商明 - 上海交通大学 - 变革性分子前沿科学中心

个人简介

教育背景 2011.09-2016.07 中科院上海有机所，金属有机国家重点实验室，理学博士,导师：余金权（Jin-Quan Yu）教授,戴辉雄研究员（其中2015年在美国斯克里普斯研究所学习） 2006.09-2010.07 复旦大学，理学学士工作经历 2021.02至今上海交通大学变革性分子前沿科学中心，长聘教轨副教授 2017.08-2020.08 美国斯克里普斯研究所（Scripps Research Institute，CA），博士后，合作导师：Phil S. Baran 教授 2016.07-2017.08 美国波士顿学院（Boston College），博士后，合作导师：Masayuki Wasa 教授 2011.02-2011.08 中科院上海有机所，生命有机国家重点实验室，研究助理，导师：李昂研究员学术任职、荣誉与获奖 2022 上海市青年科技35人引领计划 2022 Thieme Chemistry Journals Award 2015 上海有机所“汪猷”奖学金 2015 阿达玛斯学术论文奖，卓越奖 2014 国家奖学金 2014 中科院院长奖 2009复旦大学人民奖学金国际著名学术期刊JACS, Nat.Commun.,ACS Catal., Org. Lett等审稿人

研究领域

惰性化学键活化与重组；不对称催化  核酸的高效合成方法开发，DNA编码化合物库（DEL）化学

近期论文

查看导师最新文章（温馨提示：请注意重名现象，建议点开原文通过作者单位确认）

Sun, S.-Z.;# Cai, Y.-M.;# Zhang, D.-L.; Wang, J.-B.; Yao, H.-Q.; Rui, X.-Y.; Martin, R.; Shang, M.* J. Am. Chem. Soc. 2022, 144, 1130. Xiang, J.;# Shang, M.; # Kawamata, Y.; Lundberg, H.; Reisberg, S.; Chen, M.; Mykhailiuk, P.; Beutner, G.; Gallego, G. M.; Starr, J.; Davies, A.; Paraselli, B.; Blackmond, D. G.; Baran, P. S. “Hindered Dialkyl Ether Synthesis via Electrogenerated Carboncations” Nature, 2019, 573, 398. (# Co-first author) Shang, M.; # Feu, K. S., # Vantourout, J. C.; Barton, L. M.; Osswald, H. L.; Kato, N.; Gagaring, K.; McNamara, C. W.; Chen, G.; Hu, L.; Ni, S.; Fernández-Canelas, P.; Chen, M.; Merchant, R. R.; Qin, T.; Schreiber, S. L.; Melillo, B.; Yu, J.-Q.; Baran, P. S. “Modular, Stereocontrolled Cβ-H/Cα-C Activation of Alkyl Carboxylic Acids” Proc. Natl. Acad. Sci.. U.S.A. 2019, 116, 8721. (# Co-first author) Shang, M.; Sun, S.-Z.; Dai, H.-X.; Yu, J.-Q. “Cu(II)-Mediated C–H Amidation and Amination of Arenes: Exceptional Compatibility with Heterocycles”, J. Am. Chem. Soc. 2014, 136, 3354. Shang, M.; Sun, S.-Z.; Wang, H.-L.; Laforteza, B.N.; Dai, H.-X.; Yu, J.-Q. “Exceedingly Fast Cu(II)-Promoted ortho-C–H Trifluoromethylation of Arenes with TMSCF3” Angew. Chem. Int. Ed. 2014, 53, 10439. Shang, M.; Wang, H.-L.; Sun, S.-Z.; Dai, H.-X.; Yu, J.-Q. “Cu(II)-Mediated ortho-C–H Alkynylation of (Hetero)Arenes with Terminal Alkynes” J. Am. Chem. Soc. 2014, 136, 11590. Shang, M.; Wang, X.; Koo, S. M.; Youn, J.; Chan, J. Z.; Yao, W..; Hastings, B. T.; Wasa, M. “Frustrated Lewis Acid/Brønsted Base Catalyst for Direct Enantioselective α-Amination of Carbonyl Compounds” J. Am. Chem. Soc. 2017, 139, 95. Shang, M.; # Wang, M.-M.; # Saint-Denis, T. G.; Li, M.-H.; Dai, H.-X.; Yu, J.-Q. “Cu-Mediated Late-Stage Functionalization of Heterocycle-Containing Molecules” Angew. Chem. Int. Ed. 2017,56, 5317. (# Co-first author) Shang, M.; Cao, M.; Wang, Q.; Wasa, M. “Direct Enantioselective Mannich-Type Reaction of Ketones and Esters Using Frustrated Lewis Acid/Brønsted Base Catalyst” Angew. Chem. Int. Ed. 2017, 56, 13338. Shang, M.; # Chan, J. Z.; # Cao, M.; Chang, Y.; Wang, Q.; Cook, B.; Torker, S.; Wasa, M. “C–H Functionalization of Amines via Alkene-Derived Nucleophiles through Cooperative Action of Chiral and Achiral Lewis Acid Catalysts: Applications in Enantioselective Synthesis” J. Am. Chem. Soc. 2018, 140, 10593. (# Co-first author) Shang, M.; Shao, Q.; Sun, S.-Z.; Chen, Y.-Q.; Xu, H.; Dai, H.-X.; Yu, J.-Q. “Identification of Monodentate Oxazoline as a Ligand for Copper-Promoted ortho-C–H Hydroxylation and Amination” Chem. Sci. 2017, 8, 1469. Shang, M.; Sun, S.-Z.; Dai, H.-X.; Yu, J.-Q. “Cu(OAc)2-Catalyzed Coupling of Aromatic C–H Bonds with Arylboron Reagents” Org. Lett. 2014, 16, 5666. Shang, M.; Zeng, S.-H.; Sun, S.-Z.; Dai, H.-X.; Yu, J.-Q. “Ru(II)-Catalyzed ortho-C–H Amination of Arenes and Hetero-arenes at Room Temperature”, Org. Lett. 2013, 15, 5286. Shang, M.; Sun, S.-Z.; Wang, H.-L.; Wang, M.-M.; Dai, H.-X. “Recent Progress on Copper-Mediated Directing-Group-Assisted C(sp2)–H Activation” Synthesis. 2016, 48, 4381. Wang, Jie.; # Shang, M.; # Lundberg, H.; Feu, K. S.; Hecker, S. J.; Qin, T.; Blackmond , D. G.; Baran, P. S. “Cu-Catalyzed Decarboxylative Borylation” ACS. Catal. 2018, 8, 9537. (# Co-first author) Liu, Y.-J.; Xu, H.; Kong, W.-J.; Shang, M.; Dai, H.-X.; Yu, J.-Q. "Overcoming the Limitations of Directed C–H Functionalizations of Heterocycles" Nature 2014, 515, 389. Chu, L.; Shang, M.; Tanaka, K.; Chen, Q.; Pissarnitski, N.; Streckfuss, E.; Yu, J.-Q. “Remote meta-C−H Activation Using a Pyridine-Based Template: Achieving Site-Selectivity via the Recognition of Distance and Geometry” ACS Cent. Sci. 2015, 1, 394.