田荣强，博士，副教授, 硕士生导师，电子邮箱：tianrq@zzu.edu.cn；

教育与工作经历

2001-2005 聊城大学 化学化工学院  学士

2005-2010 郑州大学 化学学院 博士（硕博连读）

2010-2012 新加坡南洋理工大学 数理学院  博士后

2012-至今 郑州大学化学学院

研究领域

有机磷化学，有机合成方法学

主要从事低配位有机磷化合物和含磷杂环化合物的合成及反应研究，发现新的磷化学反应，揭示反应规律。

科研项目

2014-2016“具有磷杂二茂铁骨架的π酸配体合成及其催化性能研究”，国家自然科学基金资助项目 (编号201302174)，已结项.

2017磷杂富烯类化合物的合成、反应性能及机理研究，中国博士后科学基金面上资助(1621316006)。

2017-2019 过渡金属催化的C-P键断裂及相关化学反应研究，郑州大学优秀青年发展基金, (1621316006)。

2020-2021新型π酸配体的合成及其在异丁烯制备异戊醛工艺中的应用，河南省高等学校重点科研项目（20A150040）

2020-2021 环张力促进的C-P键的转化、机理及应用，郑州大学青年教师（自然科学）基础研究培育基金（JC202053019）

奖励与荣誉

河南省优秀科技论文壹等奖 两项，河南省自然科学优秀学术论文贰等奖

2016-2017学年和2011-2022学年郑州大学“三育人”先进个人

2021年河南省优秀毕业论文指导教师

国家级大学生创新创业项目指导教师

河南省本科高校大学生创新创业训练计划项目优秀成果奖

2021年获评郑州大学教学优秀三等奖

代表性研究论文

1. Mingyue Cui, Ke Feng, Rongqiang Tian,* and Zheng Duan*, Phosphorus-Involved Wagner−Meerwein Rearrangement of Phosphiranes: An Entry to Four-Membered Phosphacycles, Org. Lett. 2022, DOI:10.1021/acs.orglett.2c04052.

2. Yueshan Hou, Mingyue Cui, Keke Zhang, Lihui Chen* and Rongqiang Tian*, Annulation of phosphole sulfides via [3 + 2] cycloaddition with nitrones, Org. Chem. Front. 2022, 9, 6606–6610.

3. Junjian Wang, Jingrong Chen, Rongqiang Tian,* and Zheng Duan*, Activation of CS2 with the 2H‑Phosphindole Complex to Construct P,S-Polycycles, Org. Lett. 2022, 24, 33, 6117–6121.

4. Junjian Wang, Haotian Luo, Xinghua Wang, Donghui Wei,* Rongqiang Tian,* and Zheng Duan*, Dearomatization [4+2] Cycloaddition of Nonactivated Benzene Derivatives, Org. Lett. 2022, 24, 4404−4408.

5. Mingyue Cui, Juan Li, Rongqiang Tian * and Zheng Duan*, Tandem [5 + 1]/[8 + 2] cycloaddition reactions involving phosphiranes and tropones: facile access to 6,5,7-fused tricyclic skeletons, Org. Chem. Front. 2022, 9, 2753–2758.

6.  Hong Li, Rongqiang Tian* and Zheng Duan*, Intramolecular Activation of Enones by Electrophilic Phosphinidene Complexes to Construct 2‑Phosphafurans, Org. Lett. 2022, 24, 767−770.

7.  Lingzhi Qiu, Qiaoyu Zhang, Donghui Wei, Rongqiang Tian* and Zheng Duan*, Insight into fragmentation of a phosphirane to form phosphinidene complexes: an illustration with the 1-phenylselenylphosphirane W(CO)₅ complex, Dalton Trans. 2022, 51, 3046–3050.

8.  Keke Zhang, Qiaoyu Zhang, Donghui Wei, Rongqiang Tian,* Zheng Duan*, Hetero-Diels-Alder Reactions of 2H-Phospholes with Allenes: Synthesis and Functionalization of 6-Methylene-1-phosphanorbornenes, Org. Chem. Front. 2021, 8, 3740-3745.

9.  Yanjie Liu, Xinran Fan, Rongqiang Tian*, Zheng Duan* FeCl₂ Catalyzed Three-Component Reactions of Phospholes, Pyrrolidine and Ketones (Aldehydes): Chemoselective Synthesis of 1-Phosphafulvenes, Org. Lett. 2021, 23, 2943-2947.

10.  Juan Li, Mingyue Cui, Rongqiang Tian*, Zheng Duan*, François Mathey Cycloadditions of 1-iminylphosphirane complexes with allenes, Chin. Chem. Lett. 2021, 32, 449-452.

11.  Min Wang, Lingzhi Qiu, Mingyue Cui, Rongqiang Tian,* Zheng Duan,* François Mathey Mn₂(CO)₁₀ Catalyzed Intramolecular Dimerization of Diphosphirane Complexes, Organometallics, 2021, 40, 306-309.

12. Yanjie Liu, Rongqiang Tian,* Zheng Duan,* François Mathey Nonbenzenoid Aromaticity of 1-Phosphafulvenes: Synthesis of Phosphacymantrene, Dalton Transactions, 2021, 50, 476 - 479.

13. Yanjie Liu, Keke Zhang, Rongqiang Tian,* Zheng Duan,* and François Mathey，1,1-Addition of α‑C₂‑Bridged Biphospholes with Alkynes, Org. Lett. 2020, 22, 6972−6976.

14. Min Wang, Tingting Yang, Rongqiang Tian,* Donghui Wei, * Zheng Duan * and Francois Mathey, The chemistry of phosphirane-substituted phosphinidene complexes, Chem. Commun. 2020, 56, 9707-9710

15. Yang Xu, Chenyang Jiao, Juan Li, Rongqiang Tian,* Zheng Duan,* and François Mathey， An Approach to Peri-Fused Heterocycles: A Metal-Mediated Cascade Carbonylative Cyclization/Dearomatic Diels−Alder Reaction. Org. Lett. 2019, 21, 9512−9515

16.  Min Wang, Yang Xu, Donghui Wei, Rongqiang Tian,* Zheng Duan,* and Francois Mathey, Transition-Metal-Like Reversible Cycloadditions of [tBuSP-W(CO)5] with Alkenes and Alkynes. Chem. Eur. J. 2019, 25, 15036– 15039

17.  Yang Xu, Min Wang, Donghui Wei, Rongqiang Tian,* Zheng Duan* and François Mathey* An approach to 7-aza-1-phosphanorbornane complexes: strain promoted rearrangement of 1-iminylphosphirane complexes and cycloaddition with olefins. Dalton Trans. 2019, 48, 5523-5526

18. Jinkui Chai, Rongqiang Tian,* Di Wu, Donghui Wei, Qun Xu, Zheng Duan* and François Mathey,* The coordination chemistry of phosphinidenes sulfides. Synthesis and catalytic properties of Pd4 and Pt4 clusters. Dalton Trans. 2018, 47, 13342–13344

19. Rongqiang Tian,* Chunli Zhang, Yang Xu, Chenguang Liu, Zheng Duan,* and François Mathey, The Chemistry of 1-Acylphosphirane Complexes: A Phosphorus Analogue of the Cloke–Wilson Rearrangement, Chem. Eur. J. 2017, 23, 13006 – 13009

20. Zhengsong Hu, Rongqiang Tian,* Kang Zhao, Yanjie Liu, Zheng Duan,* and François Mathey ̧* Generation and Trapping of a 1‑Phosphafulvene: An Illustration of the P=C/C=C Analogy, Org. Lett. 2017, 19, 5004-5006

21.  Jonathan Wong, Yongxin Li, Yanwei Hao, Rongqiang Tian,* and François Mathey.* Isomerization of Secondary Phosphirane into Terminal Phosphinidene Complexes: An Analogy between Monovalent Phosphorus and Transition Metals. Angew. Chem. Int. Ed. 2015, 54, 12891 –12893
    

22. Zhengsong Hu, Zongyang Li, Kang Zhao, Rongqiang Tian,* Zheng Duan,*and François Mathey.* Reaction of Phospholes with Aldimines: A One-Step Synthesis of Chelating, Alpha-C₂-Bridged Biphospholes. Org. Lett. 2015, 17, 3518−3520

23. Rongqiang Tian, Hui Liu, Zheng Duan, and François Mathey, The Abnormal Hydrolysis of 7-Phosphanorbornenium Salts: A Case of Phosphonium-Phosphenium Equivalence. J. Am. Chem. Soc. 2009, 131, 16008-16009.