沈明 - 华东师范大学 - 物理与电子科学学院

个人简介

教育经历 2006-2010：华东理工大学本科 2010-2015：华东师范大学硕博连读（无线电物理） 2012-2014：法国里尔大学高场核磁共振中心联合培养博士研究生（分子与凝聚态物质）

研究领域

固体磁共振(Solid-state NMR)方法学与应用方法学研究方向：（1）Paramagnetic NMR实验技术与第一性原理计算NMR、EPR参数（2）超快魔角旋转条件(fast/ultra-fast MAS)下的同核/异核相关谱学方法（3）四极核表征方法应用研究方向：（1）全固态电池中的固体电解质和界面（2）锂离子电池正极充放电机制与容量衰减机制（3）NMR crystallography(磁共振+DFT计算)研究无机晶体、非晶材料中的局域结构技术专长：高级固体核磁共振技术方法高分辨一维技术：同核去耦、背景信号抑制伪二维分辨技术： MAT/PASS/MATPASS/pj-MATPASS 二维同核与异核技术： HECTOR/DHMQC、HSQC/PRESTO/REDOR、SRESPDOR NOESY/fp-RFDR/DQ-SQ 面向四极核技术：solid-echo/14N overtone/CPMG、QCPMG、WURST-CPMG/STMAS、MQMAS

近期论文

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Inconsistency between superstructure stability and long-term cyclability of oxygen redox in Na layered oxides Energy & Environmental Science 2024 | Journal article DOI: 10.1039/D3EE02915H CONTRIBUTORS: Hui Liu; Chong Zhao; Xiang Wu; Chunjing Hu; Fushan Geng; Ming Shen; Bei Hu; Bingwen Hu; Chao Li Unexpected temperature dependence of 1H paramagnetic shift in MAS NMR of nickelocene Magnetic Resonance Letters 2024-03 | Journal article DOI: 10.1016/j.mrl.2024.200119 CONTRIBUTORS: Xinbiao Jiang; Jiefan Liu; Xiaobing Lou; Bingwen Hu; Ming Shen Measuring T1 relaxation in paramagnetic solids with solid-state NMR: a case study on the milling induced phase transition in Li6CoO4 Physical Chemistry Chemical Physics 2023 | Journal article DOI: 10.1039/D3CP00757J CONTRIBUTORS: Nianrui Guo; Fushan Geng; Guozhong Lu; Xinbiao Jiang; Chao Li; Bingwen Hu; Ming Shen Probing the degradation of LiCoO2 in batteries subjected to high-voltage cycling with 17O solid-state NMR spectroscopy Chemical Communications 2023 | Journal article DOI: 10.1039/D3CC02547K CONTRIBUTORS: Guozhong Lu; Fushan Geng; Nianrui Guo; Shouquan Yao; Ming Shen; Bingwen Hu Probing microstructure of solid-state synthesized LiCoO2 with MAS NMR spectroscopy Magnetic Resonance Letters 2023-11 | Journal article DOI: 10.1016/j.mrl.2023.01.001 CONTRIBUTORS: Suyu Gu; Guozhong Lu; Nianrui Guo; Juncheng Xu; Yu Jiang; Ming Shen; Bingwen Hu “Win‐Win” Modification of LiCoO2 Enables Stable and Long‐Life Cycling of Sulfide‐Based All Solid‐State Batteries ChemSusChem 2023-10-20 | Journal article DOI: 10.1002/cssc.202300517 CONTRIBUTORS: Guozhong Lu; Ying Jiang; Xiang Wu; Fushan Geng; Chao Li; Bingwen Hu; Ming Shen The study of electrochemical cycle for LiCoO2 by dual-mode EPR Magnetic Resonance Letters 2023-02 | Journal article DOI: 10.1016/j.mrl.2022.04.002 CONTRIBUTORS: Bei Hu; Fushan Geng; Ming Shen; Bingwen Hu Vanadium dissolution at 30 °C and its suppression at a low temperature of ?20 °C for a Na3V1.5Cr0.5(PO4)3 cathode Chemical Communications 2022 | Journal article DOI: 10.1039/D2CC02715A CONTRIBUTORS: Yuxin Liao; Fushan Geng; Yu Jiang; Ming Shen; Bingwen Hu Sb@Ni6 superstructure units stabilize Li-rich layered cathode in the wide voltage window Journal of Power Sources 2022-12 | Journal article DOI: 10.1016/j.jpowsour.2022.232148 CONTRIBUTORS: Bo Cao; Yiwei Li; Mingjian Zhang; Ningyan Cheng; Ming Shen; Bingwen Hu; Jianyuan Li; Zhibo Li; Shenyang Xu; Wenguang Zhao et al. Quantitative and space-resolved in situ 1D EPR imaging for the detection of metallic lithium deposits The Journal of Chemical Physics 2022-11-07 | Journal article DOI: 10.1063/5.0125080 CONTRIBUTORS: Fushan Geng; Guozhong Lu; Yuxin Liao; Ming Shen; Bingwen Hu Tailoring Anionic Redox Activity in a P2-Type Sodium Layered Oxide Cathode via Cu Substitution ACS Applied Materials & Interfaces 2022-06-29 | Journal article DOI: 10.1021/acsami.2c02858 CONTRIBUTORS: Bei Hu; Qing Qiu; Chao Li; Ming Shen; Bingwen Hu; Wei Tong; Kunchan Wang; Qingping Zhou; Yanming Zhang; Zhiyan He et al. A multifunctional manipulation to stabilize oxygen redox and phase transition in 4.6 V high-voltage LiCoO2 with sXAS and EPR studies Journal of Power Sources 2021-12 | Journal article DOI: 10.1016/j.jpowsour.2021.230661 CONTRIBUTORS: Bei Hu; Fushan Geng; Ming Shen; Chong Zhao; Qing Qiu; Yang Lin; Changxin Chen; Wen Wen; Shun Zheng; Xiaoshi Hu et al. Operando EPR and EPR Imaging Study on a NaCrO2 Cathode: Electronic Property and Structural Degradation with Cr Dissolution The Journal of Physical Chemistry Letters 2021-01-21 | Journal article DOI: 10.1021/acs.jpclett.0c03327 CONTRIBUTORS: Fushan Geng; Qi Yang; Chao Li; Bei Hu; Chong Zhao; Ming Shen; Bingwen Hu A rings-in-pores net: crown ether-based covalent organic frameworks for phase-transfer catalysis Chemical Communications 2020 | Journal article DOI: 10.1039/C9CC07639E CONTRIBUTORS: Ji-Chuang Shen; Wei-Ling Jiang; Wen-Di Guo; Qiao-Yan Qi; De-Li Ma; Xiaobing Lou; Ming Shen; Bingwen Hu; Hai-Bo Yang; Xin Zhao Anionic redox reactions and structural degradation in a cation-disordered rock-salt Li1.2Ti0.4Mn0.4O2 cathode material revealed by solid-state NMR and EPR Journal of Materials Chemistry A 2020 | Journal article DOI: 10.1039/D0TA03358H CONTRIBUTORS: Fushan Geng; Bei Hu; Chao Li; Chong Zhao; Olivier Lafon; Julien Trébosc; Jean-Paul Amoureux; Ming Shen; Bingwen Hu Superionic Conductors via Bulk Interfacial Conduction Journal of the American Chemical Society 2020-10-21 | Journal article DOI: 10.1021/jacs.0c07060 CONTRIBUTORS: Chenji Hu; Yanbin Shen; Ming Shen; Xi Liu; Hongwei Chen; Chenghao Liu; Tuo Kang; Feng Jin; Li Li; Jing Li et al. Deciphering the Origin of High Electrochemical Performance in a Novel Ti-Substituted P2/O3 Biphasic Cathode for Sodium-Ion Batteries ACS Applied Materials & Interfaces 2020-09-16 | Journal article DOI: 10.1021/acsami.0c11427 CONTRIBUTORS: Bei Hu; Fushan Geng; Chong Zhao; Bertrand Doumert; Julien Trébosc; Olivier Lafon; Chao Li; Ming Shen; Bingwen Hu Simple Transformation of Covalent Organic Frameworks to Highly Proton-Conductive Electrolytes ACS Applied Materials & Interfaces 2020-02-19 | Journal article DOI: 10.1021/acsami.9b19953 CONTRIBUTORS: Bin Zhou; Jiabo Le; Zhangyuan Cheng; Xuan Zhao; Ming Shen; Maoling Xie; Bingwen Hu; Xiaodong Yang; Liwei Chen; Hongwei Chen Unraveling the Critical Role of Ti Substitution in P2-NaxLiyMn1–yO2 Cathodes for Highly Reversible Oxygen Redox Chemistry Chemistry of Materials 2020-02-11 | Journal article DOI: 10.1021/acs.chemmater.9b03765 CONTRIBUTORS: Chao Li; Chong Zhao; Bei Hu; Wei Tong; Ming Shen; Bingwen Hu Monitoring the evolution of local oxygen environments during LiCoO2 charging via ex situ17O NMR Chemical Communications 2019 | Journal article DOI: 10.1039/C9CC03304A CONTRIBUTORS: Fushan Geng; Ming Shen; Bei Hu; Yufeng Liu; Lecheng Zeng; Bingwen Hu Retarding Phase Transformation During Cycling in a Lithium‐ and Manganese‐Rich Cathode Material by Optimizing Synthesis Conditions ChemElectroChem 2019-03 | Journal article DOI: 10.1002/celc.201801739 CONTRIBUTORS: Bei Hu; Xiaobing Lou; Chao Li; Fushan Geng; Mengchu Yang; Ming Shen; Bingwen Hu Reversible High-Voltage N-Redox Chemistry in Metal–Organic Frameworks for High-Rate Anion-Intercalation Batteries ACS Applied Energy Materials 2019-01-28 | Journal article DOI: 10.1021/acsaem.8b01428 CONTRIBUTORS: Xiaobing Lou; Fushan Geng; Bei Hu; Chao Li; Ming Shen; Bingwen Hu Bimetallic zeolite imidazolate framework for enhanced lithium storage boosted by the redox participation of nitrogen atoms Science China Materials 2018 | Journal article DOI: papers3://publication/doi/10.1007/s40843-017-9200-5 CONTRIBUTORS: Lou, Xiaobing; Ning, Yanqun; Li, Chao; Hu, Xiaoshi; Shen, Ming; Hu, Bingwen Carbon-coated Li 3 V 2 (PO 4 ) 3 derived from metal-organic framework as cathode for lithium-ion batteries with high stability Electrochimica Acta 2018 | Journal article DOI: 10.1016/j.electacta.2018.03.100 CONTRIBUTORS: Liao, Yuxing; Li, Chao; Lou, Xiaobing; Hu, Xiaoshi; Ning, Yanqun; Yuan, Fengyi; Chen, Bo; Shen, Ming; Hu, Bingwen High-fidelity spectroscopy reconstruction in accelerated NMR Chemical Communications 2018 | Journal article DOI: 10.1039/C8CC06132G CONTRIBUTORS: Xiaobo Qu; Tianyu Qiu; Di Guo; Hengfa Lu; Jiaxi Ying; Ming Shen; Bingwen Hu; Vladislav Orekhov; Zhong Chen Indirect detection of broad spectra in solid-state NMR using interleaved DANTE trains Journal of Magnetic Resonance 2018 | Journal article DOI: papers3://publication/doi/10.1016/j.jmr.2018.07.005 CONTRIBUTORS: Li, Yixuan; Tr??bosc, Julien; Hu, Bingwen; Shen, Ming; Amoureux, Jean-Paul; Lafon, Olivier The electrochemical Na intercalation/extraction mechanism of ultrathin cobalt(II) terephthalate-based MOF nanosheets revealed by synchrotron X-ray absorption spectroscopy Energy Storage Materials 2018 | Journal article DOI: 10.1016/j.ensm.2018.02.021 CONTRIBUTORS: Li, Chao; Yang, Qi; Shen, Ming; Ma, Jingyuan; Hu, Bingwen Reduction of the 13C cross-polarization experimental time for pharmaceutical samples with long T1 by ball milling in solid-state NMR Solid State Nuclear Magnetic Resonance 2018-10 | Journal article DOI: 10.1016/j.ssnmr.2018.08.001 CONTRIBUTORS: Xiaobing Lou; Ming Shen; Chao Li; Qun Chen; Bingwen Hu A new insight into the lithium storage mechanism of sulfurized polyacrylonitrile with no soluble intermediates Energy Storage Materials 2018-09 | Journal article DOI: 10.1016/j.ensm.2018.04.013 CONTRIBUTORS: Zhao-Qing Jin; Yong-Gang Liu; Wei-Kun Wang; An-Bang Wang; Bing-Wen Hu; Ming Shen; Tong Gao; Peng-Cheng Zhao; Yu-Sheng Yang Exploring the Capacity Limit: A Layered Hexacarboxylate-Based Metal–Organic Framework for Advanced Lithium Storage Inorganic Chemistry 2018-03-19 | Journal article DOI: 10.1021/acs.inorgchem.7b02939 CONTRIBUTORS: Xiaobing Lou; Yanqun Ning; Chao Li; Ming Shen; Bei Hu; Xiaoshi Hu; Bingwen Hu Composite pulses in directly and indirectly detected (14)N MAS overtone spectroscopy Solid State Nucl Magn Reson 2017 | Journal article DOI: 10.1016/j.ssnmr.2017.01.007 10.1016/j.ssnmr.2017.01.007. Epub 2017 Feb 3. CONTRIBUTORS: Shen, M.; Chen, Q.; Hu, B. ECNU-10 zeolite: A three-dimensional MWW-Type analogue Microporous and Mesoporous Materials 2017 | Journal article DOI: 10.1016/j.micromeso.2017.07.004 CONTRIBUTORS: Ji, P.; Shen, M.; Lu, K.; Hu, B. W.; Jiang, J. G.; Xu, H.; Wu, P. High-capacity cobalt-based coordination polymer nanorods and their redox chemistry triggered by delocalization of electron spins Energy Storage Materials 2017 | Journal article DOI: 10.1016/j.ensm.2017.02.002 CONTRIBUTORS: Li, C.; Lou, X. B.; Shen, M.; Hu, X. S.; Yan, W. S.; Zou, Y. M.; Tong, W.; Hu, B. W. Minimizing the t 1 -noise when using an indirect 1 H high-resolution detection of unlabeled samples Solid State Nuclear Magnetic Resonance 2017 | Journal article DOI: 10.1016/j.ssnmr.2017.06.008 CONTRIBUTORS: Shen, Ming; Wegner, S.; Tr??bosc, J.; Hu, B.; Lafon, O.; Amoureux, J. P. Room-temperature synthesis of a cobalt 2,3,5,6-tetrafluoroterephthalic coordination polymer with enhanced capacity and cycling stability for lithium batteries New Journal of Chemistry 2017 | Journal article DOI: 10.1039/C6NJ03165J CONTRIBUTORS: Xiaobing Lou; Xiaoshi Hu; Chao Li; Yanqun Ning; Qun Chen; Ming Shen; Bingwen Hu Highly reversible lithium storage in cobalt 2,5-dioxido-1,4-benzenedicarboxylate metal-organic frameworks boosted by pseudocapacitance Journal of Colloid and Interface Science 2017-11 | Journal article DOI: 10.1016/j.jcis.2017.07.063 CONTRIBUTORS: Yuxing Liao; Chao Li; Xiaobing Lou; Peng Wang; Qi Yang; Ming Shen; Bingwen Hu Ultrathin Manganese-Based Metal–Organic Framework Nanosheets: Low-Cost and Energy-Dense Lithium Storage Anodes with the Coexistence of Metal and Ligand Redox Activities ACS Applied Materials & Interfaces 2017-09-06 | Journal article DOI: 10.1021/acsami.7b09363 CONTRIBUTORS: Chao Li; Xiaoshi Hu; Wei Tong; Wensheng Yan; Xiaobing Lou; Ming Shen; Bingwen Hu Mesoporous Cobalt 2, 5-thiophenedicarboxylic Coordination Polymer for High Performance Na-ion Batteries Materials Letters 2017-01 | Journal article DOI: 10.1016/j.matlet.2017.01.126 CONTRIBUTORS: Yanqun Ning; Xiaobing Lou; Ming Shen; Bingwen Hu A thermally activated manganese 1,4-benzenedicarboxylate metal organic framework with high anodic capability for Li-ion batteries New J. Chem. 2016 | Journal article DOI: 10.1039/c6nj02179d CONTRIBUTORS: Hu, Huiping; Lou, Xiaobing; Li, Chao; Hu, Xiaoshi; Li, Tian; Chen, Qun; Shen, Ming; Hu, Bingwen Al-doped SBA-15 catalysts for low-temperature dehydration of 1,3-butanediol into butadiene ChemCatChem 2016 | Journal article DOI: papers3://publication/doi/10.1002/cctc.201601202 CONTRIBUTORS: Pera-Titus, Marc; Jing, Fangli; Katryniok, Benjamin; Paul, Sebastien; Fang, Lin; Liebens, Armin; Shen, Ming; Hu, Bingwen; Dumeignil, Franck Broad-band excitation in indirectly detected 14N overtone spectroscopy with composite pulses Solid State Nuclear Magnetic Resonance 2016 | Journal article DOI: 10.1016/j.ssnmr.2016.05.001 CONTRIBUTORS: Shen, Ming; Chen, Qun; Amoureux, Jean-Paul; Hu, Bingwen Capacity control of ferric coordination polymers by zinc nitrate for lithium-ion batteries RSC Adv. 2016 | Journal article DOI: 10.1039/c6ra17608a CONTRIBUTORS: Lou, Xiaobing; Hu, Huiping; Li, Chao; Hu, Xiaoshi; Li, Tian; Shen, Ming; Chen, Qun; Hu, Bingwen Elimination of the baseline distortions in WURST-CPMG static experiments Solid State Nuclear Magnetic Resonance 2016 | Journal article DOI: 10.1016/j.ssnmr.2016.05.002 CONTRIBUTORS: Peng, Bo; Shen, Ming; Amoureux, Jean-Paul; Hu, Bingwen Facile synthesis of the Basolite F300-like Nanoscale Fe-BTC Framework and its Lithium Storage Properties RSC Adv. 2016 | Journal article DOI: papers3://publication/doi/10.1039/C6RA22738D CONTRIBUTORS: Hu, Xiaoshi; Lou, Xiaobing; Li, Chao; Ning, Yanqun; Liao, Yuxing; Chen, Qun; Mananga, Euge?ne S.; Shen, Ming; Hu, Bingwen High Anodic Performance of Co 1,3,5-Benzenetricarboxylate Coordination Polymers for Li-Ion Battery ACS Applied Materials & Interfaces 2016 | Journal article DOI: 10.1021/acsami.6b03648 CONTRIBUTORS: Li, Chao; Lou, Xiaobing; Shen, Ming; Hu, Xiaoshi; Guo, Zhi; Wang, Yong; Hu, Bingwen; Chen, Qun Reversible lithium storage in manganese and cobalt 1,2,4,5-benzenetetracarboxylate metal–organic framework with high capacity RSC Adv. 2016 | Journal article DOI: 10.1039/c6ra07727g CONTRIBUTORS: Li, Tian; Li, Chao; Hu, Xiaoshi; Lou, Xiaobing; Hu, Huiping; Pan, Likun; Chen, Qun; Shen, Ming; Hu, Bingwen The organic-moiety-dominated Li+ intercalation/deintercalation mechanism of a cobalt-based metal–organic framework Journal of Materials Chemistry A 2016 | Journal article DOI: 10.1039/C6TA06413B CONTRIBUTORS: Chao Li; Xiaoshi Hu; Xiaobing Lou; Lijuan Zhang; Yong Wang; Jean-Paul Amoureux; Ming Shen; Qun Chen; Bingwen Hu Comparison of various NMR methods for the indirect detection of nitrogen-14 nuclei via protons in solids Journal of Magnetic Resonance 2015 | Journal article DOI: 10.1016/j.jmr.2015.06.008 CONTRIBUTORS: Shen, Ming; Trébosc, Julien; O'Dell, Luke A.; Lafon, Olivier; Pourpoint, Frédérique; Hu, Bingwen; Chen, Qun; Amoureux, Jean-Paul