargeable lithium batteries. Journalof Power Sources, 138, 271-273,doi:10.1016/j.jpowsour.2004.06.032 (2004).
212 The effect of localcurrent density on electrode design for lithium-ion batteries. Journalof Power Sources, 207, 127-133, doi:10.1016/j.jpowsour.2011.12.063(2012).
213 Electro-thermalmodeling and experimental validation for lithium ion battery. Journalof Power Sources, 199, 227-238,doi:10.1016/j.jpowsour.2011.10.027 (2012).
214 Preparation andcharacterization of high-density spherical Li0.97Cr0.01FePO4/C cathode materialfor lithium ion batteries. Journal of Power Sources, 158,543-549, doi:10.1016/j.jpowsour.2005.08.045 (2006).
215 A new process ofpreparing composite microstructure anode for lithium ion batteries. Journalof Power Sources, 184, 532-537,doi:10.1016/j.jpowsour.2008.02.064 (2008).
216 Synthesis andcharacterization of Sn-doped LiMn(2)O(4) cathode materials for rechargeableLi-ion batteries. Journal of the Electrochemical Society, 155,A760-A763, doi:10.1149/1.2965635 (2008).
217 Co/Yb hydroxidecoating of spherical Ni(OH)(2) cathode materials for Ni-MH batteries atelevated temperatures. Journal of the Electrochemical Society, 153,A566-A569, doi:10.1149/1.2161581 (2006).
218 Preparation ofCu6Sn5-encapsulated carbon microsphere anode materials for Li-ion batteries bycarbothermal reduction of oxides.Journal of the Electrochemical Society, 153,A1859-A1862, doi:10.1149/1.2229276 (2006).
219 In SituPolymerization of Methoxy Polyethylene Glycol (350) Monoacrylate andPolyethyleneglycol (200) Dimethacrylate Based Solid-State Polymer Electrolytefor Li-Ion Batteries. Journal of the Electrochemical Society, 159,A915-A919, doi:10.1149/2.003207jes (2012).
220 Internal ShortCircuit Trigger Method for Lithium-Ion Battery Based on Shape Memory Alloy. Journalof the Electrochemical Society, 164, A3038-A3044,doi:10.1149/2.0731713jes (2017).
221 Fusing Phenomenon ofLithium-Ion Battery Internal Short Circuit. Journal of the ElectrochemicalSociety, 164, A2738-A2745, doi:10.1149/2.1721712jes (2017).
222 Determination oflithium-ion transference numbers in LiPF6-PC solutions based on electrochemicalpolarization and NMR measurements. Journal of the Electrochemical Society, 155,A292-A296, doi:10.1149/1.2837832 (2008).
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