许茂桐 - 同济大学 - 化学科学与工程学院

个人简介

许茂桐，2016年本科毕业于多伦多大学化学系，随后继续在多伦多大学攻读硕士和博士学位（2016-2021），师从英国、加拿大皇家科学院院士Douglas W. Stephan教授。研究方向包含主族元素化学物的合成及其在小分子（一氧化碳、二氧化碳、氢气等）催化转化上的应用。截至目前，在Angew. Chem., J. Am. Chem. Soc.等学术期刊发表论文十余篇；并在多个知名国际会议中做学术汇报；入选2021年度上海领军人才（海外）青年项目，2023年入选国家级青年人才计划。教育及工作经历 2022，特聘研究员，同济大学 2021，博士学位，多伦多大学 2018，硕士学位，多伦多大学 2016，学士学位，多伦多大学荣誉与奖励 2020，国家优秀自费留学生奖学金 2016，Collin H. Bayley Fellowship in Chemistry 2015，Canadian Society for Chemistry Silver Medal 科研项目 2022，自然科学基金青年基金 2021，上海领军人才（海外）青年项目

研究领域

主族元素化学（Main group Chemistry）受阻路易斯酸碱对（Frustrated Lewis Pairs）小分子活化和催化（Small-molecule Activation and Catalysis）有机金属化学（Organometallics）

近期论文

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Maotong Xu, Bastiaan Kooij, Tongtong Wang, Jack H. Lin, Zheng-wang Qu*, Stefan Grimme, Douglas W. Stephan*, Facile synthesis of cyanide and isocyanides from CO, Angew. Chem. Int. Ed. 2021, 60, 16965-16969 Maotong Xu, Zheng-wang Qu*, Stefan Grimme, Douglas W. Stephan*, Lithium Dicyclohexylamide in Transition-Metal-Free Fischer-Tropsch Chemistry, J. Am. Chem. Soc. 2021, 143, 634-638 Maotong Xu§, Tongtong Wang§, Zheng-wang Qu*, Stefan Grimme, Douglas W. Stephan*, Reactions of a dilithiomethane with CO and N2O: An avenue to an anionic ketene and a hexafunctionalized benzene, Angew. Chem. Int. Ed. 2021, 60, 25281-25285 共一 Maotong Xu, Andrew R. Jupp, Maegan S. E. Ong, Katherine I. Burton, Saurabh S. Chitnis, Douglas W. Stephan*, Synthesis of Urea Derivatives from CO2 and Silylamines, Angew. Chem. Int. Ed. 2019, 58, 5707-5711 Maotong Xu, Andrew R. Jupp, Douglas W. Stephan*, Acyl‐Phosphide Anions via an Intermediate with Carbene Character: Reactions of K[PtBu2] and CO, Angew. Chem. Int. Ed. 2019, 58, 3548-3552 Maotong Xu, Andrew R. Jupp, Zheng‐Wang Qu, Douglas W. Stephan*, Alkali Metal Species in the Reversible Activation of H2, Angew. Chem. Int. Ed. 2018, 57, 11050-11054 Maotong Xu, Andrew R. Jupp, Douglas W. Stephan*, Stoichiometric Reactions of CO2 and Indium‐Silylamides and Catalytic Synthesis of Ureas, Angew. Chem. Int. Ed. 2017, 56, 14277-14281 Maotong Xu, Josephine Possart, Alexander E. Waked, Julie Roy, Werner Uhl*, Douglas W. Stephan*, Halogenated triphenylgallium and indium in frustrated Lewis pair activations and hydrogenation catalysis, Phil. Trans A. 2017, 2101, 375, 1-12 Tongtong Wang§, Maotong Xu§, Andrew R. Jupp, Zheng-wang Qu*, Stefan Grimme, Douglas W. Stephan*, Selective catalytic Frustrated Lewis Pair Hydrogenation of CO2 in the Presence of Silylhalides, Angew. Chem. Int. Ed. 2021, 60, 25771-25775 共一 Tongtong Wang, Maotong Xu, Andrew R. Jupp, Shi-Ming Chen, Zheng-Wang Qu*, Stefan Grimme, Douglas W. Stephan*, Frustrated Lewis pair catalyzed hydrodehalogenation of benzyl-halides, Chem. Commun. 2022, 58, 1175-1178 Tongtong Wang, Maotong Xu, Andrew R. Jupp, Zheng-Wang Qu*, Stefan Grimme, Douglas W. Stephan*, Steric Influence on Reactions of Benzyl Potassium Species with CO, Chem. Asian J. 2021, 16, 3640-3644 Kevin M. Szkop, Andrew R. Jupp, Hlib Razumkov, Maotong Xu, Douglas W. Stephan*, Chem. Eur. J. 2019, 25, 10084 -10087 Trevor Janes, Maotong Xu, Datong Song*, Synthesis and reactivity of Li and TaMe3 complexes supported by N, N′-bis(2,6-diisopropylphenyl)-o-phenylenediamido ligands, Dalton Trans. 2016, 45, 10672-10680 Yanxin Yang, Maotong Xu, Datong Song*, Organocatalysts with carbon-centered activity for CO2 reduction with boranes, Chem. Commun. 2015, 51, 11293-11296