鲍红丽 - 中国科学院海西研究院 -

个人简介

EDUCATION AND RESEARCH EXPERIENCE Since 12/2013 Professor Fujian Institute of Research on the Structure of Matter 12/2009-12/2013 Postdoc. 02/2004-06/2008 Ph.D. Shanghai Institute of Organic Chemistry & University of Science and Technology of China. (Advisor: Kuiling Ding & Tianpa You) 09/1998-07/2002 B.S. University of Science and Technology of China . (Advisor: Prof. Tianpa You) AWARDS AND HONORS 2021年中国科协十大代表 2021年由中国化学会授予“中国均相催化青年奖” 2020年获得第十五届福建青年科技奖 2019年获得Asian Core Program Lectureship Award,（Japan&Singapore） 2019年入选国家自然科学基金优秀青年基金 2018年获得福建省五四青年奖章 2018年福建省直机关三八红旗手 2017年获得ThiemeChemistryJournalAward（2017） 2017年获得第三届福州青年科技奖 2012年获得ChiltonAward

研究领域

Peroxides as Key Reagents for Organic Reactions Nonselective decomposition of peroxides into many different species is easy. How to harness the decomposition and selectively utilize the resulted species is another story. Our group is working on all kinds of peroxides and try to understand the behaviors of peroxides under different circumstances. There are still so many puzzles. At least we observed many ways to break bonds of alkyl peroxides. Different reaction occurs based on different decomposition style. Our research interests include but not limit to: 1) Work modes of peroxides 2) Alkyl peroxides as alkylating reagents and internal oxidants 3) Peroxides enabled new reactions 4) Unnatural amino acids synthesis.

近期论文

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Copper-Catalyzed Radical Enantioselective Carbo-Esterification of Styrenes Enabled by a Perfluoroalkylated-PyBox Ligand. Zaicheng Nie,§ Mong-Feng,§ Chiou, Jinfeng Cui, Yanjie Qu, Xiaotao Zhu, Wujun Jian, Haigen Xiong, Yajun Li and Hongli Bao,* Angew. Chem. Int. Ed. 2022. Accepted.(§These two authors contributed equally) Radical 1,2,3-Tricarbofunctionalization of α-Vinyl-β-Ketoesters Enabled by Carbon Shift from All-carbon Quaternary Center. Qi Zhang, Mong-Feng Chiou, Changqing Ye, Xiaobin Yuan, Yajun Li,* and Hongli Bao* Chem. Sci. 2022. DOI: 10.1039/D2SC00902A.[Link] Synthesis of unsymmetrically tetrasubstituted pyrroles and studies of AIEE in pyrrolo[1,2-a]pyrimidine derivatives. Taian Li,§ Mong-Feng Chiou,§ Yajun Li, Changqing Ye, Min Su, Mengyu Xue, Xiaobin Yuan, Chuanchuan Wang, Wen-Ming Wan, Daliang Li* and Hongli Bao* Chem. Sci. 2022. DOI: 10.1039/D2SC00837H.[Link] Palladium-catalyzed three-component 1,4-carboarylation of 1,3-enynes with malonic esters and aryl iodides. Jingjing Bao, Rongbiao Wei, Yajun Li* and Hongli Bao Synthesis 2022. Accepted Radical Oxyazidation of Alkenes in Pure Water. Jinfeng Cui, Huan Zhou,* Yajun Li* and Hongli Bao Synthesis 2022. DOI:10.1055/a-1804-8859. [Link] Living Covalent-Anionic-Radical Polymerization via a Barbier Strategy. Min Su, Yu-Jing Sheng, Yu-Jiao Chen, Tao Li, Quan-Xi Shi, Hang Xiao, Meng-Qin Pu, Hongli Bao, and Wen-Ming Wan* ACS Macro Lett. 2022, 11, 354–361. [Link] Asymmetric Radical Carboesterification of Dienes. Xiaotao Zhu, Wujun Jian, Meirong Huang, Daliang Li, Yajun Li, Xinhao Zhang and Hongli Bao* Nat. Commun., 2021, 12, 6670.[Link] Iron-Catalyzed Asymmetric Decarboxylative Azidation Kaikai Wang, Yajun Li, Xiaoyan Li, Daliang Li,* and Hongli Bao* Org. Lett. 2021, 23, 8847–8851.[Link] Barbier-Type Nitro/Nitroso Addition Polymerization as a Versatile Approach for Molecular Design of Polyarylamines through C–N Bond Formation. Min Su, Tao Li, Quan-Xi Shi, Hang Xiao, Hongli Bao*, and Wen-Ming Wan* Macromolecules 2021, 54, 9919–9926.[Link] Direct Synthesis of Pentasubstituted Pyrroles and Hexasubstituted Pyrrolines from Propargyl Sulfonylamides and Allenamides. Changqing Ye,§ Yihang Jiao,§ Mong-Feng Chiou, Yajun Li and Hongli Bao. Chem. Sci. 2021, 12, 9162-9167 (§These two authors contributed equally).[Link] Iron Phthalocyanine-Catalyzed Radical Phosphinoylazidation of Alkenes: A Facile Synthesis of β-azido-Phosphine Oxide with a Fast Azido Transfer Step. Xiaoxu Ma, Mong-Feng Chiou, Liang Ge, Xiaoyan Li, Yajun Li, Li Wu and Hongli Bao* Chin. J. Catal. 2021, 42, 1634-1640.[Link] Iron-Catalyzed Decarboxylative Heck-Type Alkylation of Con-jugate 1,3-Dienes Kaikai Wanga, Shaowei Chenb, Yajun Li, Daliang Li*, Hongli Bao* Chin. J. Org. Chem., 2021, 41, 2707-2714. [Link] Reductive Deuteration of Ketones with Magnesium and D2O for the Synthesis of α-Deutero-o-methyl-benzhydrol. Nengbo Zhu, Wen-Ming Wan, and Hongli Bao* Org. Synth. 2021, 98, 51-67.[Link] Regioselective Three-Component Synthesis of Vicinal Diamines via 1,2-Diamination of Styrenes. Jie Cao, Daqi Lv, Fei Yu, Mong-Feng Chiou, Yajun Li, and Hongli Bao* Org. Lett. 2021, 23, 3184–3189. [Link] Iron-Catalyzed Radical Asymmetric Aminoazidation and Diazidation of Styrenes. Daqi Lv, Qiao Sun, Huan Zhou, Liang Ge, Yanjie Qu, Taian Li, Xiaoxu Ma, Yajun Li and Hongli Bao* Angew. Chem. Int. Ed. 2021, 60, 12455–12460. [Link] Metal-free Alkynylsulfonylation of Vinylarenes. Fei Wang, Huan Zhou, Yajun Li, and Hongli Bao* Org. Chem. Front., 2021, 8, 1817-1822. [Link] Synthesis of Amidine Derivatives by Intermolecular Radical-Addition to Nitrile Groups of AIBN Derivatives. Min Su, Nengbo Zhu, Mong-Feng Chiou and Hongli Bao* Synlett 2021, 32, 395-400. [Link] (Invited paper by Prof. Ang Li and Prof. Chen Zhu) Copper-Catalyzed Three-component Oxycyanation of Alkenes. Yuehua Zeng, Yajun Li, Daqi Lv and Hongli Bao* Org. Chem. Front., 2021, 8, 908-914. [Link] Iron-catalysed Asymmetric Carboazidation of Styrenes. Liang Ge,§ Huan Zhou,§ Mong-Feng Chiou,§ Heming Jiang, Wujun Jian, Changqing Ye, Xiaoyan Li, Xiaotao Zhu, Haigen Xiong, Yajun Li, Lijuan Song, Xinhao Zhang,* and Hongli Bao* Nat. Catal. 2021. 4, 28–35.[Link] Highlighted by synform [Link] (§These three authors contributed equally) Radical azidation as a means of constructing C(sp3)-N3 bonds. Liang Ge, Mong-Feng Chiou, Yajun Li, Hongli Bao* Green Synth. Catal. 2020, 1, 86-120.