Ma, Shengqian - University of South Florida

个人简介

Shengqian Ma obtained his B.S. degree from Jilin University, China in 2003, and graduated from Miami University (Ohio) with a Ph.D. degree under the supervision of Hong-Cai Joe Zhou (currently at Texas A&M University) in 2008. After finishing two-year Director’s Postdoctoral Fellowship at Argonne National Laboratory, he joined the Department of Chemistry at University of South Florida (USF) as an Assistant Professor in August 2010. He was promoted to an Associate Professor with early tenure in 2015 and to a Full Professor in 2018. He received the 2015 USF Faculty Outstanding Research Achievement Award and 2018 Outstanding Faculty Award. He is the recipient of 2014 NSF CAREER Award and has beenselected as the Thomson Reuters Highly Cited Researcher in 2014, 2015, 2016, 2017, 2018, and 2019; he was also awarded the IUPAC-2015 Young Chemist Travel Award and the 2009 IUPAC Prize for Young Chemists from International Union of Pure & Applied Chemistry (IUPAC); hereceived the Young Investigator Award from American Chemical Society (ACS) Division of Inorganic Chemistry and the Director’s Postdoctoral Fellowship from Argonne National Laboratory in 2008 as well. His current research interest focuses on the development of functional porous materials including metal-organic frameworks (MOFs), covalent organic frameworks (COFs), porous organic polymers (POPs), and microporous carbon materials for energy, biological, environmental-related applications. He has published more than 220 papers (over 180 since independent career) with the total citations over 22000 and the H-index of 77. Education 2003 Jilin University, Changchun, China, BS in Applied Chemistry 2008 Miami University, Oxford, OH, PhD in Chemistry (Advisor: Hong-Cai Joe Zhou) Professional Experience 2001-2003 Undergraduate Research Assistant, State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, China (Supervisor: Feng-Shou Xiao) 2003-2008 Graduate Research Assistant, Department of Chemistry & Biochemistry, Miami University, Oxford, OH (Advisor: Hong-Cai Joe Zhou) 2008-2010 Director’s Postdoctoral Fellow, Argonne National Laboratory, Argonne, IL(Supervisor: Dijia Liu) 2010-2015 Assistant Professor, Department of Chemistry, University of South Florida,Tampa, FL 2015-2018 Associate Professor, Department of Chemistry, University of South Florida,Tampa, FL 2018-Present Full Professor, Department of Chemistry, University of South Florida, Tampa, FL

研究领域

We are a synthetic inorganic and organic materials research group focusing on task-specific design and functionalization of advanced porous materials. The space within nanoporous materials provides virtually unlimited room for imagination, allowing designed incorporation of different functionalities for numerous potential applications. The research of our group aims to engineering the nanospace of advanced porous materials including metal-organic frameworks (MOF), covalent organic framework (COF) and porous organic polymer (POP) for energy/biological/environmental-related applications centered on the following topics: 1. Rational design and functionalization of MOF materials for catalysis 2. Exploration of mesoporous MOF/COF as a new type of platform for enzyme/protein immobilization 3. Development of functional porphyrin-based framework materials 4. Task-specific design and functionalization of COF/POP materials for water treatment 5. Rational design and functionalization of COF/POP materials for catalysis 6. Rational design and functionalization of MOF/POP/COF materials for gas storage and gas separation 7. Targeted synthesis of microporous carbon and nanostructured materials from MOFs/COFs/POPs

近期论文

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“Secondary Sphere Effects on Porous Polymeric Organocatalysts for CO2 Transformations: Subtle Modifications Resulting in Superior Performance” Song, Y.; Sun, Q.*; Lan, P. C.; Ma, S.* ACS Appl. Mater. Interfaces, 2020, 12, DOI: 10.1021/acsami.0c08817. “Metal-Organic Framework Disintegrants: A New Generation of Enzyme Preparation Platforms with Boosted Activity” An, H.; Song, J.; Wang, T.; Xiao, N.; Zhang, Z.; Cheng, P.; Ma, S.; Chen, Y. Angew Chem. Int. Ed., 2020, 59, DOI: 10.1002/anie.202007827. “Postsynthetic Oxidation of Coordination Site in a Heterometallic Metal-Organic Framework: Tuning Catalytic Behaviors” Han, Y.; Sinnwell, M. A.; Surbella III, R. G.; Xue, W.; Huang, H.; Zheng, J.; Peng, B.; Verma, G.; Yang, Y.; Liu, L.; Ma, S.; Thallapally, P. K. Chem. Mater. 2020, 32, DOI: 10.1021/acs.chemmater.0c01267. “Synthesis, Characterization, and Antimicrobial Investigation of a Novel Chlorhexidine Cyclamate Complex” Dubovoy, V.; Desai, P.; Hao, Z.; Cheng, Ch.-Y.; Verma, G.; Wojtas, L.; Brinzari, T. V.; Boyd, J. M.; Ma, S.; Asefa, T.; Pan, L. Cryst. Growth Des. 2020, 20, DOI:10.1021/acs.cgd.0c00107. “Synthesis, Characterization, and Investigation of the Antimicrobial Activity of Cetylpyridinium Tetrachlorozincate” Dubovoy, V.; Nawrocki, S.; Verma, G.; Wojtas, L.; Desai, P.; Al-Tameemi, H.; Brinzari, T. V.; Stranick, M.; Chen, D.; Xu, S.; Ma, S.; Boyd, J. M.; asefa, T.; Pan, L. ACS Omega 2020, 5, 10359-10365. “Porous Organic Polymer Nanotrap for Efficient Extraction of Palladium” Aguila, B.; Sun, Q.*; Cassady, H. C.; Shan, C.; Liang, Z.; Al-Enizi, A. M.; Nafady, A.; Wright, J. T.; Meulenberg, R. W.; Ma, S.* Angew Chem. Int. Ed., 2020, 59, DOI: 10.1002/anie.202006596. “Fabrication of Photoresponsive Crystalline Artificial Muscles Based on PEGylated Covalent Organic Framework Membranes” Guo, X.; Mao, T.; Wang, Z.; Cheng, P.; Chen, Y.; Ma, S.; Zhang, Z. ACS Central Science, 2020, 6, 787-794. “A Robust soc-MOF Platform Exhibiting High Gravimetric Uptake and Volumetric Deliverable Capacity for On Board Methane Storage” Verma, G.; Kumar, S.; Vardhan, H.; Ren, J.; Niu, Z.; Pham, T.; Wojtas, L.; Butikofer, S.; Garcia, J. C. E.; Chen, Y.-S.; Space, B.; Ma, S.* Nano Res., 2020, 13, DOI: 10.1007/s12274-020-2794-9. “Tailored Porous Organic Polymers for Task-Specific Water Purification” Sun, Q.; Aguila, B.; Song, Y.; Ma, S.* Acc. Chem. Res., 2020, 53, 812-821. “PEG@ZIF-8/PVDF Nanocomposite Membrane for Efficient Pervaporation Desulfurization via a Layer-by-Layer Technology” Sun, H.; Magnuson, Z.; He, W.; Zhang, W.; Vardhan, H.; Han, X.*; He, G.*; Ma, S.* ACS Appl. Mater. Interfaces, 2020, 12, 20664-20671. “Fabricating Covalent Organic Framework Capsules with Commodious Microenvironment For Enzymes” Li, M.; Qiao, S.; Zheng, Y.; Andaloussi, Y. H.; Li, X.; Zhang, Z.; Li, A.; Cheng, P.; Ma, S.; Chen, Y. J. Am. Chem. Soc., 2020, 142, 6675-6681. “Robust Bimetallic Ultramicroporous Metal–Organic Framework for Separation and Purification of Noble Gases” Wang, T.; Peng, Y.-L.; Lin, E.; Niu, Z.; Li, P.; Ma, S.; Zhao, P.; Chen, Y.; Cheng, P.; Zhang, Z. Inorg. Chem. 2020, 59, 4868-4873. “Highly Efficient Electrocatalytic Hydrogen Evolution Promoted by O–Mo–C Interfaces of Ultrafine β-Mo2C Nanostructures” Yang, H.; Chen, X.; Hu, G.; Chen, W.-T.; Bradley, S.; Zhang, W.; Verma, G.; Nann, T.; Jiang, D.; Kruger, P.; Wang, X.*; Tian, H.*; Waterhouse, G.; Telfer, S.; Ma, S.* Chem. Sci., 2020, 11, 3523-3530. “Protein Structure-Directed Metal-Organic Zeolite-Like Networks as Biomacromolecule Carriers” Wang, H.; Han, L.; Zheng, D.; Yang, M.; Andaloussi, Y. H.; Cheng, P.; Zhang, Z.; Ma, S.; Zaworotko, M. J.; Feng, Y.; Chen, Y. Angew Chem. Int. Ed., 2020, 59, 6263-62675 “A Corrole-Based Covalent Organic Framework Featuring Desymmetrized Topology” Zhao, Y.; Dai, W.; Peng, Y.; Niu, Z.; Sun, Q.; Shan, C.; Yang, H.; Wojtas, L.; Yuan, D.; Zhang, Z.*; Dong, H.*; Zhang, X.*; Zhang, B.*; Feng, Y.; Ma, S.* Angew Chem. Int. Ed., 2020, 59, 4354-4359. “Predisposed Intrinsic and Extrinsic Proton Conduction in Robust Covalent Organic Frameworks for Hydrogen Fuel Cell Application” Yang, Y.; He, X.; Zhang, P.; Andaloussi,Y.; Zhang, H.; Jiang, Z.; Chen, Y.; Ma, S.; Cheng, P.; Zhang, Z. Angew Chem. Int. Ed., 2020, 59,3678-3684. “Programming Covalent Organic Frameworks for Photocatalysis: Investigation of Chemical and Structural Variations” Wang, S.; Sun, Q.*; Chen, W.; Tang, Y.; Aguila, B.; Pan, Y.; Zheng, A.; Yang, Z.; Wojtas, L.; Ma, S.* Xiao, F.-S.* Matter, 2020, 2, 416-427. “Covalent organic frameworks for separation applications” Wang, Z.; Zhang, S.; Chen, Y.*; Zhang, Z.*; Ma, S.* Chem. Soc. Rev., 2020, 49, 708-735. (Invited contribution to the themed Collection in Chem. Soc. Rev. on “New frontiers in Covalent Organic Frameworks: Design and Applications”) “Beyond Confined Catalysis in Porous Materials” Wang, X.; Lan, P. C.; Wang, S.; Ma, S.* Natl. Sci. Rev., 2020, 7, DOI: 10.1093/nsr/nwaa044. (Research Highlight) “Skeleton Engineering of Homo-Coupled Conjugated Microporous Polymers for Highly Efficient Uranium Capture via Synergistic Coordination” Zhang, L.; Ye, G.*; Pu, N.; Yu, B.; Chen, J.; Xu, S.*; Ma, S.* ACS Appl. Mater. Interfaces, 2020, 12, 3688-3696. "Predisposed Intrinsic and Extrinsic Proton Conduction in Robust Covalent Organic Frameworks for Hydrogen Fuel Cell Application" Yang, Y.; He, X.; Zhang, P.; Andaloussi, Y.; Zhang, H.; Jiang, Z.; Chen, Y.; Ma, S.; Cheng, P.; Zhang, Z. Angew Chem. Int. Ed., 2020, 59, 3678-3684. "Programming Covalent Organic Frameworks for Photocatalysis: Investigation of Chemical and Structural Variations" Wang, S.; Sun, Q.*; Chen, W.; Tang, Y.; Aguila, B.; Pan, Y.; Zheng, A.; Yang, Z.; Wojtas, L.; Ma, S.*; Xiao,F.-S.* Matter, 2020, 2, 416-427. "Regulation of the degree of interpenetration in metal-organic frameworks" Verma, G.; Butikofer, S.; Kumar, S.; Ma, S.* Top. Curr. Chem., 2020, 378, 4. "Recent advances in MOF-based photocatalysis: environmental remediation under visible ligh" Wang, Q.; Gao, Q.; Al-Enizi, A. M.; Nafady, A.; Ma, S.* Inorg. Chem. Front., 2020, 7, 300-339. "Pore Surface Engineering of Covalent Organic Frameworks: Structural Diversity and Applications" Vardhan, H.; Al-Enizi, A. M.; Nafady, A.; Ma, S.* Nanoscale, 2019, 11, 21679-21708. "Mapping out the Degree of Freedom of Hosted Enzymes in Confined Spatial Environments" Sun, Q.; Pan, Y.; Wang, X.; Li, H.; Farmakes, J.; Aguila, B.; Yang, Z.*; Ma, S.* Chem, 2019, 5, 3184-3195. "Iridium complex Immobilization on Covalent Organic Framework for Effective C-H Borylation" Vardhan, H.; Pan, Y.; Yang, Z.; Verma, G.; Nafady, A.*; El-enizi, A.; Alotaibi, T.; Almaghrabi, O.; Ma, S.* APL Materials, 2019, 7, 101111. "Microporous Cyclen-Based Octacarboxylate Hydrogen-Bonded Organic Framework Exhibiting Selective Gas Adsorption" Stackhouse, C.; Ren, J.; Shan, C.; Nafady, A.; Al-Enizi, A.; Ubaidullah, M.; Niu, Z.; Ma, S.* Cryst. Growth Des. 2019, 19, 6377-6380. "Robust Corrole-Based Metal-Organic Frameworks with Rare 9-Connected Zr/Hf-Oxo Clusters" Zhao, Y.; Qi, S.; Niu, Z.; Peng, Y.; Shan, C.; Verma, G.; Wojtas, L.; Zhang, Z.; Zhang, B.*; Feng, Y.; Chen, Y.-S.; Ma, S.* J. Am. Chem. Soc., 2019, 141, 14443-14450. "De Novo Design and Facile Synthesis of 2D Covalent Organic Frameworks: A Two-in-One Strategy" Li, Y.; Chen, Q.; Xu, T.; Xie, Z.; Liu, J.; Yu, X.; Ma,S.; Qin, T.; Chen, L. J. Am. Chem. Soc., 2019, 141, 13822-13828. "Heterogenization of Trinuclear Palladium Complex into an Anionic Metal-Organic Framework through Post-synthetic Cation Exchange" Ren, J.; Lan, P. C.; Chen, M.; Zhang, W.; Ma, S.* Organometallics, 2019, 38, 3460-3465. "Design Strategies to Enhance Amidoxime Chelators for Uranium Recovery" Aguila, B.; Sun, Q.; Cassady, H.; Abney, C.; Li, B.; Ma, S.* ACS Appl. Mater. Interfaces, 2019, 11, 30919-30926. "Membrane-supported 1D MOF hollow superstructure array prepared by polydopamine-regulated contra-diffusion synthesis for uranium entrapment" Yu, B.; Ye, G.;* Chen, J.;* Ma, S. Environ. Pollut., 2019, 253, 39-48. "Bio-inspired Creation of Heterogeneous Reaction Vessels via Polymerization of Supramolecular Ion Pair" Dong, K.; Sun, Q.;* Tang, Y.; Shan, C.; Aguila, B.; Wang, S.; Meng, X.; Ma, S.;* Xiao, F.-S.* Nature Commun. 2019, 10, 3059. "Tunable Synthesis of Hollow Metal-Nitrogen-Carbon Capsules for Efficient Oxygen Reduction Catalysis in Proton Exchange Membrane Fuel Cells" Yang, H.; Chen, X.; Chen, W.-T.; Wang, Q.; Cantillo Cuello, N.; Nafady, A.; Al-Enizi, M. A.; Waterhouse, I. N. G.; Goenaga, A. G.; Zawodzinski, A. T.; Kruger, E. P.; Clements, E. J.; Zhang, J.*; Tian, H.*; Telfer, S*; Ma, S.* ACS Nano, 2019, 13, 8087-8098. "PolyCOFs: A New Class of Freestanding Responsive Covalent Organic Framework Membranes with High Mechanical Performance" Wang, Z.; Yu, Q.; Huang, Y.; An, H.; Zhao, Y.; Feng, Y.; Li, X.; Shi, X.; Liang, J.; Pan, F.; Cheng, P.; Chen, Y.*; Ma, S.*; Zhang, Z.* ACS Central Science, 2019, 5, 1352-1359. "Investigation of the Anticancer Activity of Coordination-Driven Self-Assembled Two-Dimensional Ruthenium Metalla-Rectangle" Vardhan, H.; Nafady, A.;* Al-Enizi, A. M.; Khandker, K.; El-Sagher, H. M.; Verma, G.; Duncan, M. A.; Alotaibi, T. M.; Ma, S.* Molecules, 2019, 24, 2284. "Solvent-assisted coordination driven assembly of a supramolecular architecture featuring two types of connectivity from discrete nanocages" Niu, Z.; Wang, L.; Fang, S.; Lan, P. C.; Aguila, B.; Perman, J.; Ma, J.-G.*; Cheng, P.; Li, X.; Ma, S.* Chem. Sci., 2019, 10, 6661-6665. "Pore Environment Engineering in Metal-Organic Frameworks for Efficient Ethane/Ethylene Separation" Wang, X.; Niu, Z.; Al-Enizi, A.; Nafady, A.; Wu, Y.; Aguila, B.; Verma, G.; Wojtas, L.; Chen, Y.-S.; Li, Z.*; Ma, S.* J. Mater. Chem. A, 2019, 7, 13585-13590. "Metal-Organic Framework Based Methane Nano-trap for the Capture of Coal-Mine Methane" Niu, Z.; Cui, X.; Pham, T.; Lan, P. C.; Xing, H.; Forrest, K. A.; Wojtas, L.; Space, B.; Ma, S.* Angew Chem. Int. Ed., 2019, 58, 10138-10141. "Porous Metal-Metalloporphyrin Gel as Catalytic Binding Pocket for Highly Efficient Synergistic Catalysis" Zhang, W.; Dynes, J. J.; Hu, Y.; Jiang, P.*; Ma, S.* Nature Commun. 2019, 10, 1913. "Reaction Environment Modification in Covalent Organic Frameworks for Catalytic Performance Enhancement" Sun, Q.; Tang, Y.; Aguila, B.; Wang, S.; Xiao, F.-S.*; Thallapally, P. K.; Al-Enizi, A. M.; Nafady, A.; Ma, S.* Angew Chem. Int. Ed., 2019, 58, 8670-8675. "Promoting Frustrated Lewis Pair for Heterogeneous Chemoselective Hydrogenation via Tailored Pore Environment within Metal-Organic Framework" Niu, Z.; Zhang, W.; Lan, P. C.; Aguila, B.; Ma, S.* Angew Chem. Int. Ed., 2019, 58, 7420-7424. "Squaramide-Decorated Covalent Organic Framework as a New Platform for Biomimetic Hydrogen-Bonding Organocatalysis" Li, X.; Wang, Z.; Sun, J.; Gao, J.; Zhao, Y.;Â Cheng, P.; Aguila, B.; Ma, S.*; Chen, Y.*; Zhang, Z.* Chem. Commun., 2019, 55, 5423-5426. "Optimizing Radionuclide Sequestration in Anion Nanotraps with Record Pertechnetate Sorption" Sun, Q.; Zhu, L.; Aguila, B.; Thallapally, P. K.; Xu, C.; Chen, J.; Wang, S.*; Rogers, D.; Ma, S.* Nature Commun. 2019, 10, 1646. "Tuning Pore Heterogeneity in Covalent Organic Frameworks for Enhanced Enzyme Accessibility and Resistance against Denaturants" Sun, Q.; Aguila, B.; Lan, P. C.; Ma, S.*; Adv. Mater. 2019, 31, 1900008. "Siderophore-inspired chelator hijacks uranium from aqueous medium" Ivanov, A. S.; Parker, B. F.; Zhang, Z.; Aguila, B.; Sun, Q.; Ma, S.; Jansone-Popova, S.; Arnold, J.; Mayes, R. T.; Dai, S.; Bryantsev, V. S.; Rao, L.; Popovs, I. Nat. Commun. 2019, 10, 819. "Opportunities of Porous Organic Polymers for Radionuclide Sequestration" Sun, Q.; Aguila, B.; Ma, S.* Trends in Chemistry 2019, 1, 292-303. "Vanadium Docked Covalent Organic Frameworks: An Effective Heterogeneous Catalyst for Modified Mannich-Type Reaction" Vardhan, H.; Hou, L.; Yee, E.; Nafady, A.; Al-Abdrabalnabi, M.; Al-Enizi, A.; Pan, Y.; Yang, Z.; Ma, S.* ACS Sustainable Chem. Eng., 2019, 7, 4878-4888. "Hollow Capsules of Doped Carbon Incorporating Metal@Metal Sulfide and Metal@Metal Oxide Core-Shell Nanoparticles Derived from Metal-Organic Framework Composites for Efficient Oxygen Electrocatalysis" Guo, F.; Yang, H.*; Liu, L.; Han, Y.; Al-Enizi, A.; Nafady, A.; Kruger, P.; Telfer, S.*; Ma, S.* J. Mater. Chem. A, 2019, 7, 3624-3631. "Indium-Organic Frameworks Based on Dual Secondary Building Units Featuring Halogen-Decorated Channels for Highly Effective CO2 Fixation" Yuan, Y.; Li, J.; Sun, X.; Li, G.; Liu, Y.*; Verma, G.; Ma, S.* Chem. Mater. 2019, 31, 1084-1091. "Photomechanical organic crystals as smart materials for advanced applications" Yu, Q.; Aguila, B.; Gao, J.; Xu, P Chen, Q.; Yan, J.; Xing, D.; Chen, Y.; Cheng, P.; Zhang, Z.;* Ma, S.* Chem. Eur. J., 2019, 25, 5611-5622. "Incorporation of Biomolecules in Metal-Organic Frameworks for Advanced Applications" An, H.; Li, M.; Gao, J.; Zhang, Z.; Ma, S.; Chen, Y.* Coord. Chem. Rev., 2019, 384, 90-106. "Chemical Detection using a Metal-organic Framework Single Crystal Coupled to an Optical Fiber" Zhu, C.; Perman, J.; Gerald II, R.; Ma, S.*; Huang, J.* ACS Appl. Mater. Interfaces, 2019, 11, 4393-4398. "Covalent Organic Framework Decorated with Vanadium as a New Platform for Prins Reaction and Sulphide Oxidation" Vardhan, H.; Verma, G.; Ramani, S.; Nafady, A.; Al-Enizi, A.; Pan, Y.; Yang, Z.; Yang, H.; Ma, S.* ACS Appl. Mater. Interfaces, 2019, 11, 3070-3079. "Antibodies@MOFs: in Vitro Protective Coating for Biopharmaceuticals Preparation and Storage" Feng, Y.; Wang, H.; Zhang, S.; Zhao, Y.; Gao, J.; Zhang, Z.; Zaworotko, M. J.; Cheng, P.; Ma, S.*; Chen, Y.* Adv. Mater. 2019, 31, 1805148. "Opportunities of Covalent Organic Frameworks for Advanced Applications" Song, Y.; Sun, Q.*; Aguila, B.; Ma, S.* Adv. Sci. 2019, 6, 1801410.