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Achieving Nickel-Catalyzed Reductive C(sp2)–B Coupling of Bromoboranes via Reversing the Activation SequenceMeng, C.-F.; Zhang, B.-B.; Liu, Q.; Chen, K.-Q.; Wang, Z.-X.; Chen, X.-Y. UCASJ. Am. Chem. Soc. 2024. 10.1021/jacs.4c01450.
N-heterocyclic nitrenium-catalyzed photoreductive radical-polar crossover for alkene dicarbofunctionalizationHan, Y.-F.; Zhang, B.-B.; Sun, N.-N.; Wang, Z.-X.; Chen, X.-Y. UCASGreen Synth. Catal. 2024, asap
Photoinduced N-heterocyclic nitrenium-catalyzed single electron reduction of Se–Se bond for the generation of nucleophilic selenolatesZhang, C.-S.; Chen, K.-Q.; Zhou, L.; Yang, Z.-S.; Wang, Z.-X.; Chen, X.-Y. UCASOrg. Chem. Front. 2024. 10.1039/D3QO02012F.
Chalcogen bonding enabled photosynthesis of aryl selenides from aryl sulfonium saltsTan, F.; Su, X.-D.; Zhang, Q.-S.; Zhang, B.-B.; He, L.; Liu, Q.; Chen, X.-Y. UCASOrg. Chem. Front. 2024, 10.1039/D3QO01719B.
N-Heterocyclic Nitrenium Charge Transfer Catalysis via Inner-Sphere Electron Transfer Concerted with Halogen-Atom DissociationZhang, C.; Fang, C.-Z.; Yi, L.; Zhu, C.; Wang, Z.-X.; Chen, X.-Y.; Rueping, M. UCASOrg. Chem. Front. 2024. 10.1039/D3QO01779F.
Bio-inspired Halogen Bonding-Promoted Cross Coupling for the Synthesis of Organoselenium CompoundsLi, B.; Yi, L.; Maity, B.; Jia, J.; Shen, Y.; Chen, X.-Y.; Cavallo, L.; Rueping, ACS Catal. 2023, 13, 15194–15202.
Photoinduced Single-Electron Reduction of Alkenes ( invited review)Li, X.; Tu, Y.-L.; Chen, X. -Y. UCASEur. J. Org. Chem. 2023, e202301060.
Cross-Electrophile C-PIII Coupling of Chlorophosphines with Organic Halides: Photoinduced PIII and Aminoalkyl Radical Generation Enabled by Pnictogen BondingTu, Y.-L.; Zhang, B.-B.; Qiu, B.-S.; Wang, Z.-X.; Chen, X. Y. UCASAngew. Chem. Int. Ed. 2023, e202310764.
Reduction of unactivated alkyl chlorides enabled by light-induced single electron transferDai, L.; Zhang, Z.-F.; Chen, X.-Y. UCASSci. China: Chem., 2023, DOI: 10.1007/s11426-023-1787-3.
Charge transfer complex enabled photoreduction of ether phosphonium salts for the selective oxyalkylation of enamidesQiao, S.; Chen, K.; Liu, Q.; Wang, Z.; Chen, X. Y. UCASChin. Chem. Lett. 2023, 108979.
Visible-Light-Induced Photoreduction of Carborane Phosphonium Salts: Efficient Synthesis of Carborane-Oxindole-Pharmaceutical HybridsLiu, Q.; Zhang, B.-B.; Sheng, H.; Qiao, S.; Wang, Z.-X.; Chen, X.-Y. UCASAngew. Chem. Int. Ed. 2023, e202305088.
Near-infrared-light-induced iron(I) dimer-enabled halogen atom transfer for rapid iodoperfluoroalkylation of alkenesSu, X.-D.;+ L, Q.;+ Li X.-N.;+ Zhang B.-B.; Wang Z.-X.; Chen X.-Y. UCASChem Catal. 2023, 10.1021/acs.orglett.3c01989.
Charge Transfer Complex-Enabled Synthesis of (Hetero)arylated m-Carboranes from m-Carborane Phosphonium SaltsZhang, Q.-S.; He, L.; Liu, Q.; Chen, X.-Y. UCASOrg. Lett. 203, 10.1021/acs.orglett.3c01989.
N-Heterocyclic Nitrenium-Catalyzed Photohomolysis of CF3SO2Cl for Alkene TrifluoromethylationRen, X.-J.; Liao, P.-W.; Sheng, H.; Wang, Z.-X.; Chen, X.-Y. UCASOrg. Lett. 2023, 25, 6189–6194.
Pnictogen Bonding Enabled Photosynthesis of Chiral Selenium-Containing Pyridines from Pyridylphosphonium SaltsLiu, Q.; Zhang, B.-B.; Zhang, C.-S.; Han, J.-N.; Wang, Z.-X.; Chen, X.-Y. UCASFundam. Res. 2023, 10.1016/j.fmre.2023.03.013
Photoinduced N-Heterocyclic Nitrenium-Catalyzed Single Electron Reduction of Acyl Fluorides for Phenanthridine SynthesisBao, L.; Wang, Z.-X.; Chen, X.-Y. UCASOrg. Lett. 2023, 25, 565-568.
Visible-Light-Induced N-Heterocyclic Carbene-Catalyzed Single Electron Reduction of Mono-FluoroarenesSheng, H.; Liu, Q.; Zhang, B.-B.; Wang, Z.-X.; Chen, X.-Y. UCASAngew. Chem. Int. Ed. 2023, e202218468.
Photocatalytic Charge Transfer Complex Enables Hydroarylation of Alkenes for Heterocycle SynthesisRen, Y.-Z.; Fang, C.-Z.; Zhang, B.-B.; He, L.; Tu, Y.-L.; Chen, X.-Y. UCASOrg. Lett. 2023, 25, 3585–3589.
Additive Free, N-Heterocyclic Nitrenium Catalyzed Photoreduction of Cycloketone Oxime EstersSu, X.-D.; Yang, Z.; Gong, W.; Wang, Z.-X.; Chen, X.-Y. UCASOrg. Chem. Front. 2023, 10, 1160-1165 .
Photocatalytic dehydrations for Ritter reactionBao, L.; Zhang, B.-B.; Wang, Z.-X.; Chen, X.-Y. UCASOrg. Chem. Front. 2023, 10, 1375-1379.
Electron donor–acceptor complex enabled cascade reaction of unprotected o-anilide aryl chlorides for heterocycle synthesisYang, Z.-S., Tang, W.-X., Zhang, B.-B., Sun, D.-Q., Chen, K.-Q., Chen, X.-Y. UCASOrg. Chem. Front. 2023, 10, 1219-1223.
Direct photolysis of N-methoxypyridiniums for the pyridylation of carbon/heteroatom-hydrogen bondsSheng, H.; Zhang, B.-B.; Liu, Q.; Yang, Z.-S.; Wang, Z.-X.; Chen, X.-Y. UCASSci. China: Chem. 2022, 65, 2494–2499.
N-Heterocyclic Nitreniums Can Be Employed as Photoredox Catalysts for the Single-Electron Reduction of Aryl Halides (most downloaded articles for the previous 30 days)Kun-Quan Chen, Bei-Bei Zhang, Zhi-Xiang Wang*, and Xiang-Yu Chen* UCASOrg. Lett. 2022, 24, 25, 4598–4602
Charge Transfer Complex Enabled Photoreduction of Wittig Phosphonium SaltsTan, F.; Zheng, P.; Liu, Q.*; Chen, X.-Y.* UCASOrg. Chem. Front. 10.1039/D2QO01079H.
Visible-light-induced direct hydrodifluoromethylation of alkenes with difluoromethyltriphenylphosphonium iodide saltRen, X.; Liu, Q.; Wang, Z.*; Chen, X.-Y.* UCASChin. Chem. Lett. 2022. 10.1016/j.cclet.2022.04.071
Catalytic charge transfer complex enabled difluoromethylation of enamides with difluoromethyltriphenylphosphonium bromideLi, P.; Liu, Q.; Sun, D.-Q.; Chen, X.-Y. UCASOrg. Biomol. Chem., 2022, 20, 7599
Additive-Free Generation of Cyanoalkyl Radicals via Photoinduced Single Electron Transfer from Dichalcogenides to Cycloketone Oxime EstersSu, X.-D.; Zhang, B.-B.; Liu, Q.; Yang, Z.-S.; Wang, Z.-X.; Chen, X.-Y. UCASEur. J. Org. Chem.
Alkynyl Sulfonium Salts Can Be Employed as Chalcogen-Bonding Catalysts and Generate Alkynyl Radicals under Blue-Light IrradiationLu, Y.; Liu, Q.; Wang, Z.-X.*; Chen, X.-Y.* UCASAngew. Chem. Int. Ed. 2022, 61, e202116071.
Aryldiazonium salts can serve as nitrogen-based Lewis acid catalysts and their applications in the formation of photoactive charge transfer complexesRen, X.; Liu, Q.; Yang, Z.-S.; Wang, Z.; Chen, X.-Y. UCASChin. Chem. Lett. 2022.
Metal-Free Generation of Acyl Radical via Photoinduced SingleElectron Transfer from Lewis Base to Acyl ChlorideBao, L.; Wang, Z.-X.; Chen, X.-Y. UCASOrg. Lett. 2022. doi: 10.1021/acs.orglett.2c03339
Photoinduced Halogen-Bonding Enabled Synthesis of Oxindoles and Isoindolinones from Aryl IodidesTang, W.-X.; Chen, K.-Q.; Sun, D.-Q.; Chen, X.-Y. UCASOrg. Biomol. Chem., 2022. DOI: 10.1039/D2OB01818G
Water Facilitated Photolysis of Perfluoroalkyl Iodides via Halogen BondingFang, C.-Z.; Zhang, B.-B.; Li, B.; Wang, Z.-X.*; Chen, X.-Y.* UCASOrg. Chem. Front. 2022. 10.1039/D2QO00056C.
Visible-light-induced N-heterocyclic carbene mediated cascade transformation of N-alkenoxypyridinium saltsSheng, H.; Liu, Q.; Chen, F.; Wang, Z*.; Chen, X.-Y.* UCASChin. Chem. Lett. 2022. 10.1016/j.cclet.2022.01.028.
Pyrylium salts acting as both energy transfer and electron transfer photocatalysts for E → Z isomerization of activated alkenes and cyclization of cinnamic or biaryl carboxylic acids.Bao, L.; Cheng, J.-T.; Wang, Z.-X.*; Chen, X.-Y.* UCASOrg. Chem. Front. 2022. 10.1039/D1QO01623G.
DFT insight into asymmetric alkyl–alkyl bond formation via nickel-catalysed enantioconvergent reductive coupling of racemic electrophiles with olefinsZhang, C.-S.; Zhang, B.-B.; Zhong, L.; Chen, X.-Y.*; Wang, Z.-X.* UCASChem. Sci. 2022. 10.1039/D1SC05605K.
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