段伟良 - 扬州大学 - 化学化工学院（创新材料与能源研究院）

个人简介

2007年3月获京都大学理学博士学位 2007至2008年在美国伊利诺伊大学香槟分校化学系从事博士后研究 2008年8月加入中国科学院上海有机化学研究所任副研究员课题组长，独立开展研究工作，14年6月起任研究员 2016年任扬州大学特聘教授 2017年入选江苏省“双创人才”

研究领域

1. 过渡金属催化惰性碳氢键活化反应的研究 2. 不对称催化：包括手性配体的合成应用和不对称催化反应的研究

近期论文

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Xu, B.-B.; Ye, J.; Yuan, Y.; Duan, W.-L.* Palladium-Catalyzed Asymmetric C−H Arylation for the Synthesis of Planar Chiral Benzothiophene-Fused Ferrocenes. ACS Catalysis 2018, 8, 11735. Li, Z.; Duan, W.-L.* Palladium-Catalyzed C-H Alkenylation of Arenes with Alkynes: Stereoselective Synthesis of Vinyl Chlorides via a 1,4-Chlorine Migration. Angew. Chem. Int. Ed. 2018, 57, 16041. Dai, G.-F.; Song, Y.-C.; Xoap, F.;* Duan, W.-L.* Palladium-Catalyzed Asymmetric 1,4-Addition of Diarylphosphines to α,β-Unsaturated Sulfonamides. Synthesis 2018, 50, 3506. Zhu, T.; Li, Z.; Xiao, F.;* Duan, W.-L.* Pd-catalyzed oxidative homo-coupling of acrylates and aromatic alkenes for the conjugated diene synthesis. Tetrhedron Lett. 2018, 59, 3238. Wei, X.; Duan, W.-L.* Palladium-Catalyzed Asymmetric 1,6-Addition of Diarylphosphines to Allylidenemalonates for Chiral Phosphine Synthesis. Synthesis 2016, 48, 4155. Zhu, T.; Li, Z.; Xiao, F.;* Duan, W.-L.* Palladium-catalyzed enantioselective hydrophosphination of enones for the synthesis of chiral P,N-compounds. Tetrhedron Lett. 2016, 57, 2990. Li, Z.; Duan, W.-L.* Recent Advances in the Asymmetric Conjugate Addition Reactions of Phosphorus Nucleophiles to Electron-Deficient Alkenes. Chin. J. Org. Chem. 2016, 36, 1805. Zhang, S.; Lu, J.; Ye, J.;* Duan, W.-L.* Asymmetric C—H Arylation for the Synthesis of Planar Chiral Ferrocenes: Controlling Enantioselectivity Using Chiral Phosphoric Acids. Chin. J. Org. Chem. 2016, 36, 752. Lin, Z.-Q.; Wang, W.-Z.; Yan, S.-B.; Duan, W.-L.*. Palladium-Catalyzed Enantioselective C–H Arylation for the Synthesis of P-Stereogenic Compounds. Angew. Chem. Int. Ed. 2015, 54, 6265. Yan,S.-B.; Zhang, S.; Duan, W.-L.* Palladium-Catalyzed Asymmetric Arylation of C(sp3)–H Bonds of Aliphatic Amides: Controlling Enantioselectivity Using Chiral Phosphoric Amides/Acids. Org. Lett. 2015, 17, 2458. Ying, C.-H.; Duan, W.-L.* Palladium-Catalyzed Direct C–H Allyation of Arenes without Directing Groups, Org. Chem. Front. 2014, 1, 546. Li, C.; Li, W.-X.; Xu, S.; Duan, W.-L.* Palladium-Catalyzed 1,4-Addition of Secondary AlkylphenylPhosphines to α,β-Unsaturated Carbonyl Compounds for the Synthesis of Phosphorus- and Carbon-Stereogenic Compounds. Org. Chem. Front. 2014, 1, 541. Chen, Y.-R.; Duan, W.-L.* Palladium-Catalyzed Intramolecular Direct Arylation for Phosphorus Heterocycle Synthesis. Synthesis. 2014, 46, 1067. Ying, C.-H.; Yan, S.-B.; Duan, W.-L.* 2-Hydroxy-1,10-phenanthroline vs 1,10-Phenanthroline: Significant Ligand Acceleration Effects in the Palladium-Catalyzed Oxidative Heck Reaction of Arenes. Org. Lett. 2014, 16, 500. Huang, J.; Zhao, M.-X.; Duan, W.-L.* Palladium-Catalyzed Asymmetric 1,6-Addition of Diphenylphosphine to (4-Aryl-1,3-butadienylidene)bis(phosphonates) for the Synthesis of Chiral Phosphines. Tetrahedron: Lett. 2014, 55, 629. Chen, Y.-R.; Feng, J.-J.; Duan, W.-L.* NHC–Copper-Catalyzed Asymmetric 1,4-Addition of Diarylphosphines to α,β-Unsaturated Ketones. Tetrahedron: Lett. 2014, 55, 595. Lu, J.; Ye, J.; Duan, W.-L.* Palladium-Catalyzed Asymmetric 1,6-Addition of Diarylphosphines to a,ß,c,d-Unsaturated Sulfonic Esters: Controlling Regioselectivity by Rational Selection of Electron-Withdrawing Groups. Chem. Commun. 2014, 50, 698. Chen, Y.-R.; Duan, W.-L.* Silver-Mediated Oxidative C–H/P–H Functionalization: An Efficient Route for the Synthesis of Benzo[b]phosphole Oxides. J. Am. Chem. Soc. 2013, 135, 16754. Lu, J.; Ye, J.; Duan, W.-L.* Palladium-Catalyzed Asymmetric Addition of Diarylphosphines to α,β-Unsaturated Sulfonic Esters for the Synthesis of Chiral Phosphine Sulfonate Compounds. Org. Lett. 2013, 15, 5016. Li, C.; Li, W.-X.; Xu, S.; Duan, W.-L.* Pd-Catalyzed Asymmetric Alkylation of Methylphenylphosphine with Alkyl Halides for the Synthesis of P-stereogenic Compounds. Chin. J. Org. Chem. 2013, 33, 799.