董志兵 - 武汉工程大学 - 化学与环境工程学院

个人简介

董志兵，男，湖北鄂州人,1980年生。教授、博士，“楚天学者计划”楚天学子特聘教授，化学与环境工程学院副院长。2007年9月-2008年9月赴德国慕尼黑大学从事访问研究(导师是德国科学院院士、法国科学院院士、巴伐利亚科学院院士PaulKnochel教授)；2008年12月博士毕业(德国慕尼黑大学和南开大学联合培养博士)；2010年3月2011年3月，日本东京大学理学院ShuKobayashi(小林修)教授小组博士后；2011年3月-2012年4月，在德国亚琛工业大学有机所Carstenbolm教授(JOC副主编)小组从事洪堡学者研究；2013年9月-2014年9月，在武汉大学做访问学者(合作导师：雷爱文教授，省教育厅青年骨干教师计划)；2017年11月-2018年10月，在德国慕尼黑大学做访问学者(合作导师：PaulKnochel教授德国洪堡基金会、中国留学基金委、德国西门子基金会共同资助)；2012年5月-至今，“楚天学者计划楚天学子特聘教授。长期从事有机合成方法学及其应用研究，用以合成有药物活性的化合物以及开发功能性新材料，已经在《OrganicLetters)、、《GreenChemistry》、《Chemistry-AEuropeanJournal》《EuropeanJournalofOrganicChemistry.》、《TetrahedronLetters》、《Synthesis,》《JournalofOrganometallicChemistry》等主流刊物上发表了研究论文50余篇(均被SCI收录)。先后主持国家自然科学基金、教育部、科技厅、教育厅等纵向项目7项。研究小组和德国、日本、韩国、法国以及国内科研院所的同行保持紧密的合作和交流。小组经费充足，各种化学试剂种类已达100种，实验室硬件设施良好，能满足有机合成的常规操作。目前的管理和运作模式均参考欧洲实验室。本组培养的硕士生、本科」生多次获得国家奖学金、特等奖学金，在各级比赛中均取得了优秀的成绩。

研究领域

主要研究方向：主要从事有机合成方法学研究，用以合成有药物活性的化合物以及开发功能性新材 1)过渡金属催化的CC，CN，CO以及C-S键形成反应； 2)金属有机试剂参与的有机化学反应； 3)功能性配合物的设计合成以及不对称催化 4)多组分串联反应、水相有机合成

近期论文

查看导师最新文章（温馨提示：请注意重名现象，建议点开原文通过作者单位确认）

1)ChemoselectiveChan-LamCouplingReactionsbetweenBenzimid-azoline-2-ThionesandArylboronicAcids,XingLiu,Zhi-BingDong,J.Org.Chem.,2019,accepted,DOI:10.1021/acs.joc.9b01370. 2)DivergentTotalSynthesisofAspinolidesB,EandJ,Cai-ZhuChang,Jia-LinGeng,Yu-GuoDu,Zhi-BingDong*,JunLiu*,Tetrahedron2019,75,3933-3938. 3)Synthesisofalkyldithiocarbamatesbyusingthiuramdisulfidereagents:ametal-freeC(sp3)-Sbondformation,YuCheng,Han-YingPeng,Zhi-BingDong*,TetrahedronLett.,2019,60,617-620. 4)Transition-metal-freeC(sp3)−Scouplinginwater:synthesisofbenzyldithiocarbamatesusingthiuramdisulfidesasorganosulfursource,Han-YingPeng,Zhi-BingDong*.Eur.J.Org.Chem.,2019,949-956. 5)Synthesisoffunctionalizeddiaryldulfidesbycobalt-catalyzedcouplingbetweenarylzincpivalatesanddiaryldisulfides,Zhi-BingDong*,MoritzBalkenhohl,EricTan,PaulKnochel*,Org.Lett.,2018,20,7581-7584. 6)One-potsynthesisof2-benzyl/2-Allylsubstitutedthiobenzoazolesusingtransition-metal-freeconditionsinwater,Shi-BoZhang,XingLiu,Ming-YuanGao,Zhi-BingDong*,J.Org.Chem.,2018,83,14933-14941. 7)SynthesisofPhenylDithiocarbamatesStartingfromSodiumDialkyldithiocarbamatesandArylBoronicAcids:aCopperCatalyzedS-Arylation.Ming-YuanGao,WanXu,Shi-BoZhang,Yue-ShengLi,Zhi-BingDong*.Eur.J.Org.Chem.,2018,6693-6698. 8)Copper-CatalyzedandAir-MediatedMildCross-DehydrogenativeCouplingofArylThioureasandH-Phosphonates:SynthesisofThiophosphonates.Cai-ZhuChang,XingLiu,HuiZhu,Zhi-BingDong*.J.Org.Chem.,2018,83,13530-13535. 9)Copper(I)-CatalyzedTandemOne-PotSynthesisof2-Arylthiobenzothiazolesand2-ArylthiobenzoxazolesinWater.XingLiu,Shi-BoZhang,HuiZhu,Zhi-BingDong*.J.Org.Chem.,2018,83,11703-11711. 10)Copper(II)-PromotedCascadeSynthesisof2-AminobenzothiazolesStartingfrom2-IodoanilinesandSodiumDithiocarbamates.HuiZhu,Shi-BoZhang,XingLiu,YuCheng,Han-YingPeng,Zhi-BingDong*.Eur.J.Org.Chem.,2018,5711–5716. 11)AlCl3-PromotedSynthesisof2-MercaptoBenzoheterocyclesbyUsingSodiumDimethyldithiocarbamateasThiocarbonylSurrogate.XingLiu,Shi-BoZhang,Zhi-BingDong*.Eur.J.Org.Chem.,2018,5406-5411. 12)FacilesynthesisofS-arylisothioureasviatheS-arylationofarylthioureaswitharyliodidesinwater.XingLiu,HuiZhu,Shi-BoZhang,YuCheng,Han-YingPeng,Zhi-BingDong*.TetrahedronLett.,2018,59,3165-3170. 13)AnEfficientChan-LamS-ArylationofArylthioureaswithArylBoronicAcids.XingLiu,Shi-BoZhang,Hui,Zhu,YuCheng,Han-YingPeng,Zhi-BingDong*.Eur.J.Org.Chem.,2018,4483-4489. 14)Copper-CatalyzedS-ArylationofArylthioureasbyUsingDiaryliodoniumSalts.HuiZhu,XingLiu,YuCheng,Han-YingPeng,Yue-ShengLi,Zhi-BingDong*.Synthesis2018,50,2247-2254. 15)Copper-catalyzedsynthesisofarylthioamidesfromarylaldehydesandtetramethylthiuramdisulfide.Meng-TianZeng,MinWang,Han-YingPeng,YuCheng,Zhi-BingDong*.Synthesis2018,50,644-650. 16)CoppercatalyzedS-arylationstartingfromarylboronicacidsandtetraalkylthiuramdisulfide.WanXu,FanGao,Zhi-BingDong*.Eur.J.Org.Chem.,2018,821-828. 17)Phenyldithiocarbamates:efficientsulfurationreagentsinChan-Lamcouplingreaction.YuCheng,XingLiu,Zhi-BingDong*.Eur.J.Org.Chem.,2018,815-820. 18)AhighlyefficientCuCl2-catalyzedC-Scouplingofaryliodideswithtetraalkylthiuramdisulfides:synthesisofaryldithiocarbamates.QiangCao,Han-YingPeng,YuCheng,Zhi-BingDong*.Synthesis2018,50,1527-1534. 19)ControlledtuningofLCSTbasedonpoly(N-isopropylacrylamide)Hydroxypropylcellulosetemperature-sensitivehydrogelbyelectronbeampre-radiationmethod,YueshengLi,JiangtaoQin,HuaxiBao,YanHan,XianglinZeng,HuaZheng,YaqiongHuang,XiangxiangXia,Zhi-BingDong,RenhuoHu,YiLiu,J.Polym.Res.,2018,25,19. 20)ControlledpreparationandhighlyphotocatalyticactivityofportableMCC-g-GMA@TiO2photocatalystbypre-radiationgrafting-embeddingmethod,Yue-ShengLia,Jiang-TaoQin,YanHan,Ji-FuDu,Zhi-BingDong,Shao-FaSun,YiLiu,Appl.Catal.B:Environ.2017,218,101–110. 21)Copper-catalyzedC(sp2)-Scouplingreactionsforthesynthesisofaryldithiocarbamateswiththiuramdisulfidereagents.Zhi-BingDong*,XingLiu,CarstenBolm*.Org.Lett.,2017,19,5916-5919. 22)Anenvironmentallybenignandefficientsynthesisofsubstitutedbenzothiazole-2-thiol,benzoxazole-2-thiol,benzimidazoline-2-thioneinwater.XingLiu,MinLiu,WanXu,Meng-TianZeng,HuiZhu,Cai-ZhuChang,Zhi-BingDong*.GreenChem.,2017,19,5591-5598. 23)FluorinatedporousconjugatedpolyporphyrinsthroughdirectC-Harylationpolycondensation:preparation,porosity,anduseasheterogeneouscatalystsforBaeyer-Villigeroxidation.QiangCao,QingYin,QiChen*,Zhi-BingDong*,Bao-HangHan*.Chem.Eur.J.,2017,41,9831-9837. 24)Nickel-catalyzedC-Scoupling:synthesisofdiarylsulfidesstartingfromphenyldithiocarbamatesandiodobenzenes.XingLiu,QiangCao,WanXu,Meng-TianZeng,Zhi-BingDong*.Eur.J.Org.Chem.,2017,5795-5799. 25)Palladium-catalyzedsynthesisof2-aminobenzothiazolesviatandemreaction.WanXu,Meng-TianZeng,MinLiu,ShaShaLiu,Yue-ShengLi,Zhi-BingDong*.Synthesis2017,49,3084-3090. 26)Selectivesynthesisof2-aminobenzoxazolesand2-mercaptobenzoxazolesbyusingo-aminophenolsasstartingmaterial.MinLiu,Meng-TianZeng,WanXu,LiWu,Zhi-BingDong*.TetrahedronLett.,2017,58,4352-4356. 27)Copper-catalyzedC-Scrosscouplingreaction:S-arylationofarylthioureas.HuiZhu,XingLiu,Cai-ZhuChang,Zhi-BingDong*.Synthesis2017,49,5211-5216. 28)Copper-catalyzedS-arylationoftetraalkylthiuramdisulfidesbyusingdiaryliodoniumsalts.Meng-TianZeng,WanXu,XingLiu,Cai-ZhuChang,HuiZhu,Zhi-BingDong*.Eur.J.Org.Chem.,2017,6060-6066. 29)Coppercatalyzedsynthesisofbenzoxazolesandbenzothiazolesviatandemmanner.WanXu,Meng-TianZeng,Sha-ShaLiu,Yue-ShengLi,Zhi-BingDong*.TetrahedronLett.,2017,58,4289-4292. 30)BasepromotedsynthesisofO-aryl(alkyl)N,N-dimethylthiocarbamatesstartingfromcheapandenvironmentallybenigndisulfide.Zhi-BingDong*,MinWang,HuiZhu,XingLiu,Cai-ZhuChang.Synthesis2017,49,5258-5262. 31)Palladium-catalyzedtandemsynthesisof2-aminobenzothiazolesstartingfromunreactive2-chloroanilines.WanXu,Meng-TianZeng,MinLiu,XingLiu,Cai-ZhuChang,HuiZhu,Yue-ShengLi,Zhi-BingDong*.Chem.Lett.,2017,46,641-643. 32)Iodobenzene-promotedPd-catalysedortho-directedC–Hactivation:thesynthesisofbenzothiazolesviaintramolecularcoupling.Meng-TianZeng,WanXu,MinLiu,XingLiu,Cai-ZhuChang,HuiZhu,Zhi-BingDong*.Synopen2017,1,1-7. 33)Copper-catalyzedamidationofbenzoicacidsusingtetraalkylthiuramdisulfidesasaminesources.Meng-TianZeng,WanXu,MinLiu,XingLiu,Cai-ZhuChang,HuiZhu,Zhi-BingDong*.Syn.Comm.,2017,47,1434-1440. 34)Copper-catalyzedtandemreactionof2-haloanilineswiththiocarbamoylchloride:synthesisof2-aminobenzothiazoles.Cai-ZhuChang,WanXu,Meng-TianZeng,MinLiu,XingLiu,HuiZhu,Zhi-BingDong*.Syn.Comm.,2017,47,1262-1267. 35)Metal-freeortransition-metal-catalyzedone-potsynthesisof2-aminobenzothiazoles.WanXu,Meng-TianZeng,MinLiu,XingLiu,Cai-ZhuChang,HuiZhu,Zhi-BingDong*.J.Sulf.Chem.,2017,38,644-654. 36)BasepromotedsynthesisofN-phenyl-benzamidesbyN-benzoylationofdimethylphenylthioureas.XingLiu,WanXu,Meng-TianZeng,MinLiu,Cai-ZhuChang,HuiZhu,Zhi-BingDong*.J.Chem.Res.,2017,41,484-486. 37)Scaled-upNegishi-couplingofarylhalidesbearingunprotectedamideswithKnochel-typeorganozincreagents.Jia-ChaoXiong,WanXu,Zhi-BingDong*.J.Chem.Res.,2017,41,569-570. 38)Afacilesynthesisofsubstitutedarylthioureasinthepresenceofsodiumhydride.QiangCao,FangLiu,MinWang,WanXu,Meng-TianZeng,MinLiu,Yue-ShengLi,Zhi-BingDong*.J.Chem.Res.,2017,41,301-303. 39)NaH-promotedtransformationofarylthioureastoaryl-isothioureasbyS-allylationandS-benzylationreactions.MinLiu,Meng-TianZeng,WanXu,Cai-zhuChang,XingLiu,HuiZhu,Yue-shengLi,Zhi-BingDong*.J.Chem.Res.,2017,41,165-167. 40)Across-couplingsynthesisoffunctionalisedbiarylsusingKnochel-typeorganozincreagentsandapyridineenhancedpalladiumcatalyst.MinWang,FangLiu,Meng-TianZeng,WanXu,MinLiu,Zhi-BingDong*.J.Chem.Res.,2016,40,382-384. 41)Metal-FreePhosphorylationsof1,3,4-OxadiazolesandRelatedHeterocycles.LianghuaZou,Zhi-BingDong,CarstenBolm*.Synlett.,2012,11,1613-1616. 42)AnEfficientandMildortho-ZincationofAromaticsandHeterocyclesbyUsingTMP2Mg·2LiClinthePresenceofZnCl2.Zhi-BingDong*,WeihuaZhu,ZhiguangZhang,MinzhiLi.J.Organomet.Chem.,2010,695,775. 43)Structure-ReactivityRelationshipsinNegishiCross-CouplingReactions.Zhi-BingDong,GeorgManolikakes,PaulKnochel,HerbertMayr*.Chem.Eur.J.,2010,16,248. 44)SynthesisandApplicationof3-Substituted(S)-BINOLasChiralLigandsfortheAsymmetricEthylationofAldehydes.ZhiguangZhang,Zhi-BingDong,JinshanLi*.Chirality2010,22,820–826. 45)DirectZincationofReactiveAromaticsandHeterocyclesusingaMagnesiumBaseinthepresenceofZnCl2.Zhi-BingDong,GiulianoC.Clososki,StefanH.Wunderlich,AndreasUnsinn,JinshanLi,PaulKnochel*.Chem.Eur.J.,2009,15,457-468. 46)Palladium-CatalyzedCross-CouplingsofUnsaturatedHalidesBearingRelativelyAcidicHydrogenAtomswithOrganozincReagents.Zhi-BingDong,GeorgManolikakes,JinshanLi,PaulKnochel*.Synthesis2009,4,681-686. 47)NegishiCross-CouplingsCompatiblewithUnprotectedAmideFunctions.GeorgManolikakes,Zhi-BingDong,HerbertMayr,JinshanLi,PaulKnochel*.Chem.Eur.J.,2009,15,1324-1328. 48)AFacileSynthesisandtheAsymmetricCatalyticActivityofBINOL-basedThiazole(Thiadiazole)ThioetherLigands.Zhi-BingDong,BingLiu,CaoFang,JinshanLi*.J.Organomet.Chem.,2008,693,17-22. 49)3-SubstitutedBINOLSchiffBasesandTheirReductiveProductsforCatalyticAsymmetricAdditionofDiethylzinctoAldehydes.BingLiu,Zhi-BingDong,CaoFang,Jin-ShanLi*.Chirality2008,20,828–832. 50)AFacileSynthesisandAsymmetricCatalyticActivityofNew3-SubstitutedChiralBINOLLigands.BingLiu,CaoFang,Zhi-BingDong,JinshanLi*.Appl.Organometal.Chem.,2008,22,55-58. 51)One-potSynthesisoftheDerivativesof2-Cyclopenten-1-onebySOCl2/EtOH.ZhiguoHu*,Zhi-BingDong.J.Chem.Res.,2007,461-463. 52)NewBINOLSchiffBaseasaTridentateLigandforCatalyticAsymmetricAdditionofDiethylzinctoAldehydesinthePresenceofTitaniumTetraisopropoxide.BingLiu,CaoFang,Zhi-BingDong,JinshanLi*.Lett.Org.Chem.,2007,3,146-148. 53)Titanium(IV)asanEssentialPromoterintheAsymmetricAdditionofDiethylzinctoAldehydesCatalyzedbyAminonaphtholandImineLigandsbasedon3-SubstitutedBinaphthol.FuyongJiang,BingLiu,Zhi-BingDong,JinshanLi*.J.Organomet.Chem,.2007,692,4377-4380. 54)SynthesisofSymmetricTrisannelatedBenzenesand1,3,5-TrimethylBenzenebyUsingSOCl2/EtOHReagent.ZhiguoHu*,Zhi-BingDong,JunLiu,WenjieLiuandXinlingZhu.J.Chem.Res.,2005,252-253. 55)SynthesisofUnsymmetricTrisannelatedBenzenesbyUsingSOCl2/EtOHReagent.ZhiguoHu*,Zhi-BingDong,JunLiu,WenjieLiuandXinlingZhu.J.Chem.Res.,2005,603-604. 56)EfficientCondensationofCycloketonesandAcetoneUsingSOCl2/EtOH.ZhiguoHu*,Zhi-BingDong,JunLiu,WenjieLiuandXinlingZhu.J.Korean.Chem.Soc.,2005,49,470-472.