程旭 - 南京大学 - 化学化工学院

个人简介

教育 1996.9-2000.8 南开大学化学系，获得本科学位 2000.9-2005.11 南开大学元素有机化学研究所，获得博士学位，研究方向为手性催化剂的设计和对映选择性催化反应，指导教师：周其林教授工作经历 2005.12-2008.11 德国Max-Planck煤炭研究所，从事博士后研究工作 2008.12-2009.12 美国德克萨斯州立Austin分校 2010.1至2012.6 美国普度大学化学系博士后 2012.9至今南京大学化学化工学院

研究领域

电化学可以将电能直接传递给化学分子，极强的驱动力，如何可控的利用这种驱动力，实现具有挑战性的物质转化，并控制这个过程的化学选择性，区域选择性，立体选择性是我们的研究兴趣所在。电化学可以现场活化惰性分子为高活性物种，这为减少在反应中使用高能试剂，转而采用多种惰性物种进行向活转化提供了可能，同时也为避免的化学化工中减少乃至避免使用危险性高的原料提供了方法。电化学合成可以通过阳极析氮，析氧，阴极析氢等过程，避免试剂量的还原剂/氧化剂的使用，这有利于开发具有高原子经济性，步骤经济性的合成反应，利用电能实现绿色合成

近期论文

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Weijie Ding, Mengfan Li, Jinkun Fan, Xu Cheng* Palladium-catalyzed asymmetric allylic 4-pyridinylation via electroreductive substitution reaction Nat. Commun.2022, 13, 5642. Lei Zhang, Xu Cheng*b, Qi-Lin Zhou*a Electrochemical Synthesis of Sulfonyl Fluorides with Triethyla-mine Hydrofluoride Chin. J. Chem. 2022, 40, 1687-1692 Weijie Dinga#, Jie Shenga#, Jin Li*b, Xu Cheng*a Electroreductive 4‑Pyridylation of Unsaturated Compounds Using Gaseous Ammonia as Hydrogen Source Org. Chem. Front. 2022, 9, 2634-2639. Shuai Liu, Xu Cheng* Insertion of ammonia into alkenes to build aromatic N-heterocycles Nat. Commun.DOI: 10.1038/s41467-022-28099-w Xu Cheng*a, Aiwen Lei*b, Tiansheng Mei*c, Hai-Chao Xu*d, Kun Xu*e, Chengchu Zeng*e Recent Applications of Homogeneous Catalysis in Electrochemical Organic Synthesis CCS Chem. Accepted, DOI: https://doi.org/10.31635/ccschem.021.202101451 Recent advances in organic electrosynthesis employing transition metal complexes as electrocatalysts Cong Maa, Ping Fanga, Zhao-Ran Liua, Shi-Shuo Xua, Kun, Xub*, Xu Chengc*, Aiwen Leid*, Hai-Chao Xue*, Chengchu, Zengb*, Tian-Sheng Meia Science Bulletin, 2021, 66, 2412-2429 Feng Liu, Jie Dai,*, Xu Cheng* Chin. J. Org. Chem. DOI: 10.6023/cjoc202105046 Contribution to the Special Issue: 100th Anniversary of College of Chemistry Nankai University Electrochemical Tandem Olefination and Hydrogenation Reaction with Ammonia Xiaofeng Zhang, Runze Jiang, and Xu Cheng* J. Org. Chem.2021, DOI: 10.1021/acs.joc.1c01024 Ring-Contraction of Hantzsch Ester and Derivatives to Pyrrole via Electrochemical Extrusion of Ethyl Acetate out of Aromatic Rings Xu Liu, Chang Liu, Xu Cheng* Green Chemistry, 2021, 23, 3468-3473 Chlorination Reaction of Aromatic Compounds and Unsaturated Carbon-Carbon Bonds with Chlorine on Demand Feng Liu, Na Wu, Xu Cheng* Org. Lett., 2021, 23, 3015-3020 Electrochemical Aziridination of Tetrasubstituted Alkenes with Ammonia Shuai Liu, Wenxuan Zhao, Jin Li1, Na Wu, Chang Liu, Xin Wang, Shuohao Li, Yan Zhu, Yong Liang*, Xu Cheng* CCS Chemistry, 2021, DOI: 10.31635/ccschem.021.202100826 Electrochemical Reduction of Nitroarenes with Gaseous Ammonia Chang Liu, † Jin Li, † Na Wu, and Xu Cheng* Org. Biomol. Chem., 2021, 19, 2468 - 2472 Electrochemical Allylic Hydrodefluorinative Reaction using Gaseous Ammonia Sheng Jie; Wu Na; Liu Xu; Liu Feng; Liu Shuai; Ding Weijie; Liu Chang; Cheng Xu Chin. J. Org. Chem.2020, 40, 3873-3880 Chemical‐Reductant‐Free Electrochemical Deuteration Reaction using Deuterium Oxide Xu Liu, Ruoyu Liu, Jiaxing Qiu, Xu Cheng*, Guigen Li Angew. Chem. Int. Ed. Accepted. Experimenting with a Suzuki–Miyaura Cross-Coupling Reaction That Demonstrates Tolerance toward Aldehyde Groups To Teach Undergraduate Students the Fundamentals of Transition-Metal-Catalyzed Reactions Jie Dai, Dadong Lu, Tao Ye, Shouyun Yu*, Xu Cheng* J. Chem. Edu.2019, 96, 2672-2675 Electrochemical Approach for Direct C−H Phosphonylation of Unprotected Secondary Amine Min Huang, Jie Dai, Xu Cheng,* and Mengning Ding* Org. Lett., 2019, 21, 7759-7762 An Electrochemical Cinnamyl C-H Amination Reaction Using Carbonyl Sulfamate Shuai Liu, Jin Li, Dalin Wang, Feng Liu, Xu Liu, Yongyuan Gao, Jie Dai, Xu Cheng* Chin. J. Chem. 2019,37, 570—574 Electrochemical hydrogenation with gaseous ammonia Jin Li, Linfeng He, Xu Liu, Xu Cheng*, Guigen Li Angew. Chem. Int. Ed. 2019, 58, 1759-1763 Application of Hantzsch Ester and Meyer Nitrile in Radical Alkynylation Reactions Xu Liu, Ruoyu Liu, Jie Dai, Xu Cheng*, and Guigen Li Org. Lett. 2018, 20, 6906-6909 Electrochemical Aziridination via Alkene Activation with a Sulfamate as Nitrogen Source Jin Li, Wenhao Huang, Jingzhi Chen, Lingfeng He, Xu Cheng*, Guigen Li Angew. Chem. Int. Ed. 2018, 57, 5695-5698.