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固态超分子化学及其晶体工程。主要包括:(1)有机超分子、药物共晶分子的晶体生长、同质多晶现象、结构与性能关系研究;(2)“二次球”策略在超分子化学的应用; (3)超分子化学的固态合成;(4)有机化合物的粉末衍射结构测定.

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H. Y. Guan, Z. Wang, A. Famulari, X. Wang, F. Guo*, J. Marti-Rujas*, Synthesis of Chelating Complexes through Solid-State Dehydrochlorination Reactions via Second Sphere Coordination Interaction with Metal Chlorides: A Combined Experimental-Molecular Modeling Study, Inorg. Chem., 2014, 53, 7438-7445. F. Guo*, H. D. Shao, Q. Yang, A. Famulari, J. Marti-Rujas*, Mechanochemicaldehydrochlorination and chelation reaction in the solid state: from a molecular salt to a coordination complex, CrystEngComm, 2014, 16, 969-973. F. Guo*, M. Q. Zhang, A. Famulari, J. Marti-Rujas*, Solid state transformations in stoichiometric hydrogen bonded molecular salts: ionic interconversion and dehydration processes”, CrystEngComm, 2013, 15, 6237-6243. L. Li, Y. Q. Fu, F. Guo*, J. Gao, J. Tong, Z. F. Zhou, Polymorphism and photoluminescence in a naphthalene-based ligand, and its supramolecular structures through second-sphere coordination with the [CoCl4](2-) anion, RSC Adv., 2013, 3, 11594-11600. H.B. Shen, J. J. Li, H.Y. Shang, J. Z. Niu, W.W. Xu, H. Z. Wang, F. Guo*, L.S. Li*, Phosphine-Free Synthesis from 1D Pb(OH)Cl Nanowires to OD and 1D PbSeNanocrystals, ACS Appl. Mater. Interfaces, 2013, 5, 10331-10336. F. Guo*, H. L. Li, L. Li, H. C. Yu, N. Lu, J. Tong, Structure and inclusion property of supramolecular host framework [H-2 L1][XCl4], L1=N,N,N',N'-tetra-p-methoxybenzyl-ethylenediamine; X = Fe, Co, Pd, Struct. Chem., 2013, 24, 1111-1119. F. Guo*, H. C. Yu, L. Li, F. Xia, J. Tong, B. X. Wang, Halogen anion-directed helical host chain and the effect of halogen anions on the inclusion property, Supramol. Chem., 2013, 25, 173-179. F. Guo,* L. Li, Y. N. Zhang, J. Tong, C. L. Song, F. Xia, W. S. Guo, Structure and inclusion behaviour of five supramolecular inclusion solids constructed from flexible organic layers with [Fe(CN)(6)](3-) as pillars by second-sphere coordination, Supramol. Chem., 2012, 24, 415-423. F. Guo*, M. Q. Zhang, N. Lu, et al. Co-crystal of [CuCl4](2-) and L1 and its inclusion compounds with three different guests (L1=N,N,N’,N’-tetra-p-methoxybenzyl-ethylenediamine), CrystEngComm, 2011, 13, 6753-6758. F. Guo*, F. Xia, H. Y. Guan, et al. Distinct supramolecular inclusion solids built by second sphere coordination of cobalt chloride anion with N,N,N ',N '-tetra-p-methylbenzyl-ethylenediamine, Solid State Sci., 2011, 13, 59-65. F. Guo*, S. Zhang, H. Y. Guan, et al., Inclusion of an anion guest within a molecular host formed by (4,6-dimethyl-1,3-phenylene)bis(N,N-dibenzylmethane) and [CuCl4](2-)/[TeCl6](2-) through second-sphere coordination, J. Coordin. Chem., 2011, 64, 2223-2233. F. Guo*, F. Xia, N. Lu, et al., Supramolecular inclusion of a pillared double-layered host by an anion-directed second-sphere coordination, Supramol. Chem., 2010, 22, 548-553. F. Guo*, N. Lu, J. Tong, et al. Layered structures constructed by second-sphere coordination via N-H ···Cl and C-H···Cl hydrogen bonding: synthesis and crystal structures of tribenzylamine and [MCl6] (M = Sn, Re, and Te), J. Coordin. Chem., 2010, 63, 809-818. E. Y. Cheung, K. Fujii, F. Guo, K. D. M. Harris*, S. Hasebe, R. Kuroda*, Stuctural Chemistry of a New Chiral Anhydrous Phase of Ru(bipy)(3)(ClO4)(2) Established from Powder X-ray Diffraction Analysis, Crystal Growth & Des., 2011, 11, 3313-3317. J. Marti-Rujas, A. Morte-Rodenas, F. Guo; N. Thomas, K. Fujii, B. M. Kariuki, K.D. M. Harris*,A Solid-State Dehydration Process in an Organic Material Associated with Substantial Hydrogen-Bond Reorganization, Investigated by Powder X-ray Diffraction, Cryst. Growth & Des., 2010, 10, 3176-3181. K. Fujii, Y. Ashida, H. Uekusa, F. Guo, K.D.M. Harris*, Selective transformation pathways between crystalline forms of an organic material established from powder X-ray diffraction analysis, Chem. Commun., 2010, 46, 4264-4266. F. Guo; J. Marti-Rujas, Javier; Z. G. Pan, C. E. Hughes, K. D. M. Harris*, Direct Structural Understanding of a Topochemical Solid State Photopolymerization Reaction, J. Phys. Chem. C., 2008, 112, 19793-19796. F. Guo, E. Y. Cheung, K.D.M. Harris,* Contracting solid state structures of trithiocyanuric acid and cyanuric acid, Cryst. Growth & Des., 2006, 6, 846-848. F. Guo, M.Casadesus, E. Y. Cheung, M. P. Coogan*, K. D.M. Harris*, On the spontaneous induction of chirality in the preparation of Werner's complex cis-[CoBr(NH3)(en)(2)]Br-2, Chem. Commun. 2006, 17, 1854-1856. S. Y. Ahn, F. Guo, B. M. Kariuki, K. D. M. Harris*, Abundant polymorphism in a system with multiple hydrogen-bonding opportunities: Oxalyldihydrazide, J. Am. Chem. Soc., 2005, 128, 8441-8452. F. Guo, K. D. M. Harris*, Structural understanding of a molecular material that is accessed only by a solid-state desolvation process: The scope of modern powder X-ray diffraction techniques, J. Am. Chem. Soc., 2005,127, 20, 7314-7315. F. Guo, W.S. Guo*, F. Toda*, Supramolecular Stereoisomer-the Conformational Isomer of 1,1,6,6 - tetraphenylhexa-2,4-diyne-1,6-diol in the Different Inclusion Compounds, CrystEngComm, 2003, 5, 45-48.

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