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Chuntao Wang, Rui Wu, Kai Chen*, Shifa Zhu*, Enantioselective Synthesis of Biscyclopropanes Using Alkynes as Dicarbene Equivalents, Angew. Chem. Int. Ed. 2023, 62, e202305864. DOI: 10.1002/anie.202305864.
Boxiang Liu, Zhicong Lin, Tairan Cheng, Tongxiang Cao, Shifa Zhu*, Synthesis of E-Dienyl Esters Using Acetylene as C2 Synthon, Org. Lett. 2023, 25, 3573-3577. DOI: 10.1021/acs.orglett.3c01209.
Rui Wu, Dong Zhu, Shifa Zhu*, Dirhodium: Carbene Transformations and Beyond, Org. Chem. Front., 2023, 10, DOI: 10.1039/D3QO00400G. (Invited Review)
Shiwei Lv, Zipeng Wang, Xiang Gao, Kai Chen*, Shifa Zhu*, 1,2-Difunctionalization of Acetylene Enabled by Light, Angew. Chem. Int. Ed. 2023, 62, e202300268. DOI: 10.1002/anie.202300268.
Kangkui Li, Xianyang Long, Shifa Zhu*, Photoredox/Nickel Dual Catalysis-Enabled Modular Synthesis of Arylallyl Alcohols with Acetylene as the Two-Carbon Synthon, ACS Catal.2023, 13, 2422-2431. DOI: 10.1021/acscatal.2c06178.
Zhicong Lin, Boxiang Liu, Yu Wang, Siju Li and Shifa Zhu*, Synthesis of Vinyl-Substituted Alcohols Using Acetylene as C2 Building Block, Chem. Sci., 2023, 14, Accepted. DOI: 10.1039/D2SC06400F
Boxiang Liu, Zhicong Lin, Yu Wang, Tairan Cheng, Tongxiang Cao, Shifa Zhu*, Trimerization of Acetylene and Alkene: Rapid Access to Polyenes, CCS Chem., 2023, 5, Accepted. DOI: 10.31635/ccschem.022.202202579.
Zhuwen Wei, Yang Chen, Jianghui Wang, Tao Yang, Zujin Zhao* and Shifa Zhu*, De Novo Synthesis of α-Oligo(arylfuran)s and Its Application in OLED as Hole-Transporting Material, Chem. Eur. J. 2023, 29, In Press (VIP). DOI: 10.1002/chem.202203444.
Zipeng Wang, Tongxiang Cao*, Shifa Zhu*, Gold-catalyzed enynal and enynol coupling by selectively steering two transient vinyl-gold intermediates, Org. Lett. 2023, 25, 9296-9300. DOI: 10.1021/acs,orglett.2c03890 .
Rui Wu, Yang Chen, Shifa Zhu*, Rh(II)-Catalyzed Enynal Cycloisomerization for Generation of Vinyl Carbene: Divergent Access to Polycyclic Heterocycles, ACS Catal. 2023, 13, 132-134. DOI: 10.1021/acscatal.2c04832
Qiu Shi, Yang Chen, Tongxiang Cao*, Shifa Zhu*, Construction of [2,5]-Furanophanes by Carbene-Mediated Alkynyl Migration Cyclization, Org. Lett. 2022, 24, 8142-8146. DOI: 10.1021/acs.orglett.2c03185.
Wendeng Li, He Zhang, Kai Chen, Huanfeng Jiang, Jianwei Sun and Shifa Zhu*, Palladium-Catalyzed Intramolecular Enantioselective C(sp3)-H Insertion of Donor/Donor Carbenes, Chem. Sci. 2022, 13, 12396-12402. DOI: 10.1039/D2SC03524C
Yang Chen, Shifa Zhu*, Modular Construction of a-Furanyl Ketones via Semi-pinacol Rearrangement-Mediated Ring Expansion, Org. Chem. Front.2022, 9, 6194-6199. DOI: 10.1039/D2QO01324J.
Rongyu Zhang, Meng Wu, Tongxiang Cao, Kui Luo, Fangjiao Huang, Ruoying Zhang, Zhipeng Huang, Jinming Zhou, Yongdong Wang, Shifa Zhu, Identification of the gossypol derivatives as andhydrogen receptor inhibitor, Bioorg. Med. Chem. Lett. 2022, 75, 128952. DOI: 10.1016/j.bmcl.2022.128952.
Shiwei Lü, Zipeng Wang and Shifa Zhu, Thiol-Yne Click Chemistry of Acetylene-Enabled Macrocyclization, Nat. Commun.2022, 13, 5001. DOI: 10.1038/s41467-022-32723-0.
Qiu Shi, Zhehui Liao, Zhili Liu, Jiajia Wen, Chenguang Li, Jiamin He, Jiazhen Deng, Shan Cen, Tongxiang Cao*, Jinming Zhou*, Shifa Zhu*, Dearomative Rearrangement: Divergent Synthesis of Benzazepines and Bridged Polycycloalkanones, Nat. Commun.2022, 13, 4402. DOI: 10.1038/s41467-22-31920-1.
Tairan Cheng, Boxiang Liu, Rui Wu and Shifa Zhu*, Cu-Catalyzed Carboboration of Acetylene with Michael Acceptors, Chem. Sci. 2022, 13, 7604-7609. DOI: 10.1039/D2SC02306G.
Qinglin Yao, Boxiang Liu, Tongxiang Cao and Shifa Zhu*, Migratory Insertion of Copper-Allenylidene from Propargyl Ester, Chem. Commun., 2022, 58, 4969-4972. DOI: 10.1039/D2CC00681B
Bo Yang, Shaodong Lu, Yongdong Wang and Shifa Zhu*, Diverse Synthesis of C2-Linked Functionalized Molecules via Molecular Glue Strategy with Acetylene, Nat. Commun., 2022, 13, 1858. DOI: 10.1038/s41467-022-29556-2.
Dong Zhu, Tongxiang Cao, Kai Chen* and Shifa Zhu*, Rh2(II)-Catalyzed Enantioselective Intramolecular Büchner Reaction and Aromatic Substitution of Donor-Donor Carbenes, Chem. Sci., 2022, 13, 1992-2000. DOI: 10.1039/D1SC05374D.
Yanmei Chen, Zhehui Liao, Tongxiang Cao* and Shifa Zhu*, An Efficient Method to Synthesize N/O, O-difluoroboron Complexes from Alkynes, Green Synth. Catal., 2022, 3, 89-94. DOI: 10.1016/j.gresc.2021.11.001.
Yang Chen, Pingchuan Shen, Tongxiang Cao, Hao Chen, Zujin Zhao* and Shifa Zhu*, Bottom-up Modular Synthesis of Well-Defined Oligo(arylfuran)s, Nat. Commun., 2021, 12, 6165. DOI: 10.1038/s41467-021-26387-5.
Shaotong Qiu, Xiang Gao and Shifa Zhu*, Dirhodium(II)-Catalysed Cycloisomerization of Azaenyne: Rapid Assembly of Centrally and Axially Chiral Isoindazole Frameworks, Chemical Science, 2021, 12, 13730-13736.
Hejiang Luo, Tongxiang Cao*, Shifa Zhu*, Divergent Synthesis of Ketone-Fused Indoles/Pyrroles via Metal-Guided Friedel-Crafts Cyclization, Chin. J. Org. Chem., 2021, 41, 3521. DOI: 10.6023oc202105021.
Bo Yang, Shi-Jun Li, Yongdong Wang*, Yu Lan*, Shifa Zhu*, Hydrogen radical-shuttle (HRS)-enabled photoredox synthesis of indanones via decarboxylative annulation. Nat. Commun., 2021, 12, 5257. DOI: 10.1038/s41467-021-25594-4.
Rui Wu, Jiajun Lu, Tongxiang Cao, Jun Ma, Kai Chen*, Shifa Zhu*, Enantioselective Rh(II)-Catalyzed Desymmetric Cycloisomerization of Diynes: Constructing Furan-Fused Dihydropiperidines with an Alkyne-Substituted Aza-Quaternary Stereocenter， J. Am. Chem. Soc., 2021, 143, 14916. DOI: 10.1021/jacs.1c07556.
Yi Kong, Tongxiang Cao* and Shifa Zhu*, TEMPO-Regulated Regio- and Stereoselective Cross-Dihalogenation with Dual Electrophilic X+ Reagents, Chin. J. Chem., 2021, 39, 3004. DOI: 10.1002/cjoc.202100472.
Shaotong Qiu, Tongxiang Cao* and Shifa Zhu*, Catalyst-Free Synthesis of Isoxazolidine from Nitrosoarene and Haloalkyne via 1,2-Halo-Migration/[3+2] Cycloaddition Cascade, Org. Biomol. Chem., 2021, 19, 3139. DOI：10.1039/d1ob00421b.
Zhehui Liao, Jiantao Zhang, Tongxiang Cao* and Shifa Zhu*, Copper Catalyzed Asymmetric Synthesis of Bicyclo[3.n.1]alkenones, J. Org. Chem., 2021, 86, 5388. DOI: 10.1021/acs.joc.1c00146.
Tongxiang Cao, Qiu Shi and Shifa Zhu*, Benzene-Free Synthesis of Multisubstituted Catechol via Oxidative Dearomatic Reorganization, Org. Lett., 2021, 23, 1411. DOI: 10.1021/acs.orglett.1c00071.
Zhili Liu, Lianfen Chen, Dong Zhu, and Shifa Zhu*, Formal Allylation and Enantioselective Cyclopropanation of Donor/Acceptor Rhodium(II) Azavinyl Carbenes, Org. Lett., 2021, 23, 1275. DOI: 10.1021/acs.orglett.0c04251.
Feng Wu, Tairan Cheng, and Shifa Zhu*, Construction of Partially Protected Nonsymmetrical Biaryldiols via Semipinacol Rearrangement of o-NQM Derived from Enynones, Org. Lett., 2021, 23, 71. DOI: 10.1021/acs.orglett.0c03717
Feng Wu, Shiwei Lu, and Shifa Zhu*, Regioselectivity-Switchable Intramolecular Hydroarylation of Ynone, Adv. Synth. Catal., 2020, 362, 5632. DOI:10.1002/adsc.202001152.
Feng Wu, Li Zhang and Shifa Zhu*, 1,4-Addition of o-naphthoquinone methides induced by silver-catalyzed cyclization of enynones: an approach to unsymmetrical triarylmethanes and benzo[f]chromenes, Org. Chem. Front., 2020, 7, 3387, DOI: 10.1039/d0qo00825g.
Ling Zhang, Qiu Shi, Tongxiang Cao* and Shifa Zhu*, Catalytic Regio- and Stereoselective Intermolecular [5+2] Cycloaddition via Conjugative Activation of Oxidopyrylium, Chem. Commun., 2020, 56, 9533, DOI: 10.1039/D0CC04309E.
Rui Wu#, Kai Chen#, Jun Ma#, Zhi-Xiang Yu* & Shifa Zhu*, Synergy of Activating Substrate and Introducing C-H···O Interaction to Achieve Rh2(II)-Catalyzed Asymmetric Cycloisomerization of 1,n-Enynes, Sci. China Chem., 2020, 63, 1230. DOI: 10.1007/s11426-020-9794-3.
Hejiang Luo, Chuan He, Huanfeng Jiang, and Shifa Zhu*, Rapid Access to Oxabicyclo[2.2.2]octane Skeleton through Cu(I)-Catalyzed Generation and Trapping of Vinyl-o-Quinodimethanes (Vinyl-o-QDMs), Chin. J. Chem., 2020, 38, 1052. DOI: 10.1002/cjoc.202000144.
Feng Wu, Shifa Zhu, Benzopyrylium Salts, Science of Synthesis Knowledge Updates, 2020, 1, 159; DOI: 10.1055/sos-SD-114-00178.
Ling Zhang#, Tongxiang Cao#, Huangfeng Jiang ang Shifa Zhu* Deconstructive Reorganization: De Novo Synthesis of Hydroxylated Benzofuran. Angew. Chem., Int. Ed., 2020, 59, 4670. DOI: 10.1002/anie.201915212.
Dong Zhu, Lianfen Chen, Hanlin Fan, Qinglin Yao and Shifa Zhu* Recent Progress on Donor and Donor-Donor Carbenes. Chem. Soc. Rev., 2020, 49, 908. DOI: 10.1039/C9CS00542K.
Jiantao Zhang, Zhehui Liao, Lianfen Chen, Huanfeng Jiang, Shifa Zhu*, Construction of Polycyclic Bridged Indene Derivatives by a Tandem 1, 3-Rearrangement/intramolecular Friedel-Crafts Cyclization of Propargyl Acetates, Chem. Commun., 2019, 55, 7382. DOI: 10.1039/c9cc03715b.
Jiantao, Zhang, Zhehui Liao, Lianfen Chen, Shifa Zhu*, Rapid Acess to Oxa-Bridged Bicylic Skeletons through Gold-Catalyzed Tendem Rearrangement Reaction, Chem, Eur. J., 2019, 25, 9405. DOI:10.1002/chem.201900807.(Hot paper , invited for OMCOS-20)
Shaotong Qiu, Renxiao Liang, Yongdong Wang, Shifa Zhu* Domino Reaction between Nitrosoarenes and Ynenones for Catalyst-Free Preparation of Indanone-Fused Tetrahydroisoxazoles, Org. Lett., 2019, 21, 2126. DOI:10.1021/acs.orglett.9b00426.
He Zhang, Tongxiang Cao, Hejiang Luo, Lianfen Chen, Shifa Zhu*, Enynone-Enabled Migratory Insertion and Schmittel Cyclization Cascade for the Synthesis of Furan-Fused Fluorenes, Org, Chem, Front., 2019, 6, 1118. DOI: 10.1039/c9qo00045c.
Feng Wu, Shifa Zhu* A Strategy to Obtain o-Naphthoquinone Methides: Ag(I) - Catalyzed Cyclization of Enynones for the Synthesis of Benzo[h] chromanes and Naphthopyryliums, Org. Lett., 2019, 21, 1488. DOI: 10.1021/acs.orglett.9b00281.
Feng Wu, Lianfen Chen,* Yongdong Wang, Shifa,Zhu*, Gold-Catalyzed Generation of Azafulvenium from Enyne Sulfonamide: Rapid Access to Full-Substituted Pyrroles, Org. Chem. Front., 2019, 6, 480. DOI: 10.1039/C8QO01278D
Tongxiao Cao, Lianfen Chen, Shifa Zhu* Mechanism-Guided Scaffold Diversification: Perturbing and Trapping the Intermediates of Maltol-Type Cascade Claisen Rearrangement, Org. Lett., 2019, 21, 90. DOI: 10.1021/acs.orglett.8b03519
Lianfen Chen, Zhili Liu, Shifa Zhu* Donor- and acceptor-enyanls/enynones, Org. Biomol. Chem., 2018, 16, 8884. DOI: 10.1039/C8OB02348D (Invited)
Dong Zhu, Liangfen Chen, He Zhang, Zhiqiang Ma, Huangfeng Jiang, Shifa Zhu* Catalyst-Controlled Highly Chemo- and Stereoselective Allylic C-H Insertion and Cyclopropanation of Donor/Donor-Carbenes, Angew.Chem., Int. Ed., 2018, 57, 12405. DOI: 10.1002/anie.201805676.
Changyuan Zhang, Lianfen Chen, Kai Chen, Chuntao Wang, Zurong Xu, Huangfeng Jiang, Shifa Zhu* Cu(I)-Catalyzed Stereoselective Synthesis of Trisubstituted Z-enol Esters via Interrupting the 1,3-O-transposition Reaction, Org. Chem. Front., 2018, 5, 2510. DOI:10.1039/c8qo00664d
Tongxiang Cao, Yi Kong, Kui Luo, Lianfen Chen, and Shifa Zhu*, Cascade Claisen Rearrangement: Rapid Synthesis of Polysubstituted Salicylaldehydes and Total Synthesis of Hemigossypol and Gossypol, Angew. Chem., Int. Ed., 2018, 57, 8702. DOI: 10.1002/anie.201801612.
Lianfen Chen, Kai Chen, Shifa Zhu*, Transition-Metal-Catalyzed Intramolecular Nucleophilic Addition of Carbonyl Groups to Alkynes, Chem, 2018, 4, 1208. DOI: 10.1016/j.chempr.2018.02.001.
Jiantao Zhang, Lianfen Chen, Huanfeng Jiang and Shifa Zhu*, Catalytic [1,3] O-to-C Rearrangement: Rapid Access to Bridged Bicyclic System, Chem. Eur. J., 2018, 24, 6927. DOI: 10.1002/chem.201801062. (Hot papper)
Hejiang Luo, Renxiao Liang, Lianfen Chen*, Huanfeng Jiang and Shifa Zhu*, A silver-catalyzed three-component reaction via stabilized cation: synthesis of polysubstituted tetrahydronaphthols and tetrahydronaphthylamines, Org. Chem. Front., 2018, 5, 1160. DOI: 10.1039/C7QO01122A
Kui Luo, Ling Zhang, Huanfeng Jiang, Lianfen Chen* and Shifa Zhu*, Selectivity-switchable construction of benzo-fused polycyclic compounds through a gold-catalyzed reaction of enyne-lactone, Chem. Commun., 2018, 54, 1893. DOI: 10.1039/C7CC09786G.
Changyuan Zhang, Lianfen Chen, Kai Chen, Huanfeng Jiangand Shifa Zhu*, Iron/zinc-catalyzed benzannulation reactions of 2-(2-oxo-alkyl)benzketones leading to naphthalene and isoquinoline derivatives, Org. Chem. Front., 2018, 5, 1028. DOI: 10.1039/C7QO01152K.(Hot papper)
Renxiao Liang, Jiantao Zhang, Lianfen Chen*, and Shifa Zhu*, Efficient Assembly of Tetracyclic Framework of Fluorenols through Silver-Catalyzed Tandem Reaction of Acceptor-Enynals and Alkynes via Unfavorable 6-endo-dig Cyclization, Asian J. Org. Chem., 2018, 7, 545. DOI: 10.1002/ajoc.201700613
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