段征教授，博士生导师，硕士生导师
邮箱：duanzheng@zzu.edu.cn
电话：0371-67783392
课题组网站：
学术头衔/兼职：河南省特聘教授、河南省化学会常务理事、河南省优秀青年科技专家、河南省高等学校青年骨干教师、河南省教育厅学术技术带头人、中法有机磷功能材料国际联合实验室P.I.，河南省有机磷功能分子国际联合实验室副主任。
研究方向：有机磷化学、金属有机和有机合成方法学研究。
教育与工作简历：
2005-至今郑州大学化学学院（原化学系） 教授
2004-2005美国加州大学河滨分校化学系 博士后
2002-2003日本北海道大学触媒研究中心 博士后
1999-2002日本北海道大学药学部 药学博士
1995-1998河南师范大学化学系,河南省化学研究所 理学硕士
1991-1995郑州大学化学系 理学学士
代表性教学成果与荣誉：
2016年2015年河南省优秀硕士学位论文指导教师
2014年2013年河南省优秀硕士学位论文指导教师
2013年2012-2013学年郑州大学“三育人”先进个人
2013年2012年河南省优秀硕士学位论文指导教师
代表性科研成果：
一、主持科研项目
国家自然科学基金面上资助项目
2013.1-2016.12 含磷共轭分子的合成及性能研究
2011.1-2013.12 利用磷杂环戊二烯合成新型含磷功能分子的研究
2008.1-2010.12 从磷杂环戊二烯合成含磷大环化合物方法的研究
省部及其它基金资助项目
2019-2020电子封装及OLED电子专用材料绿色制造关键技术及设备系统集成，横向合作项目
2018-2020 绿色制造系统集成项目：电子封装及OLED电子专用材料绿色制造关键技术及设备系统集成，工信部
2013高等学校博士学科点专项科研基金，新型有机磷光电材料研究
2011河南省科技厅国际合作项目，有机磷功能化合物研究
2009 09年河南省高等学校青年骨干教师资助计划
二、近期论文论著
1. Yue Wang, Er-Qing Li, and Zheng Duan Ligand-Dependent, Palladium-Catalyzed Stereodivergent Synthesis of Chiral Tetrahydroquinolines. Chem. Sci., 2022, 13, 8131.
2. Junjian Wang, Haotian Luo, Xinghua Wang, Donghui Wei, Rongqiang Tian and Zheng Duan Dearomatization [4+2] Cycloaddition of Nonactivated Benzene Derivatives. Org. Lett. 2022, 24, 4404–4408
3. 郭泽，吴迪，王丽丽，段征 BF3·Et2O促进的双烯酮-酚重排合成具有AIE效应的磷杂七元环化合物. Chinese Journal of Organic Chemistry, 2022, 42(8): 2481-2487.
4. Junjian Wang, Jingrong Chen, Rongqiang Tian,* and Zheng Duan* Activation of CS2 with the 2H Phosphindole Complex to Construct P,S-Polycycles. Org. Lett. 2022, 24, 33, 6117–6121.
5. Zhipeng Zhang, Li Jing, Er-Qing Li, Zheng Duan Cooperative Palladium-Catalyzed and P(NEt2)3-Mediated (4+1) Annulation of Isatins with 2-Hydroxymethylallylcarbonates. Org. Chem. Front., 2022, 9, 3215.
6. 朱雪莉a, 杨绍丽a, 郏彩霞a, 李静b,*, 段征a,* 通过邻羟基苯基膦和醛的缩合反应合成苯并氧杂磷杂环戊烯. Chinese Journal of Organic Chemistry, 2022, 42(7): 2201-2213.
7. Mingyue Cui, Juan Li, Rongqiang Tian, Zheng Duan Tandem [5+1]/[8+2] Cycloaddition Reactions Involving Phosphiranes and Tropones: A Facile Access to 6,5,7- Fused Tricyclic Skeleton. Org. Chem. Front., 2022, 9, 2753.
8. Juan Ma, Lili Wang, Zheng Duan, Chemo- and Regioselectivity-Tunable Phosphination of Alkynes. Organic Letters, 2022, 24,1550-1555.
9. Ligang Xu, Di Wu, Wenxuan Lv, Yuan Xiang, Yan Liu, Ye Tao, Jun Yin*, Mengyuan Qian, Ping Li, Liuquan Zhang, Shufen Chen, Omar F. Mohammed, Osman M. Bakr, Zheng Duan, Runfeng Chen, Wei Huang. Resonance-mediated dynamic modulation of perovskite crystallization for efficient and stable solar cells.Adv. Mater. 2022, 34, 2107111.
10. Lingzhi Qiu, Qiaoyu Zhang, Donghui Wei, Rongqiang Tian * and Zheng Duan* Insight into fragmentation of a phosphirane to form phosphinidene complexes: an illustration with the 1-phenylselenylphosphirane W(CO)5 complex. Dalton Trans., 2022,51, 3046-3050.
11. Hong Li, Rongqiang Tian and Zheng Duan Intramolecular Activation of Enones by Electrophilic Phosphinidene Complexes to Construct 2-Phosphafurans. Org. Lett. 2022, 24, 767-770.
12. Guanyu Tao, Mengyang Bai, Zhenxing Liu, and Zheng Duan Intermolecular Cyclization between Carboranylphosphines and Electron-Deficient Alkynes. Organometallics 2022, 40， 4041-4044.
13. Bai Mengyang, Tao Guanyu, Liu Zhenxin, Wang Lili, Duan Zheng A facile access to mono-C-alkynylated-o-carboranes from o-carboranes and arylsulfonylacetylenes. Chin. Chem. Lett. 2022, 33， 201-204.
14. Keke Zhang, Qiaoyu Zhang, Donghui Wei, Rongqiang Tian, Zheng Duan Hetero-Diels-Alder Reactions of 2H-Phospholes with Allenes: Synthesis and Functionalization of 6-Methylene-1- phosphanorbornenes. Org. Chem. Front., 2021, 8, 3740-3745.
15. Siming Jia, Mengmeng Ma, Er-Qing Li, Zheng Duan, and Françis Mathey Design of 1 Phosphanorbornene Derivatives as Chiral Organocatalysts for Enantioselective (4 + 2) Annulation Reactions of γ Benzyl Allenoates. Org. Lett. 2021, 23, 3337-3342.
16. Yue Wang, Manman Song, Er-Qing Li and Zheng Duan Auto-Tandem Palladium/Phosphine Cooperative Catalysis: Synthesis of Bicyclo[3.1.0]hexenes by Selective Activation of Morita–Baylis–Hillman Carbonates. Org. Chem. Front.,2021,8,3366-3371.
17. Ke Li, Zhenjie Gan, Er-Qing Li,and Zheng Duan Phosphine-Catalyzed (4 + 2) Cycloaddition of Conjugated Dienes with Enones and Its Asymmetric Variant. Org. Lett. 2021, 3(8),3094-3099.1c00780.
18. Yanjie Liu, Xinyan Fan, Rongqiang Tian, Zheng Duan. FeCl2 Catalyzed Three-Component Reactions of Phospholes, Pyrrolidine, and Ketones (Aldehydes): Chemoselective Synthesis of 1-Phosphafulvenes. Org. Lett.2021, 23(8),2943-2947.
19. Juan Li, Mingyue Cui, Rongqiang Tian, Zheng Duan, François Mathey Cycloadditions of 1-iminylphosphirane complexes with allenes. Chin. Chem. Lett. 2021，32, 449-452.
20. Guanyu Tao,Feichao Yang, Lujun Zhang, Yang Li, Zheng Duan, François Mathey Synthesis of phosphanaphthalenes and nido-carborane fused six-membered phosphacycles. Chin. Chem. Let. 2021, 32, 194-197.
21. Min Wang, Lingzhi Qiu, Mingyue Cui, Rongqiang Tian, Zheng Duan, and François Mathey. Mn2(CO)10-Catalyzed Intramolecular Dimerization of Diphosphirane Complexes. Organometallics, 2021, 40, 3, 306–309.
22. Yanjie Liu, Rongqiang Tian, Zheng Duan, François Mathey Nobenzenoid Aromaticity of 1-Phosphafulvenes: Synthesis of Phosphacymantrene. Dalton Trans., 2021,50, 476-479.
23. Lili Wang, Juan Ma, Erbing Si, Zheng Duan Recent Advances in Luminescent Annulated Borepins, Silepins, and Phosphepins. Synthesis, 2021; 53, 623-635.
24. Junjian Wang, Donghui Wei, Zheng, Duan, Mathey François Cleavage of the Inert C(sp2)–Ar σ-Bond of Alkenes by a Spatial Constrained Interaction with Phosphinidene. J. Am. Chem. Soc. 2020, 142, 50, 20973–20978.
25. Yanjie Liu, Keke Zhang, Rongqiang Tian, Zheng Duan, and François Mathey 1,1-Addition of α-C2-Bridged Biphospholes with Alkynes. Org. Lett. 2020, 22, 6972–6976.
26. Min Wang, Tingting Yang, Rongqiang Tian, Donghui Wei, Zheng Duan, François Mathey. The chemistry of phosphirane-substituted phosphinidene complexes. Chem. Commun., 2020, 56, 9707-9710.
27. Wei Hu, Er-Qing Li, Zheng Duan and Francois Mathey, Concise synthesis of phospholene and its P-stereogenic derivatives. J. Org. Chem. 2020, 85, 14772–14778.
28. Hao Cui, Ke LI, Yue Wang, Manman Song, Congcong Wang, Donghui Wei,* Er-Qing Li,* Zheng Duan* and Francois Mathey, Copper(I)/Ganphos Catalysis: Enantioselective Synthesis of Diversified Spirooxindoles Using Alkyl Substituted Imino Ester and Methyleneindolinones. Org. Biomol. Chem., 2020, 18, 3740-3746.
29. Erbing Si, Peng Zhao, Lili Wang, Zheng Duan, and François Mathey : New access to six-membered phosphacycle annulated polyaromatic ring system. Eur. J. Org. Chem. 2020, 697–701
30. Yanying Song, Lili Wang, Zheng Duan, François Mathey Divergent Intramolecular Reactions between Phosphines and Alkynes. Chin. Chem. Lett. 2020， 31，329-332
三、科技奖励
2018年河南省第四届自然科学优秀学术论文一等奖1项，二等奖2项等
2014年教育部2013年度高等学校科学研究优秀成果奖(科学技术)金属有机化合物在催化偶联与制备发光材料中的应用（自然科学奖，第4（共9人））
2014年河南省教育厅科技成果奖（优秀科技论文）一等奖2项
2011年第十一届河南省青年科技奖
2010年第五届郑州市青年科技奖
四、近期专利
1. 手性1-磷杂降冰片二烯衍生物及其合成方法
发明人：段征，李二庆，支梦娜，甘贞洁
专利号：ZL 201811293457.X
2. 一种1,3-氮杂磷杂环戊二烯类化合物及其合成方法
发明人：段征吴迪马双良
专利号：ZL 201810283704.2
3. 一种苯并磷杂环戊二烯的合成方法
发明人：段征，周洋,王越,王文彪
专利号：ZL 201710116743.9