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个人简介

教育经历 2017.08-2017.09 访问研究人员,德国康斯坦茨大学材料化学系(合作导师:Stefan Mecking教授) 2014.06-2018.03 博士后,德国莱布尼兹催化研究所 (合作导师: Matthias Beller教授) 2013.07-2014.05 研究助理,中国科学院上海有机化学研究所 2008.09-2013.07 博士,中国科学院上海有机化学研究所 (导师: 丁奎岭院士) 2004.09-2008.07 学士,华东师范大学(指导教师:吴海虹教授) 工作经历 2018.03-至今 教授,华东师范大学 荣誉及奖励 2018年,海外高层次青年人才计划 2021年,上海市“科技创新行动计划”启明星项目

研究领域

不饱和C1和C4的转化利用 连续微通道反应

近期论文

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Palladium-Catalyzed Asymmetric Hydroesterification of α-Aryl Acrylic Acids to Chiral Substituted Succinates, Xiaolei Ji, Chaoren Shen, Xinxin Tian, and Kaiwu Dong*, Organic Letters, 2021, DOI:10.1021/acs.orglett.1c03361. Improving the performance of palladium-catalysed telomerization of 1,3-butadiene by metallocene-based phosphine ligand, Hongru Zhang, Chaoren Shen,* Zhengshuai Xu, Xinxin Tian, Kaiwu Dong*, Molecular Ctalysis, 2021, DOI: 10.1016/j.mcat.2021.111883 Asymmetric Alkoxy- and Hydroxy-Carbonylations of Functionalized Alkenes Assisted by β-Carbonyl Groups, Xinyi Ren, Zhen Wang, Chaoren Shen, Xinxin Tian, Lin Tang, Xiaolei Ji, Kaiwu Dong*, Angewandte Chemie International Edition, 2021, DOI: 10.1002/anie.202105977 Enantioselective Hydroesterificative Cyclization of 1,6-Enynes to Chiral γ-Lactams Bearing a Quaternary Carbon Stereocenter, Xinyi Ren, Lin Tang, Chaoren Shen, Huimin Li, Peng Wang, Kaiwu Dong*, Organic Letters, 2021, DOI: 10.1021/acs.orglett.1c00952 (Highlighted by Synfacts) Access to α-Cyano Carbonyls Bearing a Quaternary Carbon Center by Reductive Cyanation, Xinyi Ren, Chaoren Shen, Guangzhu Wang, Zhanglin Shi, Xinxin Tian, Kaiwu Dong*, Organic Letters, 2021, DOI: 10.1021/acs.orglett.1c00465 Constructing chiral aza-quaternary carbon centers by enantioselective carbonylative Heck reaction of o-iodoanilines with allenes, Zhengshuai Xu, Chaoren Shen, Hongru Zhang, Peng Wang, Kaiwu Dong*, Organic Chemistry Frontiers, 2020, DOI: 10.1039/d0qo01486a Synthesis of Enantioenriched α,α-Difluoro-β-arylbutanoic Esters by Pd-Catalyzed Asymmetric Hydrogenation, Sitian Feng,Yitian Tang,Chenjue Yang,Chaoren Shen,Kaiwu Dong*, Organic Letters, 2020 , DOI: 10.1021/acs.orglett.0c02700 Efficient Synthesis of γ‐Lactones by Cobalt‐Catalyzed Carbonylative Ring Expansion of Oxetanes under Syngas Atmosphere, Yitian Tang, Chaoren Shen, Qiyi Yao, Xinxin Tian, Bo Wang, Kaiwu Dong*, ChemCatChem, 2020, DOI: 10.1002/cctc.202001294 Nickel-catalyzed regio- and diastereoselective hydroarylative and hydroalkenylative cyclization of 1,6-dienes, Zhengshuai Xu,Yitian Tang,Chaoren Shen,Hongru Zhang,Yuxin Gan,Xiaolei Ji,Xinxin Tian, Kaiwu Dong*, Chemical Communications, 2020, DOI: 10.1039/c9cc09450d Recent progress in transition-metal-catalyzed hydrocyanation of nonpolar alkenes and alkynes, Hongru Zhang,Xin Su,Kaiwu Dong*, Organic & Biomolecular Chemistry, 2019, DOI: 10.1039/c9ob02374g 第一作者 K. Dong, R. Sang, Z. Wei, J. Liu, R. Dühren, A. Spannenberg, H. Jiao, H. Neumann, R. Jackstell, R. Franke, M. Beller*, Cooperative catalytic methoxycarbonylation of alkenes: uncovering the role of palladium complexes with hemilabile ligands. Chem. Sci. 2018, 9, 2510-2516. K. Dong, R. Razzaq, Y. Hu, K. Ding,* Homogeneous Reduction of Carbon Dioxide with Hydrogen. Top. Curr. Chem. 2017, 375, 23-48. K. Dong, X.-F. Wu,* Carbonylations with CO2 as the CO Source and Reactivity Modifier. Angew. Chem. Int. Ed. 2017, 56,5399-5401. K. Dong,+ R. Sang,+ J. Liu, R. Razzaq, R. Franke, R. Jackstell, M. Beller, Palladium-Catalyzed Carbonylation of sec- and tert-Alcohols. Angew. Chem. Int. Ed. 2017, 56,6203-6207. K. Dong, R. Sang, X. Fang, R. Franke, A. Spannenberg, H. Neumann, R. Jackstell, M. Beller,* Efficient Palladium-catalyzed Alkoxycarbonylation of Bulk Industrial Olefins using Ferrocenyl Phosphines. Angew. Chem. Int. Ed. 2017, 56, 5267-5271. K. Dong,+ X. Fang,+ S. Gülak, R. Franke, A. Spannenberg, H. Neumann, R. Jackstell, M. Beller,* Highly active and efficient catalysts for alkoxycarbonylation of alkenes. Nat. Commun. 2017, 8, 14117-14123. K. Dong, S. Elangovan, R. Sang, A. Spannenberg, R. Jackstell, K. Junge, Y. Li,* M. Beller,* Selective catalytic two-step process for ethylene glycol from carbon monoxide. Nat. Commun. 2016, 7, 12075-12081. K. Dong,+ R. Sang,+ J.-F. Soule, C. Bruneau, R. Franke, R. Jackstell, M. Beller,* Efficient Domino Hydroformylation/Benzoin Condensation: Highly Selective Synthesis of α-Hydroxy Ketones. Chem. Eur. J. 2015, 21, 18033-18037. K. Dong, X. Fang, R. Jackstell, G. Laurenczy, Y. Li,* M. Beller,* Rh(I)-Catalyzed Hydroamidation of Olefins via Selective Activation of N–H Bonds in Aliphatic Amines. J. Am. Chem. Soc. 2015, 137, 6053-605 K. Dong, X. Fang, R. Jackstell, M. Beller,* A novel rhodium-catalyzed domino-hydroformylation-reaction for the synthesis of sulphonamides. Chem. Commun. 2015, 51, 5059-5062. K. Dong, Y. Li, Z. Wang, K. Ding,* Asymmetric Hydrogenation of α-Arylacrylic and β-Arylbut-3-enoic Acids Catalyzed by a Rh(I) Complex of a Monodentate Secondary Phosphine Oxide Ligand. Org. Chem. Front. 2014, 1, 155-160. K. Dong, Y. Li, Z. Wang, K. Ding,* Catalytic Asymmetric Hydrogenation of α-CF3- or β-CF3-Substituted Acrylic Acids using Rhodium(I) Complexes with a Combination of Chiral and Achiral Ligands. Angew. Chem. Int. Ed. 2013, 52, 14191-14195. K. Dong, Z. Wang, K. Ding,* Rh(I)-Catalyzed Enantioselective Hydrogenation of α-Substituted Ethenylphosphonic Acids. J. Am. Chem. Soc.2012, 134, 12474-12477.

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