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李梦尧和万海斐同学在 Chemical Engineering Journal 发表论文
发布时间:2023-05-26

    近日,2020级硕士生李梦尧和2021级硕士生万海斐在SCI一区期刊 Chemical Engineering Journal(IF=16.744)合作发表1,3,5-三(苯乙炔)苯基共价有机框架荧光的调控其在信息加密解密和白光发光二极管中的应用论文“Linker engineering to regulate fluorescence of 1,3,5-tris(phenylacetylene) benzene-based covalent organic frameworks for white light-emitting diodes and information encryption and decryption”。

原文链接:https://doi.org/10.1016/j.cej.2023.143538

Abstract

Luminescent covalent organic frameworks (LCOFs) is a promising luminescent material with huge potential for various applications because it can integrate various chromophores into its porous ordered structure. A facile and effective approach to edit LCOFs emission is very necessary but remains a challenge. Herein, a rigidity-flexibility combination strategy to edit the luminescence properties of LCOFs was proposed by using a flexible fluorescent 1,3,5-tris(phenylacetylene) benzene with propeller-like conformation as center skeleton and linkers with different rigidity and conjugation degree. Since the conjugated degree of LCOFs’ frameworks depended on conformation of propeller-like 1,3,5-tris(phenylacetylene)benzene skeleton, the emission wavelengths of 1,3,5-tris (phenylacetylene)benzene-based LCOFs could be edited by linkers to tune conjugated degree of the frameworks. These 1,3,5-tris(phenylacetylene)benzene-based LCOFs emitted blue, green, yellow, orange and red light depending on the conjugation degree caused by the effect of the linkers of melem, terephthalic dihydrazide, hydrazine hydrate and p-phenylenediamine on the conformation of central skeleton. Binary or ternary mixed 1,3,5-tris(phenylacetylene)benzene-based LCOFs were used for white emission, white light-emitting diodes and information encryption/decryption. The work provides a simple yet efficient method to systematically edit the emission behaviors of LCOFs by linker engineering.