朱广山 - 哈尔滨师范大学

研究领域

功能无机孔材料的合成与组装一、不同凝聚态分子筛孔材料的合成、制备与功能研究　分子筛孔材料是具有规则孔道或笼无机非金属材料。本研究主要通过选择反应原料、调整反应配比、优化反应条件和使用新颖的合成技术进行不同凝聚态分子筛孔材料的合成、制备与功能组装。同时研究分子筛孔材料生长机理、光电磁性质、气体或有机分子分离性质和催化性能等。 1.分子筛纳米晶的合成。分子筛纳米晶的合成与制备对晶体表面科学、生长机理，催化，制备反应膜等具有重要的作用。 2.分子筛大单晶的合成与组装及性能研究。高质量分子筛大单晶的合成对材料晶体结构、晶体生长机理、纳米复合材料、主客体材料、光电磁微器件研究方面有重要意义。 3.分子筛有序膜的合成与制备及性能研究。分子筛膜因其规则的微孔结构和良好的化学稳定性，使其在工业分离与催化领域有着广泛的应用背景。二、新型金属有机刚性骨架（MOF）结构的设计合成与制备化学　本研究利用刚性带有多节点羧基或胺基的环状、链状、枝状和手性配体为有机构筑基元，过渡金属离子或金属氧簇为无机构筑单元，合成具有特殊孔道，大孔道或手性孔道，高孔体积的金属有机刚性骨架纳米孔材料，并对其热稳定性、储氢、分子识别等性质进行系统的研究。包括： 1.大孔径金属有机骨架新材料开发。这一研究是近年无机材料化学研究的一个全新热点领域。由于特殊的骨架特征以及开阔的孔道结构而表现出优异的吸附性能，是理想的储氢材料。 2.具有手性孔道的金属有机骨架结构的设计合成。

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Zheng, L. Y.; Zhang, S. Q.; Zhao, L. F.; Zhu, G. S.; Yang, X. Y.; Gao, G.; Cao, S. G., Resolution of N-(2-ethyl-6-methylphenyl)alanine via free and immobilized lipase from Pseudomonas cepacia. Journal of Molecular Catalysis B-Enzymatic 2006, 38, (3-6), 119-125. Zhao, L.; Zhu, G. S.; Zhang, D. L.; Di, Y.; Qiu, S. L., Synthesis and characterization of mesoporous silica marterial with partly-ordered pore walls. Chemical Journal of Chinese Universities-Chinese 2006, 27, (2), 208-211. Zhang, Z. D.; Yan, X. X.; Tian, B. Z.; Yu, C. Z.; Tu, B.; Zhu, G. S.; Qiu, S. L.; Zhao, D. Y., Synthesis of ordered small pore mesoporous silicates with tailorable pore structures and sizes by polyoxyethylene alkyl amine surfactant. Microporous and Mesoporous Materials 2006, 90, (1-3), 23-31. Xue, M.; Zhu, G. S.; Fang, Q. R.; Guo, X. D.; Qiu, S. L., Design, structure and properties of a novel 3D metal-organic framework constructed from N-donor ligand supporting Cd(II)-carboxylate layer. Inorganic Chemistry Communications 2006, 9, (6), 603-606. Xue, M.; Zhu, G. S.; Fang, Q. R.; Guo, X. D.; Qiu, S. L., Solvothermal synthesis, structure and magnetism of two novel 3D metal-organic frameworks based on infinite helical Mn-O-C rod-shaped building units. Journal of Molecular Structure 2006, 796, (1-3), 165-171. Xu, R.; Zhu, G. S.; Yin, X. J.; Wan, X.; Qiu, S. L., In situ growth of AlPO4-5 molecular sieve on stainless steel support. Microporous and Mesoporous Materials 2006, 90, (1-3), 39-44. Xu, R.; Zhu, G. S.; Yin, X. J.; Wan, X.; Qiu, S. L., Epitaxial growth of highly-oriented AlPO4-5 molecular sieve films for microlaser systems. Journal of Materials Chemistry 2006, 16, (22), 2200-2204. Wang, C. Y.; Zhu, G. S.; Gao, B.; Wang, R. W.; Li, J.; Xin, M. H.; Qiu, S. L., In-situ synthesis and activity of nano-hydroxyapatite/lysozyme composite. Chemical Journal of Chinese Universities-Chinese 2006, 27, (8), 1421-1423. Tian, G.; Zhu, G. S.; Fang, Q. R.; Xin, M. H.; Guo, X. D.; Xue, M.; Qiu, S. L., Synthesis, structure of a novel two-dimensional inorganic-organic framework Ni(PDC) (H2O)(2) with double helical chains. Chemical Journal of Chinese Universities-Chinese 2006, 27, (6), 1020-1022. Tian, G.; Zhu, G. S.; Fang, Q. R.; Guo, X. D.; Xue, M.; Sun, J. Y.; Qiu, S. L., Design, synthesis and fluorescence of two-dimensional pillared layers by connecting infinite one-dimensional chains via 4,4 '-bipyridine. Journal of Molecular Structure 2006, 787, (1-3), 45-49. Sun, J. Y.; Zhou, Y. M.; Fang, Q. R.; Chen, Z. X.; Weng, L. H.; Zhu, G. S.; Qiu, S. L.; Zhao, D. Y., Construction of 3D layer-pillared homoligand coordination polymers from a 2D layered precursor. Inorganic Chemistry 2006, 45, (21), 8677-8684. Sun, J. Y.; Zhou, Y. M.; Chen, Z. X.; Zhu, G. S.; Fang, Q. R.; Yang, R. J.; Qiu, S. L.; Zhao, D. Y., Solvothermal synthesis and removal capacity for hydrogen chloride gas of Zn(OH)(NO3)with a rare (10,3)-d net. Journal of Solid State Chemistry 2006, 179, (4), 1230-1236. Sun, F. X.; Zhu, G. S.; Ye, L.; Fang, Q. R.; Qiu, S. L., Synthesis and crystal structure of a 3D metal-organic framework microporous compound Cd-5 (BTC)(4)(H2O)(8) center dot 6H(2)O. Chemical Journal of Chinese Universities-Chinese 2006, 27, (8), 1418-1420. Shi, C. F.; Wang, R. W.; Zhu, G. S.; Qiu, S. L.; Long, J., In situ synthesis, characterization of SiPMo-X, and different catalytic properties of SiPMo-X and SiPW-X. European Journal of Inorganic Chemistry 2006, (15), 3054-3060. Shi, C. F.; Wan, L. F.; Wang, R. W.; Long, J.; Zhu, G. S.; Qiu, S. L., Synthesis and characterization of a new HPMo/SBA-15 composite. Chemical Journal of Chinese Universities-Chinese 2006, 27, (7), 1194-1197. Qu, F. Y.; Zhu, G. S.; Lin, H. M.; Zhang, W. W.; Sun, J. Y.; Li, S. G.; Qiu, S. L., A controlled release of ibuprofen by systematically tailoring the morphology of mesoporous silica materials. Journal of Solid State Chemistry 2006, 179, (7), 2027-2035. Qu, F. Y.; Zhu, G. S.; Lin, H. M.; Zhang, W. W.; Li, S. G.; Qiu, S. L., Synthesis of mesoporous silica with spiral morphology by using chiral anionic surfactant. Chemical Journal of Chinese Universities-Chinese 2006, 27, (4), 602-604. Qu, F. Y.; Zhu, G. S.; Lin, H. M.; Sun, J. Y.; Zhang, D. L.; Li, S. G.; Qiu, S. L., Drug self-templated synthesis of ibuprofen/mesoporous silica for sustained release. European Journal of Inorganic Chemistry 2006, (19), 3943-3947. Qu, F. Y.; Zhu, G. S.; Huang, S. Y.; Li, S. G.; Sun, J. Y.; Zhang, D. L.; Qiu, S. L., Controlled release of Captopril by regulating the pore size and morphology of ordered mesoporous silica. Microporous and Mesoporous Materials 2006, 92, (1-3), 1-9. Qu, F. Y.; Zhu, G. S.; Huang, S. Y.; Li, S. G.; Qiu, S. L., Effective controlled release of captopril by silylation of mesoporous MCM-41. Chemphyschem 2006, 7, (2), 400-406.