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过渡金属催化惰性碳氢键活化的研究 不对称催化:包括手性配体的合成应用和不对称催化反应的研究

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Feng. J.-J.; Chen. X.-F.; Shi, M.; Duan, W.-L.* Palladium-Catalyzed Asymmetric Addition of Diarylphosphines to Enones toward the Synthesis of Chiral Phosphines J. Am. Chem. Soc. 2010, 132, 5562. Duan, W.-L.; Imazaki, Y.; Shintani, R.*; Hayashi, T.* Asymmetric Construction of Chiral C–N Axes through Rhodium-Catalyzed 1,4-Addition. Tetrahedron 2007, 63, 8529. Duan, W.-L.; Iwamura, H.; Shintani, R.*; Hayashi, T.* Chiral Phosphine–Olefin Ligands in the Rhodium-Catalyzed Asymmetric 1,4-Addition Reactions. J. Am. Chem. Soc. 2007, 129, 2130. Shintani, R.; Duan, W.-L.; Hayashi, T.* Rhodium-Catalyzed Asymmetric Construction of Quaternary Carbon Stereocenters: Ligand-Dependent Regiocontrol in the 1,4-Addition to Substituted Maleimides. J. Am. Chem. Soc. 2006, 128, 5628. Shintani, R.; Duan, W.-L.; Nagano, T.; Okada, A.; Hayashi, T.* Chiral Phosphine–Olefin Bidentate Ligands in Asymmetric Catalysis: Rhodium-Catalyzed Asymmetric 1,4-Addition of Aryl Boronic Acids to Maleimides. Angew. Chem., Int. Ed. 2005, 44, 4611. Duan, W-L.; Shi, M.*; Rong, G.-B. Synthesis of Novel Axially Chiral Rh-NHC Complexes Derived from BINAM and Application in the Enantioselective Hydrosilylation of Methyl Ketones. Chem. Commun. 2003, 2916.

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