施敏 - 中国科学院上海有机化学研究所 - 金属有机化学国家重点实验室

个人简介

教育 1988年4月–1991年3月,日本大阪大学工学部,获博士学位 1985年10月-1988年3月,日本歧阜大学工业化学系,获硕士学位 1980年9月-1984年7月,华东理工大学精细化工系,获学士学位工作经历 1998年4月, 进有机所工作，担任课题组长和博士生导师 1996年12月-1998年3月,日本科学技术振兴事业团,从事博士后的研究工作 1993年4月-1995年10月,日本歧阜药科大学药品合成化学研究室,助教 1995年10月-1996年12月,美国俄克拉亥玛大学从事博士后的研究工作 1991年4月-1993年3月,日本歧阜Shellac高分子材料公司开发部,技术员

研究领域

绿色化学-二氧化碳的固定，小分子活化，环境友好的硝化反应，在超临界二氧化碳流体中的化学反应。手性催化－新型的手性配体的合成，不对称Morita-Baylis-Hillman反应的研究，有机小分子催化的反应研究。金属有机化学－基于张力分子的新基元反应的开发

近期论文

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Rhodium/Silver Synergistic Catalysis in Highly Enantioselective Cycloisomerization/Cross Coupling of Keto-Vinylidenecyclopropanes with Terminal Alkynes. Song Yang,a Kang-Hua Rui,a Xiang-Ying Tang,c Qin Xu,a and Min Shi,*a,b,c J. Am. Chem. Soc. 2017, 139, 5957-5964. Metal-Free Cross-coupling of Arylboronic acid and Derivatives with DAST-type reagents for the Direct Access of Diverse Aromatic Sulfinamides and Sulfonamides. Qiang Wang, Xiang-Ying Tang,* and Min Shi,* Angew. Chem., Int. Ed. 2016, 55, 10811-10815. Catalyst-dependent Stereodivergent and Regioselective Synthesis of Indole-fused Heterocycles through Formal Cycloadditions of Indolyl-allenes. Liang-Yong Mei,? Yin Wei,? Xiang-Ying Tang,?* Min Shi,? ?* J. Am. Chem. Soc. 2015, 137, 8131-8137. Phosphine-Catalyzed Annulations of 4,4-Dicyano-2-Methylenebut-3-Enoates with Maleimides and Maleic Anhydride.Xiao-Nan Zhang, Gen-Qiang Chen, Xiang-Ying Tang, Yin Wei, and Min Shi,* Angew. Chem., Int. Ed. 2014, 53, 10768-10773. Gen-Qiang Chen, Xiao-Nan Zhang, Yin Wei, Xiang-Ying Tang,* and Min Shi,* Catalyst Dependent Divergent Synthesis of Pyrroles from 3-Alkynyl Imine Derivatives: Non-carbonylative and Carbonylative Approach. Angew. Chem., Int. Ed. 2014, 53, 8492-8497. Kai Chen,? Zi-Zhong Zhu,? Yong-Sheng Zhang,? Xiang-Ying Tang,?,* and Min Shi,?,?,* RhII-Catalyzed Intramolecular Cycloisomerizations of Methylenecyclopropanes with N-sulfonyl 1,2,3-triazoles. Angew. Chem., Int. Ed. 2014, 53, 6645-6649. Di-Han Zhang, Xiang-Ying Tang,* Min Shi,* Gold-catalyzed tandem reactions of methylenecyclopropanes and vinylidenecyclopropanes. Acc. Chem. Res. 2014, 47, 913-924. Jin-Ming Yang,? Cheng-Zhi Zhu,? Xiang-Ying Tang,?* and Min Shi,?,?,* Rhodium(II)-Catalyzed Intramolecular Annulation of 1-Sulfonyl-1,2,3-triazoles with Pyrrole and Indole rings: Facile Synthesis of N-bridgehead Azepine Skeletons. Angew. Chem., Int. Ed. 2014, 53, 5142-5146. Long Huang,a Hai-Bin Yang,a Di-Han Zhang,a Zhen Zhang,b Xiang-Ying Tang,a Qin Xu,b* and Min Shi,a,b* Gold-Catalyzed Intramolecular Regio- and Enantioselective Cycloisomerization of 1,1-Bisindolyl-5-alkynes. Angew. Chem., Int. Ed. 2013, 52, 6767-6771. Pei C.-K, Jiang Y, Wei Y, Shi M,* Enantioselective Synthesis of Highly Functionalized Phosphonate Substituted Pyrans or Dihydropyrans: Asymmetric [4+2] Cycloaddition of ?, ?-Unsaturated ?-Ketophosphonates with Allenic Esters. Angew. Chem., Int. Ed. 2012, 51, 11328-11332. Shi M*, Lu J-M, Wei Y, Shao L-X, Rapid generation of molecular complexity in the Lewis or Br?nsted acid-mediated reactions of methylenecyclopropanes. Acc. Chem. Res. 2012, 45, 641-652. Lu B-L, Dai L-Z, Shi M,* Strained Small Rings in Gold-Catalyzed Rapid Chemical Transformations. Chem. Soc. Rev. 2012, 41, 3318-3339.