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个人简介

胡炳文,现任Journal of Physical Chemistry Letters副主编。现为华东师范大学紫江教授,任华东师范大学上海市磁共振重点实验室副主任、物理与电子科学学院副院长。 本科与硕士就读于复旦大学,博士就读于法国里尔第一大学法国超高场核磁共振研究中心,从事核磁共振新方法的开发。回国后转型开拓电池体系和顺磁共振技术,目前从事核磁共振、顺磁共振的新方法新技术的开发及其在锂离子电池体系里的应用研究。 发表文章200余篇,2015年获国家自然基金委优秀青年基金支持,2022年获徐元植顺磁共振波谱学优秀青年奖。 在2014、2021全国波谱学学术会议两次做大会报告;参加如下重要会议并做邀请报告:中国物理学会 2022 秋季学术会议(F. 纳米与介观物理分会)、2023中国化学会第33届学术年会(第44分会纳米器件、纳米表征与检测技术)、2024国际实验核磁共振会议 ENC会议做邀请报告。 教育经历 本科/硕士,复旦大学,BAC+MASTER(Ping Zhou) 博士, 法国里尔第一大学, Phd (JP Amoureux),分子与凝聚态物质专业 法国超高场核磁共振研究中心(里尔) 工作经历 2009.12-2014.7, 副研究员 2014.8-2021.12, 研究员 2022.1-今, 教授 2018.7-今, 副院长 2020.12-今, 上海市磁共振重点实验室副主任 荣誉及奖励 2010年:法国北方省科学技术博士论文奖(唯一一名,由法国北部大区7所大学的联盟评审授予,Doctoral prize awarded by Consortium of seven universities in Nord-de-France)(Nord-de-France,现为Haute de France,上法兰西大区) 2022年: 徐元植顺磁共振波谱学优秀青年奖

研究领域

主营业务: (1)磁共振成像技术、顺磁共振成像技术研究电池能源材料(含固体电解质) (2)原位非原位固体核磁、原位非原位顺磁共振研究电池能源材料(含固体电解质) (3)固体核磁共振新方法的开发、顺磁共振新方法开发 (4)固体核磁共振、顺磁共振的第一性原理计算 涉及业务: (1)液体核磁共振技术 (2)原位光谱分析-离心技术

近期论文

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(1)EPR-NMR # EPR for metal-ion batteries (including in-situ EPR and in-situ EPR imaging) Jiang, Y.; Lu, G.; Kang, S.; Geng, F.; Hu, B., All-Solid-State Batteries with Pre-plated Ultrathin Lithium Metal Enabled by No Pressure Holding and Characterized by In Situ Electron Paramagnetic Resonance Imaging. The Journal of Physical Chemistry Letters 2023, 14 (20), 4682-4687. Feng, H.; Yang, Q.; Li, C.; Lin, Y.; Liu, H.; Zhang, N.; Hu, B., Completely Eradicating Singlet Oxygen in Li–O2 Battery via Cobalt(II)-Porphyrin Complex-Catalyzed LiOH Chemistry. The Journal of Physical Chemistry Letters 2023, 14 (4), 846-853. H. Liu, C. Li, C. Zhao, W. Tong, B. Hu, Coincident formation of trapped molecular O2 in oxygen-redox-active archetypical Li 3d oxide cathodes unveiled by EPR spectroscopy, Energy Storage Materials 50 (2022) 55-62. B. Hu, F. Geng, M. Shen, B. Hu, The study of electrochemical cycle for LiCoO2 by dual-mode EPR, Magnetic Resonance Letters (2023) https://doi.org/10.1016/j.mrl.2022.04.002. C. Zhao, C. Li, H. Liu, Q. Qiu, F. Geng, M. Shen, W. Tong, J. Li, B. Hu, Coexistence of (O2)n? and Trapped Molecular O2 as the Oxidized Species in P2-Type Sodium 3d Layered Oxide and Stable Interface Enabled by Highly Fluorinated Electrolyte, Journal of the American Chemical Society 143(44) (2021) 18652-18664. F. Geng, Q. Yang, C. Li, M. Shen, Q. Chen, B. Hu, Mapping the Distribution and the Microstructural Dimensions of Metallic Lithium Deposits in an Anode-Free Battery by In Situ EPR Imaging, Chemistry of Materials 33(21) (2021) 8223-8234. Y. Lin, Q. Yang, F. Geng, H. Feng, M. Chen, B. Hu, Suppressing Singlet Oxygen Formation during the Charge Process of Li-O2 Batteries with a Co3O4 Solid Catalyst Revealed by Operando Electron Paramagnetic Resonance, The Journal of Physical Chemistry Letters 12(42) (2021) 10346-10352. B. Hu, F. Geng, M. Shen, C. Zhao, Q. Qiu, Y. Lin, C. Chen, W. Wen, S. Zheng, X. Hu, C. Li, B. Hu, A multifunctional manipulation to stabilize oxygen redox and phase transition in 4.6 V high-voltage LiCoO2 with sXAS and EPR studies, Journal of Power Sources 516 (2021) 230661. F. Geng, Q. Yang, C. Li, B. Hu, C. Zhao, M. Shen, B. Hu, Operando EPR and EPR Imaging Study on a NaCrO2 Cathode: Electronic Property and Structural Degradation with Cr Dissolution, The Journal of Physical Chemistry Letters 12(2) (2021) 781-786. Y. Liao, C. Li, X. Lou, X. Hu, Y. Ning, F. Yuan, B. Chen, M. Shen, B. Hu, Carbon-coated Li3V2(PO4)3 derived from metal-organic framework as cathode for lithium-ion batteries with high stability, Electrochimica Acta 271 (2018) 608-616. C. Li, X. Lou, Q. Yang, Y. Zou, B. Hu, Remarkable improvement in the lithium storage property of Co2(OH)2BDC MOF by covalent stitching to graphene and the redox chemistry boosted by delocalized electron spins, Chemical Engineering Journal 326 (2017) 1000-1008. C. Li, X. Lou, M. Shen, X. Hu, W. Yan, Y. Zou, W. Tong, B. Hu, High-capacity cobalt-based coordination polymer nanorods and their redox chemistry triggered by delocalization of electron spins, Energy Storage Materials 7 (2017) 195-202. # NMR for metal-ion batteries (including in-situ NMR) Lu, G.; Geng, F.; Guo, N.; Yao, S.; Shen, M.; Hu, B., Probing the degradation of LiCoO2 in batteries subjected to high-voltage cycling with 17O solid-state NMR spectroscopy. Chemical Communications 2023. Liao, Y.; Feng, H.; Yang, Q.; Shen, M.; Jiang, Y.; Li, C.; Zhao, C.; Geng, F.; Hu, B., Oxygen Redox Activation at Initial Cycle to Improve Cycling Stability for the Na0.83Li0.12Ni0.22Mn0.66O2 System. ACS Applied Materials & Interfaces 2023, 15 (8), 10709-10717. G. Lu, F. Geng, S. Gu, C. Li, M. Shen, B. Hu, Distinguishing the Effects of the Space-Charge Layer and Interfacial Side Reactions on Li10GeP2S12-Based All-Solid-State Batteries with Stoichiometric-Controlled LiCoO2, ACS Applied Materials & Interfaces (2022). C. Zhao, C. Li, Q. Yang, Q. Qiu, W. Tong, S. Zheng, J. Ma, M. Shen, B. Hu, Anionic redox reaction in Na-deficient layered oxide cathodes: Role of Sn/Zr substituents and in-depth local structural transformation revealed by solid-state NMR, Energy Storage Materials 39 (2021) 60-69. Q. Qiu, C. Li, H. Liu, Y. Liao, C. Zhao, F. Geng, M. Shen, J. Li, W. Tong, B. Hu, NMR Evidence for the Multielectron Reaction Mechanism of Na3V2(PO4)3 Cathode and the Impact of Polyanion Site Substitution, J. Phys. Chem. C 125(28) (2021) 15200-15209. Y. Liao, C. Li, F. Geng, M. Shen, B. Hu, Na3V2(PO4)3 Revisited: A High-Resolution Solid-State NMR Study, The Journal of Physical Chemistry C 125(43) (2021) 24060-24066. B. Hu, X. Lou, C. Li, F. Geng, C. Zhao, J. Wang, M. Shen, B. Hu, Reversible phase transition enabled by binary Ba and Ti-based surface modification for high voltage LiCoO2 cathode, Journal of Power Sources 438 (2019) 226954. F. Geng, M. Shen, B. Hu, Y. Liu, L. Zeng, B. Hu, Monitoring the evolution of local oxygen environments during LiCoO2 charging via ex situ 17O NMR, Chemical Communications 55(52) (2019) 7550-7553. # EPR & NMR for metal-ion batteries C. Li, C. Zhao, B. Hu, W. Tong, M. Shen, B. Hu, Unraveling the Critical Role of Ti Substitution in P2-NaxLiyMn1–yO2 Cathodes for Highly Reversible Oxygen Redox Chemistry, Chemistry of Materials 32(3) (2020) 1054-1063. F. Geng, B. Hu, C. Li, C. Zhao, O. Lafon, J. Trébosc, J.-P. Amoureux, M. Shen, B. Hu, Anionic redox reactions and structural degradation in a cation-disordered rock-salt Li1.2Ti0.4Mn0.4O2 cathode material revealed by solid-state NMR and EPR, Journal of Materials Chemistry A 8(32) (2020) 16515-16526. C. Li, M. Shen, X. Lou, B. Hu, Unraveling the Redox Couples of VIII/VIV Mixed-Valent Na3V2(PO4)2O1.6F1.4 Cathode by Parallel-Mode EPR and In Situ/Ex Situ NMR, The Journal of Physical Chemistry C 122(48) (2018) 27224-27232. (2)固体核磁共振方法学: Broad-band homo-nuclear correlations assisted by (1)H irradiation for bio-molecules in very high magnetic field at fast and ultra-fast MAS frequencies; Broadband finite-pulse radio-frequency-driven recoupling (fp-RFDR) with (XY8)4(1) super-cycling for homo-nuclear correlations in very high magnetic fields at fast and ultra-fast MAS frequencies; Very-Long-Distance Correlations in Proteins Revealed by Solid-State NMR Spectroscopy; Composite pulses in directly and indirectly detected 14N MAS overtone spectroscopy Reduction of the 13 C cross-polarization experimental time for pharmaceutical samples with long T1 by ball milling in solid-state NMR; (3)核磁共振+固体电解质: Phase Structure and Helical Jump Motion of Poly(ethylene oxide)/LiCF3SO3 Crystalline Complex: A High-Resolution Solid-State C-13 NMR Approach; Polymer chain diffusion and Li+ hopping of poly(ethylene oxide)/LiAsF6 crystalline polymer electrolytes as studied by solid state NMR and ac impedance; PEO-urea-LiTFSI ternary complex as solid polymer electrolytes; (4)DFT计算磁共振参数: Optimizing the U_eff value for DFT+U calculation of paramagnetic solid-state NMR shifts by double Fermi-contact-shift verification (5)综述 Solid-state NMR studies on crystalline solid polymer electrolytes and important cathode materials for lithium-ion batteries, Annual Reports on NMR Spectroscopy,Annual Reports on NMR Spectroscopy, Academic Press, 2020, pp. 265-308. Solid-State High-Resolution NMR Studies on PEO-Based Crystalline Solid Polymer Electrolytes for Lithium-Ion Battery, Annual Reports on NMR Spectroscopy 面向金属离子电池研究的固体核磁共振和电子顺磁共振方法,物理化学学报 锂离子电池中重要正极材料体系的磁共振研究进展,储能科学与技术 金属离子电池中的磁共振:从核磁共振(NMR)到电子顺磁共振(EPR)/ Magnetic Resonance in metal-ion batteries: From NMR (Nuclear Magnetic Resonance) to EPR (Electron Paramagnetic Resonance),Journal of Electrochemistry 28(2) (2022) 2108421.

学术兼职

学术组织:《Journal of Physical Chemistry Letters》副主编、《波谱学杂志》青年编委、《功能材料与器件学报》编委、《Magnetic Resonance Letters》Editor 社会服务:国基函评、优青/重点/面上项目等会评、捷克/德国等面上项目函评

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